Methods for manufacturing fluorine-doped glass preforms for optical fibers are disclosed. An exemplary method includes exposing a soot preform to an atmosphere containing a fluorine-containing gas in a first elongated chamber of a first furnace. The first elongated chamber typically has a single isothermal hot zone, which may be maintained at a doping temperature of about 800° C. to 1200° C., to obtain a fluorine-doped soot preform. The exemplary method further includes dehydrating the fluorine-doped soot preform by exposing it to an atmosphere containing a chlorine-containing gas in a second elongated chamber of a second furnace. The second elongated chamber typically has an upper hot zone, which may be maintained at a dehydration temperature of about 1000° C. to 1350° C., and a lower hot zone, which may be maintained at a consolidation temperature of about 1500° C. to 1650° C. Dehydration of the fluorine-doped soot preform typically occurs in the upper hot zone of the second furnace. The exemplary method further includes consolidating the fluorine-doped soot preform within the lower hot zone of the second furnace to form a fluorine-doped glass preform.

A multicore optical fiber comprises a common cladding and a plurality of core portions disposed in the common cladding. Each of the core portions includes a central axis, a core region extending from the central axis to a radius r.sub.1, the core region comprising a relative refractive index Δ.sub.1, an inner cladding region extending from the radius r.sub.1 to a radius r.sub.2, the inner cladding region comprising a relative refractive index Δ.sub.2, and a depressed cladding extending from the radius r.sub.2 to a radius r.sub.3, the depressed cladding region comprising a relative refractive index Δ.sub.3 and a minimum relative refractive index Δ.sub.3 min. The relative refractive indexes may satisfy Δ.sub.1>Δ.sub.2>Δ.sub.3 min. The mode field diameter of each core portion may greater than or equal to 8.2 μm and less than or equal to 9.5 μm.

A method of forming an optical fiber, including: exposing a soot core preform to a dopant gas at a pressure of from 1.5 atm to 40 atm, the soot core preform comprising silica, the dopant gas comprising a first halogen doping precursor and a second halogen doping precursor, the first halogen doping precursor doping the soot core preform with a first halogen dopant and the second halogen precursor doping the soot core preform with a second halogen dopant; and sintering the soot core preform to form a halogen-doped closed-pore body, the halogen-doped closed-pore body having a combined concentration of the first halogen dopant and the second halogen dopant of at least 2.0 wt %.

An optical fiber can include a core comprising silica co-doped with nitrogen and chlorine and an outer cladding surrounding the core. In some aspects, the core can be characterized by an annealing temperature of less than or equal to about 1150° C. and/or the core can include a relative refractive index Δ.sub.core in a range of from about 0.15% to about 0.45%.

The present invention relates to a method for manufacturing a preform for optical fibers, which method comprises the sequential steps of: i) deposition of non-vitrified silica layers on the inner surface of a hollow substrate tube; ii) deposition of vitrified silica layers inside the hollow substrate tube on the inner surface of the non-vitrified silica layers deposited in step i); iii) removal of the hollow substrate tube from the vitrified silica layers deposited in step ii) and the non-vitrified silica layers deposited in step i) to obtain a deposited tube; iv) optional collapsing said deposited tube obtained in step iii) to obtain a deposited rod comprising from the periphery to the center at least one inner optical cladding and an optical core; v) preparation of an intermediate layer by the steps of: * deposition of non-vitrified silica layers on the outside surface of the deposited tube obtained in step iii) or deposited rod obtained in step iv) with a flame hydrolysis process in an outer reaction zone using glass-forming precursors, and subsequently; * drying and consolidating said non-vitrified silica layers into a vitrified fluorine-doped silica intermediate cladding layer; and * in case preceding step iv) was omitted collapsing; to provide a solid rod comprising from the periphery to the center the intermediate layer, at least one inner optical cladding and an optical core; wherein a fluorine-comprising gas is used during the deposition and/or drying and/or consolidating and wherein the intermediate layer has a ratio between the outer diameter of the intermediate cladding layer (C) to the outer diameter of the optical core (A) that is at least 3.5; vi) deposition of natural silica on the outside surface of the intermediate cladding layer of the solid rod obtained in step v) by melting natural silica particles in an outer deposition zone to produce an outer cladding whereby a preform is obtained.

A method for producing fluorine-containing silica glass includes: decompression degassing which includes degassing an inside of a furnace core tube under reduced pressure while heating the inside of the furnace core tube, after inserting a porous silica glass body into the furnace core tube provided in an airtight container; fluorine adding which includes supplying a fluorine compound gas into the furnace core tube and first heat-treating the porous silica glass body, under reduced pressure; and second heat-treating the porous silica glass body under reduced pressure at a temperature higher than temperatures in the decompression degassing process and the fluorine adding process.

A method for producing a fluorine-containing silica glass includes degassing which includes degassing an inside of a furnace core tube under reduced pressure while heating the inside of the furnace core tube, after inserting a porous silica glass body into the furnace core tube provided in an airtight container, supplying which includes degassing a fluorine compound gas into the furnace core tube under reduced pressure, fluorine adding which includes heat-treating the porous silica glass body under reduced pressure while supplying the fluorine compound gas into the furnace core tube and discharging a gas from the furnace core tube, and transparent vitrifying which includes heat-treating in a reduced pressure at a temperature higher than temperatures in the degassing process and the fluorine adding process.

According to embodiments, a method of making a microstructured glass article includes bundling M bare optical fibers in a fiber bundle, wherein M is an integer greater than 100. Thereafter, the fiber bundle may be inserted in a cavity of a soot preform. The soot preform may have a density of less than or equal to 1.5 g/cm.sup.3 and comprise silica-based glass soot. The soot preform and inserted fiber bundle may then be consolidated to form a microstructured glass article preform. The microstructured glass article preform may then be drawn into the microstructured glass article comprising M core elements embedded in a cladding matrix.

According to embodiments, a method of making a micro structured glass article 100 includes bundling M bare optical fibers in a fiber bundle, wherein M is an integer greater than 100. Thereafter, the fiber bundle may be inserted in a cavity of a soot preform. The soot preform may have a density of less than or equal to 1.5 g/cm3 and comprise silica-based glass soot. The soot preform and inserted fiber bundle may then be consolidated to form a microstructured glass article preform. The micro structured glass article preform may then be drawn into the microstructured glass article 100 comprising M core elements 102 embedded in a cladding matrix 104.

A manufacturing method of glass base material for optical fiber that can obtain glass base material for optical fiber with reduced fluctuation in optical properties in the longitudinal direction is provided. The manufacturing method includes: a first heat treatment step in which the porous glass base material inserted in a vessel of a sintering furnace is heated by a heater installed around the periphery of the vessel while being raised or lowered in the longitudinal direction in a chlorine-based gas containing atmosphere in the vessel of the sintering furnace; a second heat treatment step in which the porous glass base material is heated by the heater to obtain a transparent glass body while being raised or lowered in the longitudinal direction in an inert gas containing atmosphere in the vessel after the first heat treatment step; and a preliminary fluorine doping step prior to the second heat treatment step.