Polycrystalline cubic boron nitride compact include a body having sintered microcrystalline cubic boron nitride in a matrix of binder material. The microcrystalline cubic boron nitride particles have a size ranging from 2 microns to 50 microns. The particles of microcrystalline cubic boron nitride include a plurality of sub-grains, each sub-grain having a size ranging from 0.1 micron to 2 microns. The compacts are manufactured in a high pressure—high temperature (HPHT) sintering process. The compacts exhibit intergranular defect formation following introduction of wear. The sub-grains promote crack propagation based on micro-chipping rather than on a cleavage mechanism and, in sintered bodies, cracks propagate intergranularly rather than intragranularly, resulting in increased toughness and improved wear characteristics as compared to monocrystalline cubic boron nitride. The compacts are suitable for use as abrasive tools.

A surface-coated boron nitride sintered body tool is provided, in which at least a cutting edge portion includes a cubic boron nitride sintered body and a coating film formed on a surface of the cubic boron nitride sintered body. The coating film includes an A layer and a B layer. The A layer is formed of columnar crystals each having a particle size of 10 nm or more and 400 nm or less. The B layer is formed of columnar crystals each having a particle size of 5 nm or more and 70 nm or less. The B layer is formed by alternately stacking two or more compound layers having different compositions. The compound layers each have a thickness of 0.5 nm or more and 300 nm or less.

A cermet contains hard phase particles containing Ti and a binding phase containing at least one of Ni and Co, and 70% or more (by number) of the hard phase particles have a cored structure containing a core and a peripheral portion around the core. The core is composed mainly of at least one of Ti carbide, Ti nitride, and Ti carbonitride, and the peripheral portion is composed mainly of a Ti composite compound containing Ti and at least one selected from W, Mo, Ta, Nb, and Cr. The core has an average particle size α, the peripheral portion has an average particle size β, and α and β satisfy 1.1≦β/α≦1.7.

The invention relates to α/β-sialon-based materials. The invention particularly relates to α/β-sialon-based materials that have an improved sintering activity and impart high edge strength to the sintered molded articles made of said materials.

A cBN sintered body has 40%-85% cBN by volume and 15% to 60% binder phase by volume. and inevitable impurities. The binder phase has an Al compound including Al and at least one element selected from N, O and B, and a Zr compound including Zr and at least one element selected from C, N, O and B. The Zr compound includes ZrO, or ZrO and ZrO.sub.2. In an X-ray diffraction, where a peak intensity of a (111) plane of the ZrO is I.sub.1, a peak intensity of a (101) plane of tetragonal ZrO.sub.2 is I.sub.2t and a peak intensity of a (111) plane of cubic ZrO.sub.2 is I.sub.2c, a ratio of the intensity of I.sub.1 to total intensities of I.sub.1, I.sub.2t and I.sub.2c is 0.6-1.0, and an average grain size of the Al compound is 80 nm-300 nm.

Multi-step milling processes to prepare cBN composite powder forms a first powder mixture by adding a binder and a first cBN component, mills the first powder mixture for a first time period, combines a second cBN component with the milled first powder mixture to form a second powder mixture, and mills the second powder mixture for a second time period (less than the first time period) to form the cBN composite powder. A ratio of the D50 value of the second cBN component to the D50 value of the first cBN component is at least 3.0. Two-step milling with different milling times for the two cBN component fractions controls the amount of mill debris in the cBN composite powder mixture. Further processing of the cBN composite powder under HPHT conditions forms a cBN-based ceramic with an average value of a cBN particle free diameter of less than 2.0 microns.

Disclosed herein is a ceramic matrix composite comprising a preform comprising a plurality of plies; a ceramic matrix encompassing the plies and distributed through the plies; and thermally conducting particles distributed through the ceramic matrix. Disclosed herein is a method comprising distributing thermally conducting particles between plies in a preform; infiltrating chemical vapors of a ceramic precursor into the plies; and reacting the ceramic precursor to form a matrix.

The present invention provides a novel silicon carbide fiber reinforced silicon carbide composite material, which is a composite material of SiC fibers and SiC ceramics with improved toughness, that can be produced with high yield by a relatively simple production step without complex production steps such as a step of oxidation-resistant coating or an advanced interface control step.

The silicon carbide fiber reinforced silicon carbide composite material comprising a multiphase matrix containing a silicon carbide phase and a phase comprising a substance having low reactivity with respect to silicon carbide; and silicon carbide fibers disposed in the matrix can be obtained by a production step suitable for mass production. The composite material ensures greatly improved fracture toughness while maintaining the excellent properties of SiC ceramics.

A cubic boron nitride-based sintered material includes cubic boron nitride particles of 70 to 95 vol %, in which in a structure of a cross-section of the sintered material, a binder phase with a width of 1 nm to 30 nm is present between the adjacent cubic boron nitride particles, the binder phase being made of a compound containing at least Al, B, and N and having a ratio of an oxygen content to an Al content of 0.1 or less in terms of atomic ratio.

Disclosed herein are doped perovskite oxides. The doped perovskite oxides may be used as a cathode material in an electrochemical cell to electrochemically generate ammonia from N.sub.2. The doped perovskite oxides may be combined with nitride compounds, for instance iron nitride, to further increase the efficiency of the ammonia production.