C04B41/5061

Surface-coated boron nitride sintered body tool

A surface-coated boron nitride sintered body tool is provided, in which at least a cutting edge portion includes a cubic boron nitride sintered body and a coating film formed on a surface of the cubic boron nitride sintered body. The coating film includes an A layer and a B layer. The A layer is formed of columnar crystals each having a particle size of 10 nm or more and 400 nm or less. The B layer is formed of columnar crystals each having a particle size of 5 nm or more and 70 nm or less. The B layer is formed by alternately stacking two or more compound layers having different compositions. The compound layers each have a thickness of 0.5 nm or more and 300 nm or less.

CUBIC BORON NITRIDE SINTERED BODY AND COATED CUBIC BORON NITRIDE SINTERED BODY
20170362130 · 2017-12-21 ·

A cBN sintered body has 40%-85% cBN by volume and 15% to 60% binder phase by volume. and inevitable impurities. The binder phase has an Al compound including Al and at least one element selected from N, O and B, and a Zr compound including Zr and at least one element selected from C, N, O and B. The Zr compound includes ZrO, or ZrO and ZrO.sub.2. In an X-ray diffraction, where a peak intensity of a (111) plane of the ZrO is I.sub.1, a peak intensity of a (101) plane of tetragonal ZrO.sub.2 is I.sub.2t and a peak intensity of a (111) plane of cubic ZrO.sub.2 is I.sub.2c, a ratio of the intensity of I.sub.1 to total intensities of I.sub.1, I.sub.2t and I.sub.2c is 0.6-1.0, and an average grain size of the Al compound is 80 nm-300 nm.

CUBIC BORON NITRIDE SINTERED BODY AND COATED CUBIC BORON NITRIDE SINTERED BODY
20170362130 · 2017-12-21 ·

A cBN sintered body has 40%-85% cBN by volume and 15% to 60% binder phase by volume. and inevitable impurities. The binder phase has an Al compound including Al and at least one element selected from N, O and B, and a Zr compound including Zr and at least one element selected from C, N, O and B. The Zr compound includes ZrO, or ZrO and ZrO.sub.2. In an X-ray diffraction, where a peak intensity of a (111) plane of the ZrO is I.sub.1, a peak intensity of a (101) plane of tetragonal ZrO.sub.2 is I.sub.2t and a peak intensity of a (111) plane of cubic ZrO.sub.2 is I.sub.2c, a ratio of the intensity of I.sub.1 to total intensities of I.sub.1, I.sub.2t and I.sub.2c is 0.6-1.0, and an average grain size of the Al compound is 80 nm-300 nm.

CUBIC BORON NITRIDE SINTERED MATERIAL, TOOL COMPRISING CUBIC BORON NITRIDE SINTERED MATERIAL AND METHOD FOR MANUFACTURING CUBIC BORON NITRIDE SINTERED MATERIAL

A cBN sintered material comprising cBN particles and a binder phase, in which the binder phase contains AlN and AlB.sub.2, a content proportion of cBN particles is 70 to 97 vol %, cBN sintered material has a volume resistivity up to 5×10.sup.−3 Ωcm, a rate of a peak intensity derived from Al with respect to a peak intensity derived from cBN particles is less than 1.0%, cBN particles include fine particles and coarse particles, coarse particles optionally include ultra-coarse particles, with respect to the entire cBN particles, a content proportion α of fine particles is from 10 vol %, a content proportion β of coarse particles is from 30 vol %, a content proportion γ of ultra-coarse particles is 25 vol % or less, and a total of the content proportion α of fine particles and the content proportion β of coarse particles is 50 to 100 vol %.

CUBIC BORON NITRIDE SINTERED MATERIAL, TOOL COMPRISING CUBIC BORON NITRIDE SINTERED MATERIAL AND METHOD FOR MANUFACTURING CUBIC BORON NITRIDE SINTERED MATERIAL

A cBN sintered material comprising cBN particles and a binder phase, in which the binder phase contains AlN and AlB.sub.2, a content proportion of cBN particles is 70 to 97 vol %, cBN sintered material has a volume resistivity up to 5×10.sup.−3 Ωcm, a rate of a peak intensity derived from Al with respect to a peak intensity derived from cBN particles is less than 1.0%, cBN particles include fine particles and coarse particles, coarse particles optionally include ultra-coarse particles, with respect to the entire cBN particles, a content proportion α of fine particles is from 10 vol %, a content proportion β of coarse particles is from 30 vol %, a content proportion γ of ultra-coarse particles is 25 vol % or less, and a total of the content proportion α of fine particles and the content proportion β of coarse particles is 50 to 100 vol %.

Silicon carbide-tantalum carbide composite and susceptor
09764992 · 2017-09-19 · ·

Provided is a silicon carbide-tantalum carbide composite having excellent durability. A silicon carbide-tantalum carbide composite (1) includes: a body (10) whose surface layer is at least partly formed of a first silicon carbide layer (12); a tantalum carbide layer (20); and a second silicon carbide layer (13). The tantalum carbide layer (20) is disposed over the first silicon carbide layer (12). The second silicon carbide layer (13) is interposed between the tantalum carbide layer (20) and the first silicon carbide layer (12). The second silicon carbide layer (13) has a C/Si composition ratio of not less than 1.2 as measured by X-ray photoelectron spectroscopy. The second silicon carbide layer (13) has a peak intensity ratio G/D of not less than 1.0 between the G-band and D-band of carbon as measured by Raman spectroscopy.

Protecting parts made of carbon-containing composite material from oxidation

A method of protecting a part made of carbon-including composite material against oxidation, the method including a) applying a coating composition on at least a portion of the outside surface of the part, the coating composition being in the form of an aqueous suspension including: a metallic phosphate; a powder of a compound comprising titanium; and a B.sub.4C powder; and b) applying heat treatment to the coating composition applied during step a) with a treatment temperature lying in the range 330° C. to 730° C. being imposed during the heat treatment in order to obtain a coating on the outside surface of the part, the coating including a first phase in which the metallic phosphate is in crystalline form and a second phase in which the metallic phosphate is in amorphous form.

Protecting parts made of carbon-containing composite material from oxidation

A method of protecting a part made of carbon-including composite material against oxidation, the method including a) applying a coating composition on at least a portion of the outside surface of the part, the coating composition being in the form of an aqueous suspension including: a metallic phosphate; a powder of a compound comprising titanium; and a B.sub.4C powder; and b) applying heat treatment to the coating composition applied during step a) with a treatment temperature lying in the range 330° C. to 730° C. being imposed during the heat treatment in order to obtain a coating on the outside surface of the part, the coating including a first phase in which the metallic phosphate is in crystalline form and a second phase in which the metallic phosphate is in amorphous form.

SURFACE-COATED CUTTING TOOL IN WHICH HARD COATING LAYER EXHIBITS EXCEPTIONAL ADHESION RESISTANCE, PLASTIC DEFORMATION RESISTANCE, AND ANOMALOUS DAMAGE RESISTANCE

A surface-coated cutting tool according to the present invention includes a tool body and a hard coating layer including a complex carbonitride layer containing a small amount of chlorine and (Ti.sub.(1-x)Zr.sub.xyHf.sub.x(1-y))(N.sub.(1-z)C.sub.z) (0.10≤x≤0.90, 0<y≤1.0, 0.08<z<0.60), a ZrHf and C content ratios in cycles, a cycle distance between a maximum ZrHf content point and an adjacent minimum ZrHf content point and a cycle distance between a maximum C content point and an adjacent minimum C content point are 5 to 100 nm, an average value of content ratio differences Δx and Δz is 0.02 or more, a distance between the maximum ZrHf content point and the maximum C content point is ⅕ or less of the distance between a maximum content point and a minimum content point of adjacent ZrHf components, and a composition fluctuation structure is 10% or more.

SURFACE-COATED CUTTING TOOL IN WHICH HARD COATING LAYER EXHIBITS EXCEPTIONAL ADHESION RESISTANCE, PLASTIC DEFORMATION RESISTANCE, AND ANOMALOUS DAMAGE RESISTANCE

A surface-coated cutting tool according to the present invention includes a tool body and a hard coating layer including a complex carbonitride layer containing a small amount of chlorine and (Ti.sub.(1-x)Zr.sub.xyHf.sub.x(1-y))(N.sub.(1-z)C.sub.z) (0.10≤x≤0.90, 0<y≤1.0, 0.08<z<0.60), a ZrHf and C content ratios in cycles, a cycle distance between a maximum ZrHf content point and an adjacent minimum ZrHf content point and a cycle distance between a maximum C content point and an adjacent minimum C content point are 5 to 100 nm, an average value of content ratio differences Δx and Δz is 0.02 or more, a distance between the maximum ZrHf content point and the maximum C content point is ⅕ or less of the distance between a maximum content point and a minimum content point of adjacent ZrHf components, and a composition fluctuation structure is 10% or more.