There is provided a surface treatment method in which a processing gas is brought in contact with a heated processing object made of steel, an element in the processing gas is solid-solutionized, and thus a surface treatment is performed on the processing object. The processing object is heated to a heating temperature in a vicinity of a processing temperature at which the surface treatment is performed by heating an atmosphere in which the processing object is disposed. The surface treatment is performed by bringing the processing gas in contact with a surface of the processing object while the processing object which is heated is directly heated to the processing temperature.

There is provided a surface treatment method in which a processing gas is brought in contact with a heated processing object made of steel, an element in the processing gas is solid-solutionized, and thus a surface treatment is performed on the processing object. The processing object is heated to a heating temperature in a vicinity of a processing temperature at which the surface treatment is performed by heating an atmosphere in which the processing object is disposed. The surface treatment is performed by bringing the processing gas in contact with a surface of the processing object while the processing object which is heated is directly heated to the processing temperature.

A method for fabricating an article includes forming a billet consisting essentially of a stainless steel composition of manganese 2.00 wt. %-24.00 wt. % chromium 19.00 wt. %-30 wt. % molybdenum 0.50 wt. %-4.0 wt. % nitrogen 0.25 wt. %-1.10 wt. % carbon ≤1 wt. % phosphorus ≤0.03 wt. % sulfur ≤1 wt. % nickel <22 wt. % cobalt <0.10 wt. % silicon ≤1 wt. % niobium ≤0.80 wt. % oxygen ≤1 wt. % copper ≤0.25 wt. % balance iron.
The billet is annealed and cold worked to form an article. Without annealing of the article, the article is subsequently case hardened at a single case hardening temperature to form a surface layer on a top surface thereof. Articles formed with the indicated stainless steel composition with case hardened surface layers are also provided.

Downhole tools for earth-boring applications may include a component of a steel material and including a bore. An inner surface defining the bore may be treated with a surface treatment. The surface treatment may include a nitrided region having nitrogen diffused into the steel material and a ceramic material adjacent to the nitrided region; the ceramic material defining the inner surface. Methods of making downhole tools for earth-boring applications may involve exposing a component of the downhole tool to an elevated temperature to heat the component in a nitrogen-rich environment. Nitrogen may be diffused into a steel material of the component and a nitrided region may be formed at one or more surfaces of the component. A ceramic material may be coated on the nitrided region of the component.

Downhole tools for earth-boring applications may include a component of a steel material and including a bore. An inner surface defining the bore may be treated with a surface treatment. The surface treatment may include a nitrided region having nitrogen diffused into the steel material and a ceramic material adjacent to the nitrided region; the ceramic material defining the inner surface. Methods of making downhole tools for earth-boring applications may involve exposing a component of the downhole tool to an elevated temperature to heat the component in a nitrogen-rich environment. Nitrogen may be diffused into a steel material of the component and a nitrided region may be formed at one or more surfaces of the component. A ceramic material may be coated on the nitrided region of the component.

Provided is a ferritic stainless steel having a chemical composition containing, in mass %: 0.003% to 0.025% of C; 0.05% to 1.00% of Si; 0.05% to 1.00% of Mn; 0.04% or less of P; 0.01% or less of S; 16.0% to 23.0% of Cr; 0.20% to 0.80% of Cu; 0.05% to 0.60% of Ni; 0.20% to 0.70% of Nb; 0.005% to 0.020% of N; and the balance being Fe and incidental impurities, in which a nitrogen-enriched layer is present that has a nitrogen concentration peak value of 0.03 mass % to 0.30 mass % at a depth of within 0.05 μm of a surface of the steel.

Provided is a ferritic stainless steel having a chemical composition containing, in mass %: 0.003% to 0.025% of C; 0.05% to 1.00% of Si; 0.05% to 1.00% of Mn; 0.04% or less of P; 0.01% or less of S; 16.0% to 23.0% of Cr; 0.20% to 0.80% of Cu; 0.05% to 0.60% of Ni; 0.20% to 0.70% of Nb; 0.005% to 0.020% of N; and the balance being Fe and incidental impurities, in which a nitrogen-enriched layer is present that has a nitrogen concentration peak value of 0.03 mass % to 0.30 mass % at a depth of within 0.05 μm of a surface of the steel.

A combined oil control ring comprising a pair of annular side rails each having a gap, and an axially corrugated spacer expander arranged between the side rails; the corrugated spacer expander having on the inside seating tabs for pushing inner peripheral surfaces of the side rails; the side-rail-pushing surface of each seating tab being provided with a nitrided layer; an entire surface of each spacer expander except for those provided with the nitrided layer being coated with a plating film; and the plating film having Vickers hardness HV0.01 of 300 or less.

A combined oil control ring comprising a pair of annular side rails each having a gap, and an axially corrugated spacer expander arranged between the side rails; the corrugated spacer expander having on the inside seating tabs for pushing inner peripheral surfaces of the side rails; the side-rail-pushing surface of each seating tab being provided with a nitrided layer; an entire surface of each spacer expander except for those provided with the nitrided layer being coated with a plating film; and the plating film having Vickers hardness HV0.01 of 300 or less.

A method for producing an alloy steel composition includes the following steps: performing a first heat treatment on an alloy steel composition and maintaining for a first time period to soften the alloy steel composition; performing a first cooling treatment on the softened alloy steel composition; performing a treatment on the softened the alloy steel composition to form a workpiece; performing a second heat treatment on the workpiece and maintaining for a second time period; and performing a second cooling treatment on the workpiece to make the workpiece become to be a Bainite structure, and a cooling rate of the second cooling treatment is high than the cooling rate of the first cooling treatment.