This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

A method of fabricating a ceramic material, the method including forming a ceramic material by performing a first chemical reaction at least between a first powder of an intermetallic compound and a reactive gas phase, a liquid phase being present around the grains of the first powder during the first chemical reaction, the liquid gas phase being obtained from a second powder of a metallic compound by melting the second powder or as a result of a second chemical reaction between at least one element of the first powder and at least one metallic element of the second powder, a working temperature being imposed during the formation of the ceramic material, which temperature is low enough to avoid melting the first powder.

A ceramic article includes a ceramic matrix composite that has a porous reinforcement structure and a ceramic matrix within pores of the porous reinforcement structure. The ceramic matrix composite includes a surface zone comprised of an exterior surface of the ceramic matrix composite and pores that extend from the exterior surface into the ceramic matrix composite. A glaze material seals the surface zone within the pores of the surface zone and on the exterior surface of the surface zone as an exterior glaze layer on the ceramic matrix composite. The glaze material is a glass or glass-ceramic material. The ceramic matrix composite includes an interior zone under the surface zone, and the interior zone is free of any of the glaze material and has a greater porosity than the surface zone.

Provided in one implementation is a method of manufacturing a three-dimensional object. The method can include depositing a substantially uniform layer of raw material onto a substrate. The raw material can include ceramic particles. The method can include selectively fusing particles of the raw material to form a first layer of the object. The method can include clearing non-fused particles of the raw material from the first layer of the object. The method can include repeating the steps of depositing a raw material, selectively fusing particles of the raw material, and clearing non-fused particles of the raw material to form additional layers of the object above the first layer.

The invention relates to a process for producing a three-dimensional green body by a fused filament fabrication process employing at least one filament, which comprises a core material (CM) coated with a layer of a shell material (SM), and a three-dimensional extrusion printer (3D printer). The three-dimensional extrusion printer 0 contains at least one nozzle and at least one mixing element. The invention further relates to three-dimensional objects and an extruded strand obtained by the process.

A method of making a ceramic composite component includes providing a fibrous preform or a plurality of fibers, providing a first plurality of particles, coating the first plurality of particles with a coating to produce a first plurality of coated particles, delivering the first plurality of coated particles to the fibrous preform or to an outer surface of the plurality of fibers, and converting the first plurality of coated particles into refractory compounds. The first plurality of particles or the coating comprises a refractory metal.

The method for manufacturing a ceramic component, in particular a ceramic component containing zirconia and/or alumina, for a timepiece or a jewelry piece, is characterised in that it includes a step (E3) of depositing at least one additional element or compound on a ceramic powder, optionally bound, by atomic layer deposition (ALD).

A process for manufacturing a ceramic powder with binder includes at least one additional element or compound, the ceramic powder with binder being in particular based on zirconia and/or alumina and/or strontium aluminate, wherein the process includes a step (E3) of depositing at least one additional element or compound on a ceramic powder with binder by a physical vapour deposition (PVD) and/or by a chemical vapour deposition (CVD) and/or by an atomic layer deposition (ALD).

Magnetizable abrasive particles are described comprising ceramic particles having outer surfaces comprising a coating of unsintered polyion and magnetic particles bonded to the polyion. In favored embodiments, the magnetic particles have a magnetic saturation of at least 10, 15, 20, 25, 30, 35, 40, 45 or 50 emu/gram. In another embodiment, an abrasive article is described comprising a plurality of magnetizable abrasive particles as described herein retained in a binder material. Also described are method of making magnetizable abrasive particles and methods of making an abrasive article comprising magnetizable abrasive particles.

A ceramic article includes a ceramic matrix composite that has a porous reinforcement structure and a ceramic matrix within pores of the porous reinforcement structure. The ceramic matrix composite includes a surface zone and a glaze material within pores of the surface zone and on an exterior side of the surface zone as an exterior glaze layer.