An organometallic compound, which enables thin-film deposition through vapor deposition, and particularly to a Co or Fe precursor, which is suitable for use in atomic layer deposition or chemical vapor deposition, and a method of preparing the same.

A method for inducing tunable ferromagnetism with hydrogen annealing in delafossite films includes obtaining a PdCoO.sub.2 thin film, positioning the PdCoO2 thin film on a substrate, annealing the PdCoO.sub.2 thin film by hydrogenation, and cooling the PdCoO.sub.2 thin film to approximately room temperature.

A photocatalyst, a product including a photocatalyst, and a method for preparing a photocatalyst are provided. The photocatalyst is an inorganic oxide-based photocatalyst including inorganic oxide and a ferrocene-derived iron oxide layer formed on the inorganic oxide.

Described herein are methods of forming an electrocatalyst structure on an electrode, comprising depositing a first layer on the electrode using atomic layer deposition (ALD), wherein the first layer comprises a plurality of discrete nanoparticles of a first electrocatalyst, and depositing one or more of a second layer on the first layer and the electrode using ALD, wherein the one or more second layer comprises a second electrocatalyst, wherein the first layer and the one or more second layers, collectively, form a multi-layer electrocatalyst structure on the electrode. Also described are electrodes having a multi-layer electrocatalyst structure. This abstract is intended as a scanning tool for purposes of searching in the particular art and is not intended to be limiting of the present disclosure.

An anti-coking surface having a thickness up to 15 microns comprising from 15 to 50 wt. % of MnCr.sub.2O.sub.4 (for example manganochromite); from 15 to 25 wt. % of Cr.sub.0.23Mn.sub.0.08Ni.sub.0.69 (for example chromium manganese nickel); from 10 to 30 wt. % of Cr.sub.1.3Fe.sub.0.7O.sub.3 (for example chromium iron oxide); from 12 to 20 wt. % of Cr.sub.2O.sub.3 (for example eskolaite); from 4 to 20 wt. % of CuFe.sub.5O.sub.8 (for example copper iron oxide); and less than 5 wt. % of one or more compounds chosen from FeO(OH), CrO(OH), CrMn, Si and SiO.sub.2 (either as silicon oxide or quartz) and less than 0.5 wt. % of aluminum in any form provided that the sum of the components is 100 wt. % is provided on steel.

A rapid method of synthesizing nanoflowers made of nanoflakes of nickel molybdate (NiMoO.sub.4) directly on nickel foam (NF) through an aerosol-assisted chemical vapor deposition (AACVD) process is disclosed. The nickel molybdate nanoflowers were grown on NF by varying the deposition time for 60 and 120 min at a fixed temperature of 480° C. and their efficiency was investigated as oxygen evolution reaction (OER) catalysts in 1 M KOH electrolyte. The NiMoO.sub.4 nanoflowers of NF obtained after 60 minutes of AACVD process showed OER performance with lowest overpotential of 320 mV to reach standard current density of 10 mA cm.sup.−2. The catalyst continuously performed the OER for 15 h, signifying its prominent stability under electrochemical conditions.

An anti-coking surface having a thickness up to 15 microns comprising from 15 to 50 wt. % of MnCr.sub.2O.sub.4 (for example manganochromite); from 15 to 25 wt. % of Cr.sub.0.23Mn.sub.0.08Ni.sub.0.69 (for example chromium manganese nickel); from 10 to 30 wt. % of Cr.sub.1.3Fe.sub.0.7O.sub.3 (for example chromium iron oxide); from 12 to 20 wt. % of Cr.sub.2O.sub.3 (for example eskolaite); from 4 to 20 wt. % of CuFe.sub.5O.sub.8 (for example copper iron oxide); and less than 5 wt. % of one or more compounds chosen from FeO(OH), CrO(OH), CrMn, Si and SiO.sub.2 (either as silicon oxide or quartz) and less than 0.5 wt. % of aluminum in any form provided that the sum of the components is 100 wt. % is provided on steel.

A method is provided, including the following operations: depositing a liner in a feature of a substrate; depositing a monolayer of zinc over the liner; after depositing the monolayer of zinc, performing a thermal treatment on the substrate, wherein the thermal treatment is configured to cause migration of the zinc to an interface of the liner and an oxide layer of the substrate, the migration of the zinc producing an adhesive barrier at the interface that improves adhesion between the liner and the oxide layer of the substrate; repeating the operations of depositing the monolayer of zinc and performing the thermal treatment until a predefined number of cycles is reached.

Corrosion-resistant coated articles and a thermal chemical vapor deposition coating processes are disclosed. The article includes a metallic material having a first composition including a first iron concentration and a first chromium concentration, the first iron concentration being greater than the first chromium concentration, a surface of the metallic material having a second composition including a second iron concentration and a second chromium concentration, the second chromium concentration being less than the first chromium concentration, an oxide layer on the surface of the metallic material having a third composition including an iron oxide concentration and a chromium oxide concentration, the chromium oxide concentration being greater than the iron oxide concentration and being devoid of precipitates, and a thermal chemical vapor deposition coating on the oxide layer. The process includes producing the article by treating to produce the surface, oxidizing to produce the oxide layer, and applying the coating.

Corrosion-resistant coated articles and a thermal chemical vapor deposition coating processes are disclosed. The article includes a metallic material having a first composition including a first iron concentration and a first chromium concentration, the first iron concentration being greater than the first chromium concentration, a surface of the metallic material having a second composition including a second iron concentration and a second chromium concentration, the second chromium concentration being less than the first chromium concentration, an oxide layer on the surface of the metallic material having a third composition including an iron oxide concentration and a chromium oxide concentration, the chromium oxide concentration being greater than the iron oxide concentration and being devoid of precipitates, and a thermal chemical vapor deposition coating on the oxide layer. The process includes producing the article by treating to produce the surface, oxidizing to produce the oxide layer, and applying the coating.