An additive comprising one or more C.sub.3-C.sub.12 hydroxycarboxylic acids and/or one or more C.sub.3-C.sub.12 hydroxycarboxylic acid salts may be added to an aqueous system having galvanized metallurgy or a carbon steel surface in an effective amount to passivate a galvanized coating on the metallurgy or to decrease white rust formation or other types of corrosion upon the galvanized metallurgy or carbon steel surface in an aqueous system. In a non-limiting embodiment, the C.sub.3-C.sub.12 hydroxycarboxylic acid or the C.sub.3-C.sub.12 hydroxycarboxylic acid salt additive may utilize the zinc in the galvanized coating to achieve passivation. The passivation may occur while the system is shut down or in service. The aqueous system may be or include a cooling tower, a cooling water system, and combinations thereof. The additive may be used with or in the absence of a phosphorous-containing compound.

Certain metal surfaces are often unable to be effectively contacted with fluids containing hydrofluoric acid due to significant corrosion issues. Titanium and titanium alloy surfaces represent but one example. Corrosion inhibitor compositions comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof can be used to suppress metal corrosion, including that taking place on titanium and titanium alloy surfaces. Methods for suppressing corrosion of a metal surface can comprise: contacting a metal surface with a corrosive environment, the corrosive environment comprising hydrofluoric acid; introducing a corrosion inhibitor composition to the corrosive environment, the corrosion inhibitor composition comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof; contacting the metal surface with the corrosion inhibitor composition; and allowing the corrosion inhibitor composition to suppress corrosion of the metal surface being contacted by the corrosive environment.

Corrosion inhibitor formulations for use in heat transfer fluids include: (a) an optionally substituted benzoic acid or a salt thereof; (b) at least a first n-alkyl monocarboxylic acid or a salt thereof and a second n-alkyl monocarboxylic acid or a salt thereof, the first n-alkyl monocarboxylic acid and the second n-alkyl monocarboxylic acid being different; and (c) an azole compound. A ratio of weight percent of the first n-alkyl monocarboxylic acid or the salt thereof to weight percent of the second n-alkyl monocarboxylic acid or the salt thereof ranges from about 1:0.75 to about 1:2.00. A ratio of weight percent of the benzoic acid or the salt thereof to combined weight percent of the first n-alkyl monocarboxylic acid or the salt thereof and the second n-alkyl monocarboxylic acid or the salt thereof ranges from about 1:0.30 to about 1:2.25.

Corrosion inhibitor compositions are provided that can include a mixture of one or more transition metals, one or more organic phosphates, one or more inorganic phosphates, optionally a dispersant, and hydroxyphosphono acetic acid and/or salts thereof. Methods of mitigating or inhibiting corrosion of housing or conduits containing aqueous mediums are also disclosed. The methods can include the steps of pretreating the metal conduit with a mixture of one or more transition metals, one or more organic phosphates, one or more inorganic phosphates, and hydroxyphosphono acetic acid, introducing an aqueous medium into the metal conduit, and injecting a mixture of one or more transition metals, one or more organic phosphates, one or more inorganic phosphates, and hydroxyphosphono acetic acid and/or salts thereof into the aqueous medium.

A surface protection composition having a compound represented by the formula (1) in an amount of 0.1 to 10 mass % in terms of phosphorus element with respect to the total amount of the composition, the compound (b) the metal-containing compound in an amount of 0.1 to 10 mass % in terms of a metal element with the total amount of the composition or the amine compound in an amount of 0.1 to 5.0 mass % in terms of nitrogen element the total amount of the composition, the compound (c) (meth)acrylate having 2 or more carbon-carbon double bonds and hydrocarbon chains having four or more carbon atoms in an amount of 1.0 to 70 mass % with the total amount of the composition, the compound (d) a photopolymerization initiator in an amount of 0.1 to 10 mass % with the total amount of the composition. ##STR00001##

A method of improving corrosion and mar resistance of steel components by creating a black magnetite finish, with a medium temperature process, prior to application of a phosphate layer coating.

A composition and method of inhibiting corrosion and white rust on metal components in a water system. The composition preferably comprises an amino-acid based polymer (most preferably a polyaspartic acid or a salt thereof), hydroxyphosphonoacetic acid, and a second phosphonic acid (preferably a phosphonocarboxylic acid), and does not require the use of regulated metals. The composition is effective even in the presence of biocides. A preferred method of inhibiting white rust comprises adding an amino-acid based polymer or hydroxyphosphonoacetic acid or both to the water system. A preferred method of inhibiting corrosion or white rust comprises adding an amino-acid based polymer, hydroxyphosphonoacetic acid, and a phosphonocarboxylic acid to the water system. Preferably the active concentrations are at least 3 ppm each of the amino-acid based polymer and hydroxyphosphonoacetic acid when added to a volume of water in the water system.

Certain metal surfaces are often unable to be contacted effectively with fluids containing hydrofluoric acid due to significant corrosion issues. Steel surfaces represent but one example. Corrosion inhibitor compositions comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof can be used to suppress corrosion of steel surfaces, including those that contain multiple types or grades of steel. Methods for suppressing corrosion of a steel surface can comprise: contacting a steel surface with a corrosive environment, the corrosive environment comprising hydrofluoric acid; exposing the steel surface to a corrosion inhibitor composition, the corrosion inhibitor composition comprising an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof; and suppressing corrosion of the steel surface being contacted with the corrosive environment through exposure to the corrosion inhibitor composition.

A composition and method of inhibiting corrosion and white rust on metal components in a water system. The composition preferably comprises an amino-acid based polymer (most preferably a polyaspartic acid or a salt thereof), hydroxyphosphonoacetic acid, and a second phosphonic acid (preferably a phosphonocarboxylic acid), and does not require the use of regulated metals. The composition is effective even in the presence of biocides. A preferred method of inhibiting white rust comprises adding an amino-acid based polymer or hydroxyphosphonoacetic acid or both to the water system. A preferred method of inhibiting corrosion or white rust comprises adding an amino-acid based polymer, hydroxyphosphonoacetic acid, and a phosphonocarboxylic acid to the water system. Preferably the active concentrations are at least 3 ppm each of the amino-acid based polymer and hydroxyphosphonoacetic acid when added to a volume of water in the water system.

Certain metal surfaces are often unable to be effectively contacted with fluids containing hydrofluoric acid due to significant corrosion issues. Titanium and titanium alloy surfaces represent but one example. Corrosion inhibitor compositions comprising boric acid and an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof can be used to suppress metal corrosion, including that taking place on titanium and titanium alloy surfaces. Methods for suppressing corrosion of a metal surface can comprise: contacting a metal surface with a corrosive environment, the metal surface comprising titanium or a titanium alloy and the corrosive environment comprising hydrofluoric acid; introducing a corrosion inhibitor composition to the corrosive environment, the corrosion inhibitor composition comprising boric acid and an N-(phosphonoalkyl)iminodiacetic acid or any salt thereof; contacting the metal surface with the corrosion inhibitor composition; and allowing the corrosion inhibitor composition to suppress corrosion of the metal surface by the corrosive environment.