A process is described for the production of formaldehyde, comprising (a) subjecting methanol to oxidation with air in a formaldehyde production unit thereby producing a formaldehyde-containing stream; (b) separating said formaldehyde-containing stream into a formaldehyde product stream and a formaldehyde vent gas stream; wherein the vent gas stream, optionally after treatment in a vent gas treatment unit, is passed to one or more stages of: (i) synthesis gas generation, (ii) carbon dioxide removal, (iii) methanol synthesis or (iv) urea synthesis.

A method for producing synthesis gas may involve introducing a hydrocarbon-containing coke-oven gas and a carbon dioxide-containing converter gas into a first reaction zone where hydrogen present in the hydrocarbon-containing coke-oven gas reacts at least partly with carbon dioxide to form water, which reacts thermally with hydrocarbon to form synthesis gas containing carbon monoxide and hydrogen. The method may further involve introducing an oxygen-containing gas in a second reaction zone, and using the oxygen-containing gas and some hydrogen from the first reaction zone to produce thermal energy. Still further, the method may involve supplying the thermal energy produced in the second reaction zone to the first reaction zone.

A method is described for preparing a catalyst comprising the steps of (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.

The present disclosure relates to an integrated process for the production of formaldehyde-stabilized urea, starting with producing synthesis gas and including the preparation of methanol, ammonia, urea, and formaldehyde in amounts appropriate for the final product.

A method is described for preparing a catalyst comprising the steps of (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.

To allow hydrogen to be supplied to a dehydrogenation reaction unit for dehydrogenating an organic hydride by using a highly simple structure so that the activity of the dehydrogenation catalyst of the dehydrogenation reaction unit is prevented from being rapidly reduced. The hydrogen production system (1) comprises a first dehydrogenation reaction unit (3) for producing hydrogen by a dehydrogenation reaction of an organic hydride in presence of a first catalyst, and a second dehydrogenation reaction unit (4) for receiving a product of the first dehydrogenation reaction unit, and producing hydrogen by a dehydrogenation reaction of the organic hydride remaining in the product in presence of a second catalyst, wherein an amount of the first catalyst used in the first dehydrogenation reaction unit is equal to or less than an amount of the second catalyst used in the second dehydrogenation reaction unit, and an amount of hydrogen produced in the first dehydrogenation reaction unit is less than an amount of hydrogen produced in the second dehydrogenation reaction unit.

A fuel cell system includes: a reformer generating a reformed gas using a raw material; a fuel cell generating electric power; a raw material supply passage; a hydro-desulfurizer operative to remove sulfur component in the raw material; a recycle passage through which the reformed gas is supplied to the raw material supply passage provided upstream of the hydro-desulfurizer; a temperature detector detecting a temperature of the hydro-desulfurizer; and a controller, wherein: when the temperature of the hydro-desulfurizer reaches a predetermined temperature, the controller increases a flow rate of the raw material from a predetermined flow rate by a flow rate corresponding to a flow rate of the recycled gas, and then, the controller starts supplying the recycled gas to the recycle passage; and after the recycled gas reaches an upstream end of the recycle passage, the controller returns the flow rate of the raw material to the predetermined flow rate.

Zn-promoted and/or Ga-promoted cracking catalysts, such as cracking catalysts comprising an MSE framework zeolite or an MFI framework zeolite can provide unexpectedly superior conversion of branched paraffins when used as part of a catalyst during reforming of a hydrocarbon fuel stream. The conversion and reforming of the hydrocarbon fuel stream can occur, for example, in an internal combustion engine. The conversion and reforming can allow for formation of higher octane compounds from the branched paraffins.

A method for preparing a catalyst comprising (i) preparing a calcined shaped calcium aluminate catalyst support, (ii) treating the calcined shaped calcium aluminate support with water, and then drying the support, (iii) impregnating the dried support with a solution containing one or more metal compounds and drying the impregnated support, (iv) calcining the dried impregnated support, to form metal oxide on the surface of the support and (v) optionally repeating steps (ii), (iii) and (iv) on the metal oxide coated support. The method provides an eggshell catalyst in which the metal oxide is concentrated in an outer layer on the support.

A process and an apparatus for generating a hydrogen- and/or carbon monoxide-comprising gas product, wherein a hydrocarbon feed formed from a hydrocarbons-containing starting material is supplied together with superheated steam to a steam reforming proceeding at elevated pressure to obtain a hydrogen- and carbon monoxide-containing crude synthesis gas from which the gas product is derived are disclosed. The boiler feed water is supplied at a pressure higher than its critical pressure with heat to obtain supercritical water of which subsequently at least a portion is employed as propelling medium in a steam jet ejector by means of which the hydrocarbon feed and/or a substance employed for the formation thereof are compressed.