Disclosed herein is a fuel for use in a combustor of a gas turbine, wherein the fuel is a gas mixture that comprises hydrogen and exhaust gas from a total combustor.

A process is described for steam reforming a hydrocarbon feedstock, comprising passing a mixture of the hydrocarbon feedstock and steam through a catalyst bed comprising a particulate nickel steam reforming catalyst and a structured nickel steam reforming catalyst disposed within a plurality of externally heated tubes in a tubular steam reformer, wherein each tube has an inlet to which the mixture of hydrocarbon and steam is fed, an outlet from which a reformed gas containing hydrogen, carbon monoxide, carbon dioxide, steam and methane is recovered, and the steam reforming catalyst at the outlet of the tubes is the structured steam reforming catalyst, wherein the particulate steam reforming catalyst comprises 5 to 30% by weight nickel, and the structured steam reforming catalyst comprises nickel dispersed over the surface of a porous metal oxide present as a coating on a non-porous metal or ceramic structure.

A process for steam reforming a hydrocarbon feedstock containing one or more nitrogen compounds, including passing a mixture of the hydrocarbon feedstock and steam through a catalyst bed of one or more nickel steam reforming catalysts disposed within a plurality of externally heated tubes in a tubular steam reformer, each tube having an inlet to which the mixture of hydrocarbon and steam is fed, an outlet from which a reformed gas containing hydrogen, carbon monoxide, carbon dioxide, steam, ammonia and methane is recovered. The steam reforming catalyst at least at the outlet of the tubes comprises nickel dispersed over a porous metal oxide surface present as a coating on a non-porous metal or ceramic structure. The nickel content of the metal oxide coating is in the range of 5 to 50% by weight and the thickness of the coating is in the range of 5 to 150 micrometres.

A synthesis gas plant for producing a synthesis gas, where the synthesis gas plant includes a reforming section arranged to receive said feed gas and provide a combined synthesis gas, wherein said reforming section includes an electrically heated reforming reactor, a fired reforming reactor and an optional third reforming reactor. The reforming section is arranged to output a combined synthesis gas. An optional post processing unit downstream the reforming section is arranged to receive said combined synthesis gas stream and provide a post processed synthesis gas stream. A gas separation unit arranged to separate the combined synthesis gas stream or the post processed synthesis gas stream into a condensate, a product synthesis gas and an off-gas. At least a part of the off-gas is recycled from said gas separation unit to said one or more burners. Also, a process for producing synthesis gas from a feed gas comprising hydrocarbons.

A highly compact heat integrated fuel processor, which can be used for the production of hydrogen from a fuel source, suitable to feed a fuel cell, is described. The fuel processor assembly comprises a catalytic reforming zone (29) and a catalytic combustion zone (28), separated by a wall (27). Catalyst able to induce the reforming reactions is placed in the reforming zone and catalyst able to induce the combustion reaction is placed in the combustion zone, both in the form of coating on a suitable structured substrate, in the form of a metal monolith. Fe—Cr—Al—Y steel foils, in corrugated form so as to enhance the available area for reaction, can be used as suitable substrates. The reforming and the combustion zones can be either in rectangular shape, forming a stack with alternating combustion/reforming zones or in cylindrical shape forming annular sections with alternating combustion/reforming zones, in close contact to each other. The close placement of the combustion and reforming catalyst facilitate efficient heat transfer through the wall which separates the reforming and combustion chambers.

A reformer of the present disclosure includes a reformer body which has a cylindrical shape and extends horizontally, introducing raw fuel and water to perform a reforming reaction, the reformer body including therein a vaporization portion which generates steam, and a reforming portion which reacts the steam generated in the vaporization portion with raw fuel to generate a reformed gas; a raw fuel introduction pipe which introduces the raw fuel into the reformer body; a water introduction pipe including therein a water passage which introduces water into the reformer body; and a vaporization accelerating portion which is disposed in at least one of the vaporization portion and the water introduction pipe and accelerates vaporization of water in the vaporization portion.

In a fuel cell system, for example HTPEM fuel cells. a valve system is employed by selectively guiding exhaust gas from the burner either to the reformer for heating the reformer, especially during normal operation, or to by-pass the reformer in startup situations in order to heat the fuel cell stack before starting heating the reformer. Optionally, a compact burner/reformer unit is provided.

A modular direct reduction system for producing direct reduced iron (DRI) includes a reformer system which receives a flow of feed gas and which discharges a flow of reducing gas, the reformer system including a plurality of separate reformer modules connected together and wherein each reformer module includes a reformer vessel including an internal chamber, a reactor tube extending through the internal chamber of the reformer vessel and containing a catalyst configured to react with the feed gas received by the reactor tube to form the reducing gas, and a burner to burn a fuel gas to heat the reactor tube, and a furnace system connected to the reformer system and including a furnace having a first inlet which receives an iron ore, a second inlet which receives the reducing gas from the reformer system to form the DRI, and an outlet which discharges the DRI.

A fuel cell system is disclosed. The fuel cell system includes: a fuel cell module including a plurality of unit cells for generating electrical energy by using oxygen of air and hydrogen of a reformed fuel gas; a first module including a burner part which burns an unreacted fuel gas and air discharged from the fuel cell module, an air-heating part which heats air through heat exchange with a hot combustion gas and a flame generated by the burner part and supplies the heated air to the fuel cell module, and a water vapor generation part which converts water, flowing through an inner portion thereof, into water vapor through heat exchange with a hot combustion gas generated by the burner part; and a second module which mixes a fuel supplied from an external fuel supply source and water vapor supplied from a water-vapor generator part.

A reformer tube for producing synthesis gas by steam reforming of hydrocarbon-containing input gases is proposed where an outer shell tube is divided by means of a separating tray into a reaction chamber and an exit chamber, a dumped bed of a steam-reforming-active solid catalyst is arranged in the reaction chamber, at least one heat exchanger tube is arranged inside the reaction chamber and inside the dumped catalyst bed, whose entry end is in fluid connection with the dumped catalyst bed and whose exit end is in fluid connection with the exit chamber, the exit end of the heat exchanger tube is fed through the separating tray and opens out into a corrosion-protected inner tube which is disposed in the interior of the shell tube and is in fluid connection with a collection conduit for the synthesis gas product, and a gas-permeable thermal insulation layer is arranged between the inner wall of the shell tube and the outer wall of the inner tube.