Provided are a roughly-shaped steel material for a nitrided part, and a nitrided part obtained by nitriding the roughly-shaped steel material for a nitrided part, having a determined chemical composition, in which the portion with a diameter or width ranging from 60 to 130 mm of the roughly-shaped steel material for a nitrided part has a microstructure at a depth of 14.5 mm from a surface including, in terms of area fraction: tempered martensite and tempered bainite in total: from 70 to 100%; remaining austenite: from 0 to 5%; and a balance: ferrite and perlite; and has a microstructure at a depth of 15 mm or more from the surface including, in terms of area fraction: tempered martensite and tempered bainite in total: from 0 to less than 50%; remaining austenite: from 0 to 5%; and a balance: ferrite and perlite.

A grain-oriented electrical steel sheet that includes a base coating with a high TiN ratio advantageous for the application of tension to the steel sheet and has excellent magnetic property is provided. The grain-oriented electrical steel sheet includes: a base coating having a peak value PTiN of TiN in the form of osbornite, observed in a range of 42°<2θ<43° and a peak value PSiO.sub.2 of SiO.sub.2 in the form of cristobalite, observed in a range of 23°<2θ<25° of both more than 0 and satisfying a relationship PTiN≥PSiO.sub.2, in thin-film X-ray diffraction analysis; and an iron loss W.sub.17/50 of 1.0 W/kg or less.

A grain-oriented electrical steel sheet that includes a base coating with a high TiN ratio advantageous for the application of tension to the steel sheet and has excellent magnetic property is provided. The grain-oriented electrical steel sheet includes: a base coating having a peak value PTiN of TiN in the form of osbornite, observed in a range of 42°<2θ<43° and a peak value PSiO.sub.2 of SiO.sub.2 in the form of cristobalite, observed in a range of 23°<2θ<25° of both more than 0 and satisfying a relationship PTiN≥PSiO.sub.2, in thin-film X-ray diffraction analysis; and an iron loss W.sub.17/50 of 1.0 W/kg or less.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

An embodiment of the invention describes a method of treating an article to improve its corrosion resistance. The method includes the step of nitriding the article in a cyanide-free nitriding bath to obtain a nitrided article, heating the nitrided article in an atmosphere having nitrogen and carbon-carburizing to obtain a nitrided oxidised article. Further, in certain embodiments, the oxidised nitrided article may be coated with a metallic layer. The oxidised nitrided article with the metallic coating has improved corrosion resistance.

An embodiment of the invention describes a method of treating an article to improve its corrosion resistance. The method includes the step of nitriding the article in a cyanide-free nitriding bath to obtain a nitrided article, heating the nitrided article in an atmosphere having nitrogen and carbon-carburizing to obtain a nitrided oxidised article. Further, in certain embodiments, the oxidised nitrided article may be coated with a metallic layer. The oxidised nitrided article with the metallic coating has improved corrosion resistance.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.

Example nanoparticles may include an iron-based core, and a shell. The shell may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example alloy compositions may include an iron-based grain, and a grain boundary. The grain boundary may include a non-magnetic, anti-ferromagnetic, or ferrimagnetic material. Example techniques for forming iron-based core-shell nanoparticles may include depositing a shell on an iron-based core. The depositing may include immersing the iron-based core in a salt composition for a predetermined period of time. The depositing may include milling the iron-based core with a salt composition for a predetermined period of time. Example techniques for treating a composition comprising core-shell nanoparticles may include nitriding the composition.