Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.

A process for separating components or a fluid mixture using membranes comprising a selective layer made from copolymers of an amorphous per fluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for certain fluid components of interest while maintaining fast permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon? AF, Hyflon? AD, and Cytop?.

An air separation module includes a plurality of fibers located within a casing. A fiber membrane defines an exterior of each of the plurality of fibers. The fiber membrane also forms an interior passage along a length of each of the plurality of fibers. The fiber membrane is configured to permeate a gas through the fiber membrane. At least one perforated canister is placed between the plurality of fibers. The at least one perforated canister is configured to collect a permeated gas from the plurality of fibers.

A membrane-based air separation module includes an inlet configured to receive supply air, a first hollow fiber membrane configured to substantially remove water from the supply air to form an anhydrous air stream, and a permeate port configured to exhaust the water removed by the first hollow fiber membrane from the air separation module. The air separation module also includes a second hollow fiber membrane positioned downstream of the first hollow fiber membrane configured to receive the anhydrous air stream and substantially remove oxygen from the anhydrous air stream, an oxygen-enriched air outlet configured to exhaust the oxygen removed by the second hollow fiber membrane from the air separation module, and a nitrogen-enriched air outlet configured to supply a stream of nitrogen-enriched air to a fuel tank of an aircraft.

An air separation module includes a plurality of fibers located within a casing. A fiber membrane defines an exterior of each of the plurality of fibers. The fiber membrane also forms an interior passage along a length of each of the plurality of fibers. The fiber membrane is configured to permeate a gas through the fiber membrane. At least one perforated canister is placed between the plurality of fibers. The at least one perforated canister is configured to collect a permeated gas from the plurality of fibers.

A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of an amorphous perfluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers, such as Teflon AF, Hyflon AD, and Cytop.

An air separation module includes a plurality of fibers located within a casing. A fiber membrane defines an exterior of each of the plurality of fibers. The fiber membrane also forms an interior passage along a length of each of the plurality of fibers. The fiber membrane is configured to permeate a gas through the fiber membrane. At least one perforated canister is placed between the plurality of fibers. The at least one perforated canister is configured to collect a permeated gas from the plurality of fibers.

Described herein are facile, one-step initiated plasma enhanced chemical vapor deposition (iPECVD) methods of synthesizing hyper-thin (e.g., sub-100 nm) and flexible metal organic covalent network (MOCN) layers. As an example, the MOCN may be made from zinc tetraphenylporphyrin (ZnTPP) building units. When deposited on a membrane support, the MOCN layers demonstrate gas separation exceeding the upper bounds for multiple gas pairs while reducing the flux as compared to the support alone.

A process for separating components of a gas mixture using gas-separation copolymer membranes. These membranes use a selective layer made from copolymers of an amorphous perfluorinated dioxolane and a fluorovinyl monomer. The resulting membranes have superior selectivity performance for gas pairs of interest while maintaining fast gas permeance compared to membranes prepared using conventional perfluoropolymers such as Teflon AF, Hlyflon AD, and Cytop.

Disclosed is an asymmetric gas separation membrane made of a soluble aromatic polyimide having a specific repeating unit, the soluble aromatic polyimide including: as a tetracarboxylic acid component, a biphenyl structure and a phenyl structure; as a diamine component, a 3,3-diaminodiphenyl sulphone and a diaminodibenzothiophene, a diaminodibenzothiophene=5,5-dioxide, a diaminothioxanthene-10,10-dione, or a diaminothioxanthene-9,10,10-trione. Disclosed is a method for selectively separating and recovering a specific gas species from a mixed gas composed of a plurality of gas species using the asymmetric gas separation membrane, a method for selectively separating and recovering a nitrogen-rich gas from air using the asymmetric gas separation membrane, and a method for selectively separating carbon dioxide gas from a mixed gas containing carbon dioxide and methane and recovering methane-rich gas using the asymmetric gas separation membrane.