Patent classifications
C04B2235/3275
Dielectric Ceramic Composition and Ceramic Capacitor Using the Same
The present invention discloses a dielectric ceramic formula enabling one to obtain a multilayer ceramic capacitor by alternatively stacking the ceramic dielectric layers and base metal internal electrodes. The dielectric ceramic composition comprises a primary ingredient:
[(Na.sub.1-xK.sub.x).sub.sA.sub.1-s].sub.m[(Nb.sub.1-yTa.sub.y).sub.uB1.sub.vB2.sub.w)]O.sub.3
wherein:
A is at least one selected from the alkaline-earth element group of Mg, Ca, Sr, and Ba;
B1 is at least one selected from the group of Ti, Zr, Hf and Sn;
B2 is at least one selected from transition metal elements;
and wherein:
x, y, s, u, v, and w are molar fractions of respective elements, and m is the molar ratio of [(Na.sub.1-xK.sub.x).sub.sA.sub.1-s] and [(Nb.sub.1-yTa.sub.y).sub.uB1.sub.vB2.sub.w)]. They are in the following respective range:
0.93≤m≤1.07;
0.7≤s≤1.0;
0.00≤x≤0.05; 0.00≤y≤0.65;
0.7≤u≤1.0; 0.0≤v≤0.3; 0.001≤w≤0.100;
a first sub-component composes of at least one selected from the rare-earth compound,
wherein the rare-earth element is no more than 10 mol % parts with respect to the main component; and
a second sub-component composes a compound with low melting temperature to assist the ceramic sintering process, said frit, which is Li free and could be at least one selected from fluorides, silicates, borides, and oxides. The content of frit is within the range of 0.01 mol % to 15.00 mol % parts with respect to the main component.
Sintered MnZn ferrite body
A sintered MnZn ferrite body containing main components comprising 53.30-53.80% by mol of Fe calculated as Fe.sub.2O.sub.3, 6.90-9.50% by mol Zn calculated as ZnO, and the balance of Mn calculated as MnO, and sub-components comprising 0.003-0.020 parts by mass of Si calculated as SiO.sub.2, more than 0 parts and 0.35 parts or less by mass of Ca calculated as CaCO.sub.3, 0.30-0.50 parts by mass of Co calculated as Co.sub.3O.sub.4, 0.03-0.10 parts by mass of Zr calculated as ZrO.sub.2, and 0-0.05 parts by mass of Ta calculated as Ta.sub.2O.sub.5, pre 100 parts by mass in total of the main components (calculated as the oxides), and having an average crystal grain size of 3 μm or more and less than 8 μm and a density of 4.65 g/cm.sup.3 or more.
METHOD FOR MANUFACTURING CERAMIC ARTICLE AND CERAMIC ARTICLE
(i) a step of disposing a powder that includes an absorber absorbing light of a wavelength included in a laser beam to be irradiated and silicon dioxide as a main component; (ii) a step of sintering or melting and solidifying the powder by irradiating the powder with a laser beam; and (iii) a step of heat-treating a shaped object formed by repeating the steps (i) and (ii) at 1470° C. or more and less than 1730° C.
Lithium composite oxide sintered body plate
Provided is a lithium complex oxide sintered plate for use in a positive electrode of a lithium secondary battery. The lithium complex oxide sintered plate has a structure in which a plurality of primary grains having a layered rock-salt structure are bonded, and has a porosity of 3 to 40%, a mean pore diameter of 15 μm or less, an open porosity of 70% or more, and a thickness of 15 to 200 μm. The plurality of primary grains has a primary grain diameter, i.e., a mean diameter of the primary grains, of 20 μm or less and a mean tilt angle of more than 0° to 30° or less. The mean tilt angle is a mean value of the angles defined by the (003) planes of the primary grains and the plate face of the lithium complex oxide sintered plate.
Lithium titanate sintered plate
Provided is a lithium titanate sintered plate for use in a negative electrode of a lithium secondary battery. The lithium titanate sintered plate has a structure in which a plurality of primary grains are bonded, and has: a thickness of 10 to 290 μm; a primary grain diameter of 0.70 μm or less, the primary grain diameter being a mean grain diameter of the primary grains; a porosity of 21 to 45%; an open pore rate of 60% or more; a mean pore aspect ratio of 1.15 or more; a ratio of 30% or more of pores having an aspect ratio of 1.30 or more to all the pores; and a mean pore diameter of 0.70 μm or less, wherein volume-based D10 and D90 pore diameters satisfy the relationship: 4.0≤D90/D10≤50.
Magnetic materials with ultrahigh resistivity intergrain nanoparticles
A composite magnetic material has a plurality of grains having a magnetic ferrite phase, grain boundaries surrounding the grains, and a plurality of nanoparticles disposed at the grain boundaries. The nanoparticles of the composite material are both magnetic and electrically insulating, having a magnetic flux density of greater than about 100 mT and an electrical resistivity of at least about 10.sup.8 Ohm-cm. Also provided is a method of making the composite material. The material is useful for making inductor cores of electronic devices.
Dielectric ceramic composition and multilayer ceramic capacitor comprising the same
A dielectric ceramic composition and a multilayer ceramic capacitor comprising the same includes a barium titanate (BaTiO.sub.3)-based base material main ingredient and an accessory ingredient, and the accessory ingredient includes a third trivalent lanthanide rare earth element A and terbium (Tb) as rare earth elements, and a molar ratio (Tb/A) of a content of terbium (Tb) to the content of the trivalent lanthanide rare earth element A satisfies 0.15≤Tb/A<0.50.
Ferrite sintered magnet, motor and generator
A ferrite sintered magnet contains a main phase formed of ferrite having a hexagonal magnetoplumbite type crystalline structure; a first subphase containing La, Ca, and Fe, in which an atomic ratio of La is higher than that of the main phase, and the atomic ratio of La is higher than an atomic ratio of Ca; and a second subphase containing La, Ca, Si, B, and Fe, in which an atomic ratio of Ca is higher than an atomic ratio of La, an atomic ratio of B is higher than an atomic ratio of Fe, and the atomic ratio of Fe is lower than that of the main phase. An area ratio of the second subphase on a cross-sectional surface of the ferrite sintered magnet is greater than or equal to 1%.
ELECTROCHEMICAL CELLS FOR HYDROGEN GAS PRODUCTION AND ELECTRICITY GENERATION, AND RELATED STRUCTURES, APPARATUSES, SYSTEMS, AND METHODS
An electrochemical cell comprises a first electrode, a second electrode, and a proton-conducting membrane between the first electrode and the second electrode. The first electrode comprises a layered perovskite having the general formula: DAB.sub.2O.sub.5+δ, wherein D consists of two or more lanthanide elements; A consists of one or more of Sr and Ba; B consists of one or more of Co, Fe, Ni, Cu, Zn, Mn, Cr, and Nd; and δ is an oxygen deficit. The second electrode comprises a cermet material including at least one metal and at least one perovskite. Related structures, apparatuses, systems, and methods are also described.
All solid battery, manufacturing method of the same and solid electrolyte paste
An all solid battery includes: a solid electrolyte layer including phosphoric acid salt-based solid electrolyte; a first electrode that is formed on a first main face of the solid electrolyte layer; and a second electrode that is formed on a second main face of the solid electrolyte layer, wherein a D50% grain diameter of crystal grains of the phosphoric acid salt-based solid electrolyte is 0.5 μm or less, wherein a D90% grain diameter of the crystal grains is 3 μm or less.