A barrier layer for an article according to an exemplary embodiment of this disclosure, among other possible things includes a bond coat comprising a matrix, diffusive particles disposed in the matrix, and gettering particles disposed in the matrix. The composition of the gettering particles is a reaction product of the chemical reaction of Equation 1 defined by Equation 2:

[00001]$\begin{array}{cc}{\mathrm{Si}}_w{O}_x{C}_y{N}_z+?O_2=w\mathrm{Si}{O}_2+y\mathrm{CO}+\frac{z}{2}{N}_2& \mathrm{Equation}1\end{array}$$\begin{array}{cc}?=\frac{2w+y-x}{2}& \mathrm{Equation}2\end{array}$

A barrier layer is also disclosed.

Provided are a coating structure, a turbine part having the same, and a method for manufacturing the coating structure. The coating structure is provided on a surface of a base portion including a ceramic matrix composite. The coating structure is layered on the surface of the base portion, and includes a bond coat layer formed of a rare-earth silicate and a top coat layer layered on the bond coat layer. The residual stress present in the bond coat layer is compressive residual stress. The oxygen permeability coefficient of the bond coat layer is no greater than 10.sup.9 kg.Math.m.sup.1.Math.s.sup.1 at a temperature of not lower than 1200 C. and a higher oxygen partial pressure of not less than 0.02 MPa. The bond coat layer may contain carbonitride particles or carbonitride whiskers.

Provided are a coating structure, a turbine part having the same, and a method for manufacturing the coating structure. The coating structure is provided on a surface of a base portion including a ceramic matrix composite. The coating structure is layered on the surface of the base portion, and includes a bond coat layer formed of a rare-earth silicate and a top coat layer layered on the bond coat layer. The residual stress present in the bond coat layer is compressive residual stress. The oxygen permeability coefficient of the bond coat layer is no greater than 10.sup.9 kg.Math.m.sup.1.Math.s.sup.1 at a temperature of not lower than 1200 C. and a higher oxygen partial pressure of not less than 0.02 MPa. The bond coat layer may contain carbonitride particles or carbonitride whiskers.

An environmental resistant coating member includes a SiC long fiber-reinforced ceramics substrate and an environmental barrier coating layer provided on the whole surface of the SiC long fiber-reinforced ceramics substrate. The environmental barrier coating layer includes a SiAlON bonding layer laminated on the SiC long fiber-reinforced ceramics substrate, a mullite layer laminated on the SiAlON bonding layer, a reaction inhibition layer laminated on the mullite layer, and a gradient layer formed on the reaction inhibition layer that gradually changes from a rare-earth disilicate to a rare-earth monosilicate. The reaction inhibition layer includes at least one of an alumina layer, a garnet layer, and a rare-earth (mono)silicate layer. When the reaction inhibition layer includes two or more of these layers, the layers are formed in the order of the alumina layer, the garnet layer, and the rare-earth (mono)silicate layer from a mullite layer side toward a gradient layer side.

An environmental resistant coating member includes a SiC long fiber-reinforced ceramics substrate and an environmental barrier coating layer provided on the whole surface of the SiC long fiber-reinforced ceramics substrate. The environmental barrier coating layer includes a SiAlON bonding layer laminated on the SiC long fiber-reinforced ceramics substrate, a mullite layer laminated on the SiAlON bonding layer, a reaction inhibition layer laminated on the mullite layer, and a gradient layer formed on the reaction inhibition layer that gradually changes from a rare-earth disilicate to a rare-earth monosilicate. The reaction inhibition layer includes at least one of an alumina layer, a garnet layer, and a rare-earth (mono)silicate layer. When the reaction inhibition layer includes two or more of these layers, the layers are formed in the order of the alumina layer, the garnet layer, and the rare-earth (mono)silicate layer from a mullite layer side toward a gradient layer side.

A coating used in a vapor-oxidative atmosphere has a first layer including SIALON and a second layer covering the first layer and being exposed to the atmosphere, the second layer including mullite, wherein the first layer and the second layer get in contact with each other.

A coating used in a vapor-oxidative atmosphere has a first layer including SIALON and a second layer covering the first layer and being exposed to the atmosphere, the second layer including mullite, wherein the first layer and the second layer get in contact with each other.

An external part including a substrate made of ceramic material on a surface of which extends a transparent inorganic protective coating, the protective coating being configured so as to have a refractive index substantially equal to that of the substrate in the visible range of the light spectrum, so that the external part has a colour substantially identical to the intrinsic colour of the substrate, the coating extending over a thickness chosen between 300 nm and 5 m.

A coating used in a vapor-oxidative atmosphere has a first layer including SIALON and a second layer covering the first layer and being exposed to the atmosphere, the second layer including mullite, wherein the first layer and the second layer get in contact with each other.

A coating used in a vapor-oxidative atmosphere has a first layer including SIALON and a second layer covering the first layer and being exposed to the atmosphere, the second layer including mullite, wherein the first layer and the second layer get in contact with each other.