The invention relates to the use of an acidic aqueous composition for pretreating cans, wherein an inorganic-organic conversion layer is formed in the course of the pretreatment, said conversion layer, as such, offering an excellent adhesive base for wax which improves sliding of the formed can and for the subsequent coating. The invention relates to a wet-chemical pretreatment method in which a can cylinder is first contacted with an acidic aqueous composition that contains water-soluble inorganic compounds of Zr, Ti, Si, Hf or Ce, and water-soluble polymers comprising carboxyl groups or hydroxyl groups; and subsequently is contacted with an aqueous wax dispersion. The invention further relates to an acidic aqueous composition suitable for the pretreatment method comprising water-soluble polymers selected from condensation products of glycoluril and aldehydes. The invention further relates to a method for producing can cylinders, said method including the pretreatment according to the invention.

A resin-coated seamless aluminum can (10) having polyester resin coatings (5, 7) on the inner and outer surfaces thereof, the polyester resin coatings (5, 7) being formed on the inner and outer surfaces of an aluminum can body (1) via non-chromium inorganic surface-treating films (3, 3), the polyester resin coatings (3, 7) being formed of a lowly crystalline polyester to which have been introduced a copolymer unit stemming from a dibasic acid and a copolymer unit stemming from a polybasic acid having a valence of 3 or more.

The present invention relates to an acidic aqueous composition for coating metallic surfaces, particularly of aluminium materials, that comprises, besides water and optionally further components, a) at least one compound selected from the group consisting of organoalkoxysilanes, organosilanols, polyorganosilanols, organosiloxanes and polyorganosiloxanes, b) at least one compound selected from the group consisting of titanium, zirconium, hafnium and aluminium compounds and silicon complex fluoride, and c) at least one copolymer which is stable at least in a segment of the pH range below 6 and which comprises, in alternating configuration, monomer units containing at least one carboxylic and/or phosphonic acid group and monomer units containing no acid group. The invention further relates to a corresponding coating method and to the use of the substrates coated by this method.

A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of φ30 μm using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.

A surface-treated metal material includes a metal sheet, a plating layer formed on the metal sheet and containing aluminum, magnesium, and zinc, and a composite coating formed on a surface of the plating layer, the composite coating including an organic silicon compound, one or two of a zirconium compound and a titanium compound, a phosphoric acid compound, a fluorine compound, and a vanadium compound, wherein, when a surface of the composite coating is analyzed at a spot size of φ30 μm using micro-fluorescent X-rays, a maximum value of V/Zn, which is a mass ratio of a V content to a Zn content, is 0.010 to 0.100.

Described herein is an alternative acidic, aqueous composition for effectively phosphating metallic surfaces, which includes, besides zinc ions, manganese ions, phosphate ions and, preferably, nickel ions, at least one accelerator of a formula R.sub.1R.sub.2R.sub.3C—NO.sub.2 where each of the substituents R.sub.1, R.sub.2 and R.sub.3 on the carbon atom is selected, independently of the others, from the group consisting of hydroxymethyl, 1-hydroxyethyl, 2-hydroxyethyl, 1-hydroxypropyl, 2-hydroxypropyl, 3-hydroxypropyl, 1-hydroxy-1-methyl ethyl and 2-hydroxy-1-methylethyl. Also described herein are a method for producing such a composition, an alternative method for phosphating metallic surfaces, and a method of using phosphate coatings produced accordingly.

Described herein is a method for treatment of at least one surface of a substrate at least partially made of aluminum and/or an aluminum alloy, including at least a step of contacting the surface with an acidic aqueous composition (A) including one or more metal compounds (M) selected from the group of titanium compounds, zirconium compounds, and hafnium compounds and one or more linear polymers (P) containing (m1) hydroxyethyl- and/or hydroxypropyl-(meth)acrylate, (m2) vinylphosphonic acid, and (m3) (meth)acrylic acid in form of their polymerized monomeric units, the one or more linear polymers (P) being included in the acidic aqueous composition (A) in an amount of 50 to 5000 ppm. Also described herein is an acidic aqueous composition (A), a master batch to produce the acidic aqueous composition (A), a method of using the acidic aqueous composition (A) for treating surfaces, and substrates comprising the treated surfaces.

The instant invention concerns the use of at least one polymer P obtained by radical copolymerization of a mixture of (i) acrylic acid; (ii) methacrylic acid; and (iii) at least one 2-hydroxyethyl methacrylate phosphate for treating a metallic surface intended to be coated by a paint, a varnish or an adhesive. The invention also concerns methods of coatings making use of this polymer P, compositions comprising the polymer P and useful for these methods, and the obtained coated materials.

The instant invention concerns the use of at least one polymer P obtained by radical copolymerization of a mixture of (i) acrylic acid; (ii) methacrylic acid; and (iii) at least one 2-hydroxyethyl methacrylate phosphate for treating a metallic surface intended to be coated by a paint, a varnish or an adhesive. The invention also concerns methods of coatings making use of this polymer P, compositions comprising the polymer P and useful for these methods, and the obtained coated materials.

An apparatus for the implementation of a process for the continuous manufacturing of steel strips for packaging coated with a passivation layer is provided. An apparatus contains a transfer roller; a coating roller contacting the transfer roller, a surface of the coating roller having a plurality of hexagonally shaped cells with a line count being from 50 to 200 lines per centimeter and a volume being from 5.Math.10.sup.−6 to 10.Math.10.sup.−6 m.sup.3 per square meter of the coating roller surface; and a tank containing an aqueous passivation solution, the tank providing the aqueous passivation solution to the coating roller.