Patent classifications
C01B3/40
Low steam/carbon revamp of a plant comprising a steam reforming section and a water-gas shift section
The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH.sub.4, CO, CO.sub.2, H.sub.2 and H.sub.2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step,
said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
Low steam/carbon revamp of a plant comprising a steam reforming section and a water-gas shift section
The present invention relates to a revamp method for increasing the front-end capacity of a plant comprising a reforming section, wherein a feed is reformed in at least one reforming step to a reformed stream comprising CH.sub.4, CO, CO.sub.2, H.sub.2 and H.sub.2O a shift section wherein the reformed stream is shifted in a shift reaction in at least a high temperature shift step,
said method comprising the steps of In the High temperature shift step exchanging an original Fe-based catalyst with a non-Fe-based catalyst Increasing the feed flow to the reforming section, and The HTS step is carried out at a reduced steam/dry-gas ratio (S/DG) compared to an original S/DG in the original HTS step with the original Fe-based catalyst.
Nickel-containing catalyst composition having enhanced acidity for dry reforming processes
Modified red mud catalyst compositions, methods for production, and methods of use in dry reforming, the composition comprising: red mud material produced from an alumina extraction process from bauxite ore; and nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition.
Nickel-containing catalyst composition having enhanced acidity for dry reforming processes
Modified red mud catalyst compositions, methods for production, and methods of use in dry reforming, the composition comprising: red mud material produced from an alumina extraction process from bauxite ore; and nickel oxide, the nickel oxide present at between about 5 wt. % to about 40 wt. % of the modified red mud catalyst composition.
Zeolite-like metal-organic frameworks with ana topology
Embodiments of the present disclosure provide a metal-organic framework composition including a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers. Embodiments of the present disclosure further provide a method of separating chemical species including contacting a metal-organic framework having an ana topology with a flow of paraffins and separating the paraffins.
Zeolite-like metal-organic frameworks with ana topology
Embodiments of the present disclosure provide a metal-organic framework composition including a metal-organic framework having an ana topology, the metal-organic framework including one or more metals connected to one or more organic linkers. Embodiments of the present disclosure further provide a method of separating chemical species including contacting a metal-organic framework having an ana topology with a flow of paraffins and separating the paraffins.
A PROCESS FOR PREPARING A MOLDING, A MOLDING AND USE THEREOF AS METHANE REFORMING CATALYST
The present invention relates to a process for preparing a molding comprising a mixed oxide comprising O, Mg, and Ni, the process comprising: —(i) mixing water, a Mg source, a Ni source, and an acid, to obtain a mixture; —(ii) subjecting the mixture obtained from (i) to a shaping process; —(iii) calcining the molding obtained from (ii) in a gas atmosphere having a temperature in the range of from 700 to 1400° C.; wherein the molar ratio of the acid used in (i) to Ni, calculated as elemental Ni, of the Ni source used in (i), acid:Ni, is equal to or higher than 0.001:1. Further, the present invention relates to a molding comprising a mixed oxide comprising O, Mg, and Ni, wherein the mixed oxide comprises a specific crystalline phase Ni.sub.xMg.sub.yO, wherein the sum of x and y is 1, and wherein y is greater than 0.52. The molding is used for reforming methane to a synthesis gas comprising hydrogen and carbon monoxide.
A PROCESS FOR PREPARING A MOLDING, A MOLDING AND USE THEREOF AS METHANE REFORMING CATALYST
The present invention relates to a process for preparing a molding comprising a mixed oxide comprising O, Mg, and Ni, the process comprising: —(i) mixing water, a Mg source, a Ni source, and an acid, to obtain a mixture; —(ii) subjecting the mixture obtained from (i) to a shaping process; —(iii) calcining the molding obtained from (ii) in a gas atmosphere having a temperature in the range of from 700 to 1400° C.; wherein the molar ratio of the acid used in (i) to Ni, calculated as elemental Ni, of the Ni source used in (i), acid:Ni, is equal to or higher than 0.001:1. Further, the present invention relates to a molding comprising a mixed oxide comprising O, Mg, and Ni, wherein the mixed oxide comprises a specific crystalline phase Ni.sub.xMg.sub.yO, wherein the sum of x and y is 1, and wherein y is greater than 0.52. The molding is used for reforming methane to a synthesis gas comprising hydrogen and carbon monoxide.
ENDOTHERMIC REACTION OF A FEED GAS HEATED BY RESISTANCE HEATING
Array including a first and a second monolith of a structured catalyst for carrying out an endothermic reaction of a feed gas, wherein: a) the first and second monolith include a macroscopic structure of a first and second electrically conductive material; b) each of said first and second monoliths has a number of flow channels formed therein for conveying feed gas through the monoliths; c) the array includes at least a first and a second conductor electrically connected to said first and second monoliths, respectively, and to an electrical power supply, d) the first and second monolith are electrically connected by a monolith bridge; e) the array is configured to direct an electrical current to run from the first conductor through the first monolith to a second end, then through the bridge, and then through the second monolith to the second conductor.
ENDOTHERMIC REACTION OF A FEED GAS HEATED BY RESISTANCE HEATING
Array including a first and a second monolith of a structured catalyst for carrying out an endothermic reaction of a feed gas, wherein: a) the first and second monolith include a macroscopic structure of a first and second electrically conductive material; b) each of said first and second monoliths has a number of flow channels formed therein for conveying feed gas through the monoliths; c) the array includes at least a first and a second conductor electrically connected to said first and second monoliths, respectively, and to an electrical power supply, d) the first and second monolith are electrically connected by a monolith bridge; e) the array is configured to direct an electrical current to run from the first conductor through the first monolith to a second end, then through the bridge, and then through the second monolith to the second conductor.