Translucency of a yttria-stabilized zirconia ceramic is improved to achieve even higher translucency than what is currently offered on the market, without greatly altering its mechanical properties. The enhancement is done by incorporating magnesium-containing dopants into the microstructure of yttria-stabilized zirconia ceramic dental ceramics.

Disclosed is a rapid, reproducible solution-based method to synthesize solid sodium ion-conductive materials. The method includes: (a) forming an aqueous mixture of (i) at least one sodium salt, and (ii) at least one metal oxide; (b) adding at least one phosphorous precursor as a neutralizing agent into the mixture; (c) concentrating the mixture to form a paste; (d) calcining or removing liquid from the paste to form a solid; and (e) sintering the solid at a high temperature to form a dense, non-porous, sodium ion-conductive material. Solid sodium ion-conductive materials have electrochemical applications, including use as solid electrolytes for batteries.

A metal-ceramic composite for a fuel cell anode is disclosed. In the metal-ceramic composite, the content of the metal is greatly reduced and the intervals between the metal particles are maintained constant, achieving improved activity and conductivity. The metal-ceramic composite includes a metal catalyst raw material and a mixed-conductive ceramic. The metal catalyst raw material is present in an amount such that the content of the metal catalyst nanoparticles in the metal-ceramic composite is significantly lower than in conventional metal-ceramic composites. The presence of a small amount of the metal catalyst nanoparticles in the metal-ceramic composite minimizes the occurrence of stress resulting from a change in the volume of the metal catalyst and provides a solution to the problem of defects, achieving improved life characteristics. Also disclosed is a method for preparing the metal-ceramic composite.

The present disclosure provides a glass ceramic composite electrolyte comprising gadolinium doped ceria and glass composite with desired ionic conductivity in the temperature range of 400 to 600° C., suitable for applications in solid oxide fuel cells. Also disclosed is a process for the preparation of the glass ceramic composite electrolyte.

Provided is a zirconia sintered body having both high translucency and high strength. The zirconia sintered body includes crystal grains that include a cubic domain and a tetragonal domain, wherein a stabilizer and lanthanum is dissolved as a solid solution therein. The sintered body can be obtained by a manufacturing method including: a mixing step of obtaining a mixed powder by mixing a zirconia source, a stabilizer source, and a lanthanum source; a molding step of obtaining a green body by molding the obtained mixed powder; a sintering step of obtaining a sintered body by sintering the obtained green body at a sintering temperature of 1650° C. or higher; and a temperature lowering step of lowering the temperature from the sintering temperature to 1000° C. at a temperature lowering rate exceeding 1° C./min.

A particle mixture having: ZrO.sub.2+HfO.sub.2+Y.sub.2O.sub.3+CeO.sub.2; 0%≤Al.sub.2O.sub.3≤1.5%; other oxides than ZrO.sub.2, HfO.sub.2, Y.sub.2O.sub.3, CeO.sub.2 and Al.sub.2O.sub.3: between 0.5% and 12%. The contents of Y.sub.2O.sub.3 and CeO.sub.2, on the basis of the sum of ZrO.sub.2, HfO.sub.2, Y.sub.2O.sub.3 and CeO.sub.2, being such that 1.8%≤Y.sub.2O.sub.3≤3% and 0.1%≤CeO.sub.2≤0.9%. The mixture includes between 0.5% and 10% of particles of an oxide pigment. The content of other oxides and which are not included in the oxide pigment being less than 2%. The particles of the oxide pigment including, for more than 95%, of a material chosen from: oxide(s) of perovskite structure or equivalent of precursor(s) of these oxides, oxides of spinal structure or an equivalent amount of precursor(s) of these oxides, and oxides of hematite structure E.sub.2O.sub.3, oxides of rutile structure FO.sub.2, with “E” and “F” being chosen.

A strongly scattering optoceramic converter material having a density of less than 97% is provided, as well as a method for producing such an optoceramic material. By appropriately choosing in particular the composition, blending method, and sintering conditions, the production method permits to produce converter materials with tailored properties.

The present invention relates to a process for sintering a compacted powder of at least one oxide of a metal selected from an actinide and a lanthanide, this process comprising the following successive steps, carried out in a furnace and under an atmosphere comprising an inert gas, dihydrogen and water: (a) a temperature increase from an initial temperature T.sub.I up to a hold temperature T.sub.P, (b) maintaining the temperature at the hold temperature T.sub.P, and (c) a temperature decrease from the hold temperature T.sub.P down to a final temperature T.sub.F, in which the P(H.sub.2)/P(H.sub.2O) ratio is such that: 500<P(H.sub.2)/P(H.sub.2O)≦50 000, during step (a), from T.sub.I until a first intermediate temperature T.sub.i1 between 1000° C. and T.sub.P is reached, and P(H.sub.2)/P(H.sub.2O)≦500, at least during step (c), from a second intermediate temperature T.sub.i2 between T.sub.P and 1000° C., until T.sub.F is reached.

A process for the preparation of a membrane electrode assembly comprising providing, in the following layer order, (I) a green supporting electrode layer comprising a composite of a mixed metal oxide and Ni oxide; (IV) a green mixed metal oxide membrane layer; and (V) a green second electrode layer comprising a composite of a mixed metal oxide and Ni oxide; and sintering all three layers simultaneously.

An electrode can include a functional layer having an Ln.sub.2MO.sub.4 phase, where Ln is at least one lanthanide optionally doped with a metal and M is at least one 3d transition metal, and a heavily-doped ceria phase. An electrochemical device or a sensor device can include the electrode.