The present disclosure relates to the technical field of ceramic powder preparation, and discloses a zirconia/titania/cerium oxide doped rare earth tantalum/niobate RETa/NbO.sub.4 ceramic powder and a preparation method thereof. A general chemical formula of the ceramic powder is RE.sub.1-x(Ta/Nb).sub.1-x(Zr/Ce/Ti).sub.2xO.sub.4, 0<x<1, the crystal structure of the ceramic powder is orthorhombic, the lattice space group of the ceramic powder is C222.sub.1, the particle size of the ceramic powder ranges from 10 to 70 μm, and particles of the ceramic powder are spherical. During preparation, the raw materials are ball-milled before a high temperature solid phase reaction, then mixed with a solvent and an organic binder to obtain a slurry C, then centrifuged and atomized to obtain dry pellets, and finally sintered to obtain a zirconia/titanium oxide/cerium oxide doped rare earth tantalum/niobate RETa/NbO.sub.4 ceramic powder, which satisfies the requirements of APS technology for ceramic powders.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A thermal insulation member is directly or indirectly sandwiched between a first object and a second object and thereby suppresses or interrupts heat transfer between the first object and the second object. The thermal insulation member comprises: a first main surface opposed to the first object; and a second main surface positioned on the opposite side from the first main surface and opposed to the second object. The thermal insulation member has a porous structure of ceramic having pores. ZrO.sub.2 particles and different type material exist on surfaces of the ZrO.sub.2 particles form a skeleton of the porous structure. The different type material includes at least one selected out of SiO.sub.2, TiO.sub.2, La.sub.2O.sub.3, and Y.sub.2O.sub.3.

An antimicrobial material including a substrate and an antimicrobial mixed metal oxide, mixed metal sulfide, or mixed metal oxysulfide in and/or on the substrate is described, as well as antimicrobial coating materials and coatings formed therefrom. The antimicrobial material may be constituted in an antimicrobial surface of a surface-presenting substrate, to combat transmission and spread of microbial disease, e.g., disease mediated by microbial pathogens such as bacteria, viruses, and fungi. Antimicrobial mixed metal oxide, mixed metal sulfide, or mixed metal oxysulfide as described may be contacted with microorganisms to effect inactivation thereof.

A method of producing polycrystalline Y.sub.3Ba.sub.5Cu.sub.8O.sub.y (Y-358) whereby powders of yttrium (III) oxide, a barium (II) salt, and copper (II) oxide are pelletized, calcined at 850 to 950° C. for 8 to 16 hours, ball milled under controlled conditions, pelletized again and sintered in an oxygen atmosphere at 900 to 1000° C. for up to 72 hours. The polycrystalline Y.sub.3Ba.sub.5Cu.sub.8O.sub.y thus produced is in the form of elongated crystals having an average length of 2 to 10 μm and an average width of 1 to 2 μm, and embedded with spherical nanoparticles of yttrium deficient Y.sub.3Ba.sub.5Cu.sub.8O.sub.y having an average diameter of 5 to 20 nm. The spherical nanoparticles are present as agglomerates having flower-like morphology with an average particles size of 30 to 60 nm. The ball milled polycrystalline Y.sub.3Ba.sub.5Cu.sub.8O.sub.y prepared under controlled conditions shows significant enhancement of superconducting and flux pinning properties.

A ferrite sintered magnet comprises a plurality of main phase grains containing a ferrite having a hexagonal structure, wherein at least some of the main phase grains are core-shell structure grains each having a core and a shell covering the core; and wherein the minimum value of the content of La in the core is [La]c atom %; the minimum value of the content of Co in the core is [Co]c atom %; the maximum value of the content of La in the shell is [La]s atom %; the maximum value of the content of Co in the shell is [Co]s atom %; [La]c+[Co]c is 3.08 atom % or more and 4.44 atom % or less; and [La]s+[Co]s is 7.60 atom % or more and 9.89 atom % or less.

Provided are pre-sintered and sintered zirconia dental ceramic materials. The materials have a gradient in yttria content. The materials may have a gradient in one or more physical/mechanical property and/or one or more optical property. The materials may be made by mixing at least two zirconia ceramic powders having different yttria content. A sintered zirconia dental ceramic material may be in the form of a dental article.

The present invention provides a ferrite sintered magnet comprising ferrite crystal grains having a hexagonal structure, wherein the ferrite sintered magnet comprises metallic elements at an atomic ratio represented by formula (1). In formula (1), R is at least one element selected from the group consisting of Bi and rare-earth elements, and R comprises at least La. In formula (1), w, x, z and m satisfy formulae (2) to (5). The above-mentioned ferrite sintered magnet further has a coefficient of variation of a size of the crystal grains in a section parallel to a c axis of less than 45%.
Ca.sub.1-w-xR.sub.wSr.sub.xFe.sub.zCo.sub.m  (1)
0.360≤w≤0.420  (2)
0.110≤x≤0.173  (3)
8.51≤z≤9.71  (4)
0.208≤m≤0.269  (5)

Provided are a high-entropy carbide ceramic, a rare earth-containing high-entropy carbide ceramic, fibers thereof, precursors thereof, and preparation methods thereof. The precursor includes at least four elements selected from Ti, Zr, Hf, V, Nb, Ta, Mo, and W, with each metal element accounting for 5-35% of the total molar quantity of metal elements in the precursor. The rare earth-containing high-entropy carbide ceramic precursor includes at least four transition metal elements and at least one rare-earth metal element. The high-entropy ceramic is a single-crystal-phase high-performance ceramic prepared from the precursor, with each element being homogenously distributed at molecular level. The method for preparing the high-entropy ceramic fiber includes uniformly mixing high-entropy carbide ceramic precursor containing target metal elements with spinning aid and solvent to prepare a spinnable precursor solution, followed by spinning, pyrolyzation, and high-temperature solid solution to prepare the high-entropy carbide ceramic fiber.

A ceramic powder material containing: a first garnet-type compound containing Li, La, and Zr; and a second garnet-type compound containing Li, La, and Zr and having a composition different from a composition of the first garnet-type compound, in which the first garnet-type compound and the second garnet-type compound are represented by Formula [1] Li.sub.7-(3x+y)M1.sub.xLa.sub.3Zr.sub.2-yM2.sub.yO.sub.12, where Ml is Al or Ga, M2 is Nb or Ta, the first garnet-type compound satisfies 0≤(3x+y)≤0.5, and the second garnet-type compound satisfies 0.5<(3x+y)≤1.5.