Method for the preparation, by means of a heating technique, of a composite material composed of a matrix of at least a first oxide of at least one metal and/or at least one metalloid reinforced by reinforcements in at least a second oxide of at least one metal and/or at least one metalloid, characterised in that the following successive steps are carried out: the reinforcements are placed in at least one liquid precursor of the first oxide of at least one metal and/or at least one metalloid; said reinforcements and the liquid precursor are heated so as to form the first oxide by means of the thermal decomposition of said liquid precursor, and to deposit the first oxide thus formed around the reinforcements and between the reinforcements thus forming the matrix.

Set forth herein are garnet material compositions, e.g., lithium-stuffed garnets and lithium-stuffed garnets doped with alumina, which are suitable for use as electrolytes and catholytes in solid state battery applications. Also set forth herein are lithium-stuffed garnet thin films having fine grains therein. Disclosed herein are novel and inventive methods of making and using lithium-stuffed garnets as catholytes, electrolytes and/or anolytes for all solid state lithium rechargeable batteries. Also disclosed herein are novel electrochemical devices which incorporate these garnet catholytes, electrolytes and/or anolytes. Also set forth herein are methods for preparing novel structures, including dense thin (<50 um) free standing membranes of an ionically conducting material for use as a catholyte, electrolyte, and, or, anolyte, in an electrochemical device, a battery component (positive or negative electrode materials), or a complete solid state electrochemical energy storage device. Also, the methods set forth herein disclose novel sintering techniques, e.g., for heating and/or field assisted (FAST) sintering, for solid state energy storage devices and the components thereof.

A process for the manufacture of a refractory block including more than 80% zirconia, in percentage by weight based on the oxides. The process includes the following successive stages: melting, under reducing conditions, of a charge including more than 50% zircon, in percentage by weight, such as to reduce the zircon and obtain a molten material, application of oxidizing conditions to the molten material, casting of the molten material, and cooling until at least partial solidification of the molten material in the form of a block. Also, the process can include heat treatment of the block.

A ceramic powder material containing: a first garnet-type compound containing Li, La, and Zr; and a second garnet-type compound containing Li, La, and Zr and having a composition different from a composition of the first garnet-type compound, in which the first garnet-type compound and the second garnet-type compound are represented by Formula [1] Li.sub.7-(3x+y)M1.sub.xLa.sub.3Zr.sub.2-yM2.sub.yO.sub.12, where M1 is Al or Ga, M2 is Nb or Ta, the first garnet-type compound satisfies 0≤(3x+y)≤0.5, and the second garnet-type compound satisfies 0.5<(3x+y)≤1.5.

A refractory object may include a zircon body that is intentionally doped with a dopant including an alkaline earth element and aluminum. The refractory object can have an improved creep deformation rate. In an embodiment, the refractory object can have a creep deformation rate of not greater than about 1.8 E-5 h.sup.−1 at a temperature of 1350° C. and a stress of 2 MPa. In another embodiment, the zircon body may include an amorphous phase including an alkaline earth metal element.

Embodiments of synthetic garnet materials having advantageous properties, especially for below resonance frequency applications, are disclosed herein. In particular, embodiments of the synthetic garnet materials can have high Curie temperatures and dielectric constants while maintaining low magnetization. These materials can be incorporated into isolators and circulators, such as for use in telecommunication base stations.

Disclosed are an anti-corrosion and anti-coking ceramic coating with easy state identification for a coal-fired boiler and a preparation method thereof. The ceramic coating is formed by compounding a bottom coating layer and a surface coating layer, wherein the bottom coating layer is prepared from raw materials comprising sodium silicate, lanthanum oxide, niobium pentoxide, aluminum oxide, bismuth oxide, boron oxide, zinc oxide, silicon oxide, titanium dioxide, nano whisker, titanium nitride, and graphite fluoride, and the surface coating layer is prepared from raw materials comprising sodium silicate, lanthanum oxide, niobium pentoxide, chromium oxide, aluminum oxide, bismuth oxide, boron oxide, zinc oxide, silicon oxide, graphite fluoride, titanium nitride, silicon carbide, nano whisker, and cobalt green. An operating state of the ceramic coating is rapidly identified by a color difference between the bottom coating layer and the surface coating layer, which is beneficial to efficient maintenance of the ceramic coating during inspection.

A sintered composite ceramic includes a lithium-garnet major phase; and a lithium dendrite growth inhibitor minor phase, such that the lithium dendrite growth inhibitor minor phase comprises lithium tungstate. A method includes sintering a metal oxide component and a garnet component at a temperature in a range of 750° C. to 1500° C. to form a sintered composite ceramic.

A ceramic powder material containing a garnet-type compound containing Li, wherein the ceramic powder material has a pore volume of 0.4 mL/g or more and 1.0 mL/g or less.

A stacked structure including: a single crystal substrate and, single crystal material on the single crystal substrate, wherein the single crystal material has a same crystallographic orientation as a crystallographic orientation of the single crystal substrate. Also a method of forming the stacked structure, a ceramic electronic component, and a device.