System and process for producing steam in a steam-hydrocarbon reforming facility where oxygen is removed from demineralized water using a membrane degasifier. The membrane degasifier operates at a lower temperature compared to a deaerator, which is the conventional technology for removing oxygen.

The invention relates to a hydrogen plant for producing a hydrogen-comprising gas product comprisinga reformer system comprising at least one heat-recuperating reformer reaction unit (5) or a reformer system comprising two or more reformer units (5,22) in parallel, wherein at least one of said parallel reformer units (5) is present in the radiant section (12) of the reformer system, and at least one reformer unit (22) is located outside the radiant section (12) of the reformer system; a unit (8) configured to obtain hydrogen product gas; a carbon dioxide capture unit; the hydrogen plant further comprising a passage way configured to feed a hydrogen-comprising gas stream to the radiant section. The invention further relates to a process for producing a hydrogen-comprising gas product.

A reforming reactor for an endothermic process including a plurality of reformer tubes allowing a flow of hydrocarbons and at least one further fluid inside the tubes is provided. Wherein the reformer tubes contain in their interior a catalyst for the conversion of the hydrocarbons and the at least one further fluid to synthesis gas, and a means for heating the reformer tubes. Wherein at least a portion of the plurality of reformer tubes is provided with one or more elements for enlarging the outer surface area of a reformer tube, and the catalyst includes a structured catalyst. Also an endothermic process for the production of synthesis gas, including allowing a flow of hydrocarbons and at least one further fluid inside a plurality of reformer tubes, and heating the plurality of reformer tubes to convert said hydrocarbons and the at least one further fluid to synthesis gas.

Systems and methods are provided for using a high heat capacity gas as at least a portion of the diluent during the regeneration step of a reverse flow reactor process. Instead of using nitrogen or air as the primary diluent gas, CO.sub.2 and/or H.sub.2O can be added as diluent gas for the regeneration step in the reaction cycle. Increasing the heat capacity of the diluent gas provides a reduction in the peak temperature within the reactor relative to the amount of fuel combusted during regeneration. This can allow for a reduction in the volume of diluent used during regeneration and/or an increase in the amount of fuel used. Reducing the volume of diluent can reduce the pressure drop during regeneration, which can provide a corresponding reduction in the amount of compression required for recycle of the diluent. Increasing the amount of fuel can allow for a corresponding increase in the amount of endothermic reaction performed during the reaction step.

A segregated steam system and process in a hydrogen production facility wherein boiler feed water is heated by indirect heat exchange with a reformate, the heated boiler feed water is used to heat water condensate formed from the reformate, the heated water condensate is passed to a first steam drum for producing steam for a reformer feed gas mixture, and a second portion of the heated boiler feed water is passed to a second steam drum for producing steam for export.

Methods for dry reforming with a red mud catalyst support composition, one method including providing a methane feed and carbon dioxide feed to react over the red mud catalyst support composition at increased temperature and increased pressure to produce synthesis gas comprising H.sub.2 and CO, the composition comprising red mud material produced from an alumina extraction process from bauxite ore.

A reforming device 1 for producing a reformed gas from a methane-containing gas containing methane and carbon dioxide includes a reforming reaction tube 10 containing a catalyst layer 12 filled with a reforming catalyst 12a for reforming the methane-containing gas, and a multilayer pipe 103 for spraying a cooling fluid to an outer peripheral surface of the reforming reaction tube 10 at a position corresponding to a gas inlet of the catalyst layer 12 in a length direction of the catalyst layer 12.

A fuel cell single unit including: a fuel cell element in which an anode layer and a cathode layer are formed so as to sandwich an electrolyte layer; a reducing gas supply path for supplying a gas containing hydrogen to the anode layer; an oxidizing gas supply path for supplying a gas containing oxygen to the cathode layer; and an internal reforming catalyst layer, which has a reforming catalyst for steam-reforming a fuel gas, in at least a part of the reducing gas supply path is provided. An external reformer, which has a reforming catalyst for steam-reforming the fuel gas, is provided upstream of the reducing gas supply path, and the fuel gas partially reformed by the external reformer is supplied to the reducing gas supply path.

Systems and methods are provided for using size-reversing materials in vessels where direct heating is used to at least partially provide heat for reforming reactions under cyclic reforming conditions. An example of a size-reversing material is the combination of NiO and Al.sub.2O.sub.3. It has been discovered that size-reversing materials can undergo a phase transition that can assist with re-dispersion of metal at elevated temperatures. This can assist with maintaining catalytic activity for reforming over longer time periods in the presence of cyclic reforming conditions.

A process and plant for producing a synthesis gas chiefly consisting of hydrogen and carbon monoxide by catalytic steam reformation of a hydrocarbonaceous feed gas, wherein the heat of burners required for the chemical reforming reactions to take place is generated by producing a flue gas and wherein, by utilizing the heat contained in the synthesis gas and in the flue gas, a pure steam is generated from boiler feed water and a process steam is generated from process condensate, wherein for the generation of the pure steam synthesis gas and flue gas are used and for the generation of the process steam a part of the pure steam is used as heat-transfer medium and the remaining part of the pure steam is discharged from the process as export steam.