The present disclosure provides a coated glass substrate, first and second coating compositions, and a process for coating the substrate. The first composition includes a source of tin, a source of fluorine, a source of titanium, and a solvent. The second composition includes a source of tin, a source of fluorine, and a solvent, and can be free of titanium. The first composition is applied to the substrate under elevated temperatures, and a first or sub layer is formed on the substrate via pyrolysis. The second composition is then applied, to form a second or top layer over the sub layer.

According to one or more embodiments described herein, a coated article may comprise a transparent substrate and an optical coating. The transparent substrate may have a major surface, and the optical coating may be disposed on the major surface of the transparent substrate and form an air-side surface. The optical coating may comprise one or more layers of deposited material and one or more light-altering features which may reduce oscillations in the reflectance spectrum of the coated article. The coated article may exhibit a maximum hardness of about 8 GPa or greater, have an average photopic transmittance of about 50% or greater, and exhibit an angular color shift of less than about 10 from a reference illumination angle in a range of 0-10 degrees to an incident illumination angle in a range of 30-60 degrees relative to the air-side surface.

A light transmissive member includes a substrate having a light transmission property, wherein on one surface of the substrate, an antireflection layer in which a low-refractive index layer composed mainly of silicon oxide (SiO.sub.2) and a high-refractive index layer composed mainly of silicon nitride (SiN) are alternately stacked is formed, and on the other surface of the substrate, an antistatic layer including at least a transparent electrically conductive film layer is formed.

According to one or more embodiments described herein, a coated article may comprise a transparent substrate and an optical coating. The transparent substrate may have a major surface, and the optical coating may be disposed on the major surface of the transparent substrate and form an air-side surface. The optical coating may comprise one or more layers of deposited material and one or more light-altering features which may reduce oscillations in the reflectance spectrum of the coated article. The coated article may exhibit a maximum hardness of about 8 GPa or greater, have an average photopic transmittance of about 50% or greater, and exhibit an angular color shift of less than about 10 from a reference illumination angle in a range of 0-10 degrees to an incident illumination angle in a range of 30-60 degrees relative to the air-side surface.

Coated articles demonstrating anti-fouling properties are provided, comprising: (a) a substrate comprising sapphire; (b) an adhesion promoting layer applied to the substrate; and (c) a top layer comprising at least an anti-fouling coating applied to the adhesion promoting layer. The adhesion promoting layer is formed from a curable sol-gel composition and has a dry film thickness less than 1000 nm after curing. The present invention also provides a method of forming a coated article comprising: (a) applying a curable film-forming sol-gel composition on a sapphire substrate, to form a coated substrate with a sol-gel adhesion promoting layer having a dry film thickness less than 1000 nm after curing; (b) subjecting the coated substrate to a temperature of at least 500 C. to effect cure of the sol-gel composition; and (c) applying at least an anti-fouling coating on the adhesion promoting layer to form a multi-layer, coated article.

Exemplary antireflective coatings that have antireflective properties for light of non-normal angular incidence are disclosed. An exemplary antireflective coating includes a multilayer having alternating optical layers of high refractive index material and low refractive index material and a second layer directly contacting a first optical layer of the multilayer. The sum of the optical thickness of the second layer and the optical thickness of the first optical layer of the multilayer is between 146 nanometers and 190 nanometers.

According to one or more embodiments described herein, a coated article may comprise: a transparent substrate having a major surface, the major surface comprising a textured or rough surface inducing light scattering; and an optical coating disposed on the major surface of the transparent substrate and forming an air-side surface, the optical coating comprising one or more layers of material, the optical coating having a physical thickness of greater than 300 nm, wherein the coated article exhibits a maximum hardness of about 10 GPa or greater as measured on the air-side surface by a Berkovich Indenter Hardness Test along an indentation depth of about 50 nm or greater.

One or more aspects of the disclosure pertain to an article including a film disposed on a glass substrate, which may be strengthened, where the interface between the film and the glass substrate is modified, such that the article has an improved average flexural strength, and the film retains key functional properties for its application. Some key functional properties of the film include optical, electrical and/or mechanical properties. In one or more embodiments, the interface exhibits an effective adhesion energy of about less than about 4 J/m.sup.2. In some embodiments, the interface is modified by the inclusion of a crack mitigating layer containing an inorganic material between the glass substrate and the film.

An antireflection film is provided on a substrate. The antireflection film includes at least nine layers. An outermost layer of the nine layers is formed by SiO.sub.2 or MgF.sub.2.

According to one or more embodiments described herein, a coated article may comprise: a transparent substrate having a major surface, the major surface comprising a textured or rough surface inducing light scattering; and an optical coating disposed on the major surface of the transparent substrate and forming an air-side surface, the optical coating comprising one or more layers of material, the optical coating having a physical thickness of greater than 300 nm, wherein the coated article exhibits a maximum hardness of about 10 GPa or greater as measured on the air-side surface by a Berkovich Indenter Hardness Test along an indentation depth of about 50 nm or greater.