Provided are an ammonia synthesis system and its operation method, the system including an ammonia synthesis reactor; two or more catalyst beds included in the ammonia synthesis reactor; a backflow prevention plate disposed downstream from each of the catalyst beds except for the catalyst bed disposed at the lowest of the two or more catalyst beds for preventing a backflow of mixed gas; a distribution device disposed upstream from each of the two or more catalyst beds for distributing the mixed gas to the catalyst bed; mixed gas supply lines arranged to supply the mixed gas to each distribution device; and a mixed gas heat exchanger for supplying heat to the mixed gas by heat-exchanging the mixed gas fed through the mixed gas supply line with a heat storage medium.

An ammonia synthesis system, an operation method thereof, and an ammonia synthesis method are provided. The system includes a compressor for compressing mixed gas; a feed supply line for supplying the mixed gas to the compressor; an ammonia synthesis reactor for synthesizing ammonia by feeding the mixed gas compressed by the compressor into the reactor; a first ammonia separation device for separating syngas produced by the ammonia synthesis reactor into a sweep gas including nitrogen and hydrogen and into an ammonia rich gas; a second ammonia separation device for separating the ammonia rich gas into the ammonia and a regeneration stream including the nitrogen and the hydrogen; a feed recirculation line for recirculating the regeneration stream to the feed supply line; and a sweep gas recirculation line for recirculating the sweep gas to the ammonia synthesis reactor.

An ammonia synthesis system, an operation method thereof, and an ammonia synthesis method are provided. The system includes a compressor for compressing mixed gas; a feed supply line for supplying the mixed gas to the compressor; an ammonia synthesis reactor for synthesizing ammonia by feeding the mixed gas compressed by the compressor into the reactor; an air separation unit for separating nitrogen from air; a first cooler for cooling syngas including ammonia discharged from the ammonia synthesis reactor; and a second cooler for heat-exchanging gaseous nitrogen separated by the air separation unit with the syngas cooled by the first cooler, wherein gaseous nitrogen heat-exchanged by the second cooler is supplied to the feed supply line.

A ammonia synthesis system, an operation method thereof, and an ammonia synthesis method are provided. The system includes a compressor for compressing mixed gas; a feed supply line for supplying the mixed gas to the compressor; an ammonia synthesis reactor for synthesizing ammonia by feeding the mixed gas compressed by the compressor into the reactor; an ammonia separation device for separating syngas produced by the ammonia synthesis reactor into ammonia and a regeneration stream; a feed recirculation line for recirculating the regeneration stream to the feed supply line; and a buffer tank installed in the feed recirculation line.

Ammonia synthesis system including an ammonia synthesis reactor; two or more catalyst beds included in the ammonia synthesis reactor; one or more backflow prevention plates disposed, downstream from each of the catalyst beds except not below a lowest catalyst bed of the two or more catalyst beds, and preventing a gas backflow; distribution devices disposed upstream from each of the two or more catalyst beds and distributing gas to the catalyst bed;

hydrogen gas supply lines arranged to supply hydrogen gas to each of the distribution devices; and at least one microwave heating device for emitting microwaves to each of the two or more catalyst beds, and further including a nitrogen gas supply line disposed to supply nitrogen gas to a top-most distribution device of the distribution devices.

The invention relates to a system and a method for generating ammonia, wherein, in an ammonia reactor, ammonia (NH3) is generated from a synthesis gas, wherein the synthesis gas contains hydrogen (H2) and nitrogen (N2), wherein a nitrogren supply flow and a first heat exchanger are used, which are designed in such a way that the hot ammonia (NH3) flowing out of the ammonia reactor heats the nitrogen used as synthesis gas in the nitrogen supply flow.

A novel integrated system utilizing sulfur as alternative carbon-free fuel in an ammonia primary reformer combustion zone, with co-production of sulfuric acid from concentrated SO.sub.2 off-gas stream. Such integration shall reduce hydrocarbon fuel consumption, minimize CO.sub.2 emissions, and optimize overall energy utilization.

One or more reactants are flowed into thermal contact with a heating element in a reactor for a first time period. During a first part of a heating cycle, the one or more reactants are provided with a first temperature by heating with the heating element, such that one or more thermochemical reactions is initiated. The one or more thermochemical reactions includes pyrolysis, thermolysis, synthesis, hydrogenation, dehydrogenation, hydrogenolysis, or any combination thereof. The first heating element operates by Joule heating and has a porous construction that allows gas to flow therethrough. During a second part of the heating cycle, the one or more reactants are provided with a second temperature less than the first temperature, for example, by de-energizing the heating element. A duration of the first time period is equal to or greater than a duration of the heating cycle, which is less than five seconds.

An ammonia synthesis converter for small production units which provides full access for routine maintenance and catalyst replacement while providing adequate catalyst pressure drop to ensure kinetic performance and reduce heat leak from the catalyst beds. A shell has a removable top head and an annular basket is removably mounted in the shell. First and second catalyst beds are disposed in side-by-side catalyst pods in the annular zone of the basket extending substantially a height of the basket for axial down-flow in series. A quench gas is introduced into effluent from the first catalyst bed and the resulting mixture flows through the annular zone into a top of the second catalyst bed. A feed-effluent interchanger in the inner basket zone is adapted to receive effluent from the second catalyst bed and indirectly heat a feed to the first catalyst bed. Also, methods of operating and servicing the converter.