The disclosure provides for a layered metal with resistance to hydrogen induced cracking and method of production thereof, comprising a core metal alloy and a skin metal alloy. The core metal alloy comprises twinned boundaries. The core metal alloy has undergone plastic deformation and a heat treatment. The core metal alloy comprises nickel and cobalt. The skin metal alloy is disposed on the core metal alloy, wherein the skin metal alloy comprises an entropy greater than the core metal alloy. The core metal alloy comprises a greater density of twinned boundaries than the skin metal alloy. The skin metal alloy comprises a stacking fault energy of at least about 50 mJ/m.sup.2, and the skin metal alloy comprises iron, aluminum, and boron.

A turbomachine part includes a nickel-based superalloy substrate including, in mass content, 5.0% to 8.0% cobalt, 6.5% to 10% chromium, 0.5% to 2.5% molybdenum, 5.0% to 9.0% tungsten, 6.0% to 9.0% tantalum, 4.5% to 5.8% aluminum, hafnium in a mass content between 500 ppm and 1100 ppm, and optionally including niobium in a mass content less than or equal to 1.5%, and optionally at least one of carbon, zirconium and boron each in a mass content less than or equal to 100 ppm, the remainder being composed of nickel and unavoidable impurities.

A nickel-based alloy composition consisting, in weight percent, of: 4.0 to 5.6% aluminium, 0 0 to 1.0% titanium, 0.0 to 4.0% niobium, 0.0 to 11.9% tantalum, 2.0 to 12.7% tungsten, 0.0 to 3.0% molybdenum, 0.0 to 22.0% cobalt, 6.0 to 16.7% chromium, 0.02 to 0.35% carbon, 0.001 to 0.2% boron, 0.00 to 0.5% zirconium, 0.0 to 3.0% rhenium, 0.0 to 2.0% ruthenium, 0.0 to 3.0% iridium, 0.0 to 0.5% vanadium, 0.0 to 1.0% palladium, 0.0 to 1.0% platinum, 0.0 to 0.5% silicon, 0.0 to 0.1% yttrium, 0.0 to 0.1% lanthanum, 0.0 to 0.1% cerium, 0.0 to 0.003% sulphur, 0.0 to 0.25% manganese, 0.0 to 0.1 magnesium, 0.0 to 4.0% iron, 0.0 to 0.5% copper, 0.0 to 1.0% hafnium, the balance being nickel and incidental impurities, wherein the following equations are satisfied in which WNb, and WTa are the weight percent of niobium and tantalum respectively 1.1≤0.3W.sub.Nb+0.15W.sub.Ta.

A nickel-base superalloy is disclosed. The superally includes aluminum, cobalt, chromium, molybdenum, tantalum, titanium and tungsten, in addition to nickel, as alloy constituents, wherein rhenium can additionally be contained and the rhenium content is less than or equal to 2 wt. % and wherein the titanium content is greater than or equal to 1.5 wt. %. Further disclosed is a component made of the nickel-base superalloy.

Producing a Ni superalloy component in which the superalloy has a γ phase matrix containing intermetallic γ′ precipitates. Providing a Ni superalloy casting of the component; solutioning the component by heat treating the casting under vacuum and/or in an inert atmosphere at a temperature above the γ′ solvus to homogenize the γ phase; quenching and ageing the solutioned component to grow intermetallic γ′ precipitates in the homogenized γ phase. Before the solutioning step: heat treating the casting to produce a thermally grown oxide on the surface, oxide adherent to supress volatilization of Ni from the surface of the casting during the solutioning heat treatment. Performing the solutioning step under a Ni vapor pressure which is sufficient to supress volatilization of Ni from the surface of the casting during the solutioning heat treatment. During the solutioning heat treatment the component is encapsulated in a container protecting the casting from Si-doped contaminants.

Provided are a Ni-based alloy for a hot die having high high-temperature compressive strength, oxidation resistance, and tensile strength and capable of yielding high productivity or long die service life, and a hot forging die using the Ni-based alloy for hot die. A Ni-based alloy for hot die comprising, in mass %, W: 12.0 to 16.0%, Mo: 1.0 to 5.0%, Al: 5.0 to 7.5%, Cr: 0.5 to 5.0%, Ta: 0.5 to 7.0%, Ti: 0.1 to 3.5%, C: 0.01 to 0.25%, N: 0.0005 to 0.01%, B: 0.05% or less, S: 0.015% or less, one or two or more elements selected from rare earth elements, Y, Ca, and Mg: 0 to 0.020% in total, one or two elements selected from Zr and Hf: 1.5% or less in total, Nb: 3.5% or less, Co: 15.0% or less, the balance being Ni and inevitable impurities, wherein C and N satisfy the following relational expression 1:

C/100≤N≤C,

wherein C and N in the expression mean mass % of each component content.

A Ni-base superalloy composition to be used for powder-based additive manufacturing (AM) technology, such as selective laser melting (SLM) or electron beam melting (EBM). The cracking susceptibility during an AM process is considerably reduced by controlling the amount of elements, especially Hf, that form low-melting eutectics.

An additive manufacturing method wherein an object is formed by selectively solidifying layers of powder with at least one energy beam. The method includes forming the object from a nickel-based superalloy, wherein exposure parameters and an exposure pattern for the at least one energy beam result in the object having a directionally solidified microstructure with columnar grains aligned with a build direction, perpendicular to the layers. A composition of the nickel-based alloy by weight % may include: 9.3-9.7W, 9.0-9.5Co, 7.5-8.5Cr, 5.4-5.7Al, 3.1-3.3Ta, 1.4-1.6Hf, 0.6-0.9Ti, Mo 0.4-0.6, 007-0.015Zr, 0.01-0.02B with a carbon concentration of around 0.07-0.09 wt % and a balance of Ni.

Nickel-base composite niobium bearing alloys including delta and/or eta strengthening phases in addition to gamma prime precipitates in a gamma matrix.

The invention relates to a nickel-based superalloy comprising, in percentages by mass, 4.0 to 5.5% rhenium, 1.0 to 3.0 ruthenium, 2.0 to 14.0% cobalt, 0.3 to 1.0% molybdenum, 3.0 to 5.0% chromium, 2.5 to 4.0% tungsten, 4.5 to 6.5% aluminum, 0.50 to 1.50% titanium, 8.0 to 9.0% tantalum, 0.15 to 0.30% hafnium, 0.05 to 0.15% silicon, the balance being nickel and unavoidable impurities.

The invention also relates to a single-crystal blade (20A, 20B) comprising such an alloy and a turbomachine (10) comprising such a blade (20A, 20B).