The present invention provides a hearth roll for heat treatment furnaces, which has excellent build-up resistance, has a hexavalent-chromium-free thermal spray coating film formed on the roll surface thereof and is safe for the environment. A method for manufacturing a hearth roll for continuous annealing furnaces includes a first step of applying an aqueous solution containing chromium phosphate onto a thermal spray coating film formed on the roll surface of a hearth roll or impregnating the thermal spray coating film with the aqueous solution; and a second step of burning the hearth roll.

The present invention provides a hearth roll for heat treatment furnaces, which has excellent build-up resistance, has a hexavalent-chromium-free thermal spray coating film formed on the roll surface thereof and is safe for the environment. A method for manufacturing a hearth roll for continuous annealing furnaces includes a first step of applying an aqueous solution containing chromium phosphate onto a thermal spray coating film formed on the roll surface of a hearth roll or impregnating the thermal spray coating film with the aqueous solution; and a second step of burning the hearth roll.

A trivalent-chromium chemical conversion coating from which substantially no hexavalent chromium is released. The trivalent-chromium chemical conversion coating is one formed on the surface of a zinc or zinc-alloy deposit. In a brine spray test, the chemical conversion coating has unsusceptibility to corrosion (time required for white-rust formation) of 96 hours or longer. The chemical conversion coating has a hexavalent-chromium concentration less than 0.01 μg/cm.sup.2 in terms of metal atom amount. The amount of hexavalent chromium released after 30-day standing in a thermo-hygrostatic chamber at a temperature of 80° C. and a humidity of 95% (amount of hexavalent chromium released when the coating is immersed in 100° C. water for 10 minutes) is smaller than 0.05 μg/cm.sup.2.

A trivalent-chromium chemical conversion coating from which substantially no hexavalent chromium is released. The trivalent-chromium chemical conversion coating is one formed on the surface of a zinc or zinc-alloy deposit. In a brine spray test, the chemical conversion coating has unsusceptibility to corrosion (time required for white-rust formation) of 96 hours or longer. The chemical conversion coating has a hexavalent-chromium concentration less than 0.01 μg/cm.sup.2 in terms of metal atom amount. The amount of hexavalent chromium released after 30-day standing in a thermo-hygrostatic chamber at a temperature of 80° C. and a humidity of 95% (amount of hexavalent chromium released when the coating is immersed in 100° C. water for 10 minutes) is smaller than 0.05 μg/cm.sup.2.

Provided is a surface treatment solution composition comprising: 30 to 51 wt % of a trivalent chromium compound comprising chromium phosphate (A) and chromium nitrate (B) and having a content ratio of A/(A+B) that satisfies 0.3 to 0.6; 5 to 15 wt % of silane coupling agent; 0.2 to 3 wt % of vanadium-based anti-corrosive rust inhibitor; 3 to 12 wt % of colloidal silica; 0.5 to 5 wt % of polysiloxane copolymer; and 14 to 61.3 wt % of water, a hot dip galvanized steel sheet surface-treated using same, and a manufacturing method thereof. The hot dip galvanized steel sheet treated with the surface treatment solution composition containing trivalent chromium has an excellent corrosion resistance, blackening resistance, pipe-forming oil reactivity, and alkali resistance.

An apparatus for the implementation of a process for the continuous manufacturing of steel strips for packaging coated with a passivation layer is provided. An apparatus contains a transfer roller; a coating roller contacting the transfer roller, a surface of the coating roller having a plurality of hexagonally shaped cells with a line count being from 50 to 200 lines per centimeter and a volume being from 5.Math.10.sup.−6 to 10.Math.10.sup.−6 m.sup.3 per square meter of the coating roller surface; and a tank containing an aqueous passivation solution, the tank providing the aqueous passivation solution to the coating roller.

An apparatus for the implementation of a process for the continuous manufacturing of steel strips for packaging coated with a passivation layer is provided. An apparatus contains a transfer roller; a coating roller contacting the transfer roller, a surface of the coating roller having a plurality of hexagonally shaped cells with a line count being from 50 to 200 lines per centimeter and a volume being from 5.Math.10.sup.−6 to 10.Math.10.sup.−6 m.sup.3 per square meter of the coating roller surface; and a tank containing an aqueous passivation solution, the tank providing the aqueous passivation solution to the coating roller.

A trivalent-chromium chemical conversion coating from which substantially no hexavalent chromium is released. The trivalent-chromium chemical conversion coating is one formed on the surface of a zinc or zinc-alloy deposit. In a brine spray test, the chemical conversion coating has unsusceptibility to corrosion (time required for white-rust formation) of 96 hours or longer. The chemical conversion coating has a hexavalent-chromium concentration less than 0.01 μg/cm.sup.2 in terms of metal atom amount. The amount of hexavalent chromium released after 30-day standing in a thermo-hygrostatic chamber at a temperature of 80° C. and a humidity of 95% (amount of hexavalent chromium released when the coating is immersed in 100° C. water for 10 minutes) is smaller than 0.05 μg/cm.sup.2.

A trivalent-chromium chemical conversion coating from which substantially no hexavalent chromium is released. The trivalent-chromium chemical conversion coating is one formed on the surface of a zinc or zinc-alloy deposit. In a brine spray test, the chemical conversion coating has unsusceptibility to corrosion (time required for white-rust formation) of 96 hours or longer. The chemical conversion coating has a hexavalent-chromium concentration less than 0.01 μg/cm.sup.2 in terms of metal atom amount. The amount of hexavalent chromium released after 30-day standing in a thermo-hygrostatic chamber at a temperature of 80° C. and a humidity of 95% (amount of hexavalent chromium released when the coating is immersed in 100° C. water for 10 minutes) is smaller than 0.05 μg/cm.sup.2.

This invention provides a threaded connection for oil country tubular goods that exhibits excellent corrosion resistance and galling resistance, and a method for producing the threaded connection for oil country tubular goods. The method includes a Zn—Ni alloy plating layer formation step of forming a Zn—Ni alloy plating layer, and a chromate coating formation step of forming a chromate coating after the Zn—Ni alloy plating layer formation step. The chromate coating formation step includes a chromate treatment step and a drying step. The chromate coating formation step satisfy one or more conditions selected from the following conditions 1 to 3. Condition 1: stirring speed of the chromating solution in the chromate treatment step: a linear speed of 0.5 m/s or more; Condition 2: chromate treatment time in the chromate treatment step: less than 50 seconds; and Condition 3: drying temperature in the drying step: 60° C. or less.