A preceramic resin formulation comprising a polycarbosilane preceramic polymer, an organically modified silicon dioxide preceramic polymer, and, optionally, at least one filler. The preceramic resin formulation is formulated to exhibit a viscosity of from about 1,000 cP at about 25° C. to about 5,000 cP at a temperature of about 25° C. The at least one filler comprises first particles having an average mean diameter of less than about 1.0 μm and second particles having an average mean diameter of from about 1.5 μm to about 5 μm. Impregnated fibers comprising the preceramic resin formulation are also disclosed, as is a composite material comprising a reaction product of the polycarbosilane preceramic polymer, organically modified silicon dioxide preceramic polymer, and the at least one filler. Methods of forming a ceramic matrix composite are also disclosed.

Methods for preparing ceramic matrix composites using melt infiltration and chemical vapor infiltration are provided as well as the resulting ceramic matrix composites. The methods and products include the incorporation of sacrificial fibers to provide improved infiltration of the fluid infiltrant. The sacrificial fibers are removed, such as decomposed during pyrolysis, resulting in the formation of regular and elongate channels throughout the ceramic matrix composite. Infiltration of the fluid infiltrant can then take place using the elongate channels resulting in improved density and an improved ceramic matrix composite product.

A method of forming a composite component. The method includes laying up a plurality of composite plies to form a composite ply core. Another step of the method includes partially processing the composite ply core to form a green state core. The method further includes machining a cooling cavity on an exterior surface of the green state core. Additionally, the method includes inserting a filler material within the cooling cavity. A further step includes wrapping composite plies around the green state core and filler material to secure the filler material and form an outer enclosure. In one step, the method includes processing the green state core and outer enclosure to form the composite component.

A method of making an ceramic article according to an exemplary embodiment of this disclosure, among other possible things includes arranging fiber plies into a preform, inserting one or more sacrificial springs to the preform, infiltrating the preform with a matrix material to form an article, and thermally degrading the one or more sacrificial springs to form cooling holes. A ceramic article and a gas turbine engine component are also disclosed.

A method of producing a ceramic matrix composite component. The method includes positioning a first plurality of ceramic matrix composite plies on top of one another, disposing a filler pack on the first plurality of ceramic matrix composite plies, and positioning a second plurality of ceramic matrix composite plies on top of the filler pack. One of the first plurality of ceramic composite plies or the second plurality of ceramic composite plies includes a bend angle, to define an interstice between the plurality of ceramic matrix composite plies with the filler pack disposed in the interstice. The filler pack includes one or more sacrificial fibers disposed therein, that subsequent to removal provide a functional feature, such as a cooling manifold in the filler pack. The method further includes forming one or more channels coupled to the one or more functional features for the flow of a cooling fluid therethrough. A ceramic matrix composite is also disclosed.

A ceramic matrix composite (CMC) component and method of fabrication including a plurality of counterflow elongated functional features. The CMC component includes a plurality of longitudinally extending ceramic matrix composite plies forming a densified body and a plurality of elongated functional features formed therein the densified body. Each of the plurality of functional features is configured longitudinally extending and in alignment with the plurality of ceramic matrix composite plies. Each of the plurality of elongated functional features includes an inlet configured in cross-ply configuration. The plurality of elongated functional features are configured to provide a flow of fluid from a fluid source to an exterior of the ceramic matrix composite component. The plurality of functional features are configured in alternating flow configuration.

A foamed lightweight monolithic refractory castable is provided. The castable includes one or more refractory aggregates as a main constituent, one or more foaming additives in a range of 0.1 wt % to 3.0 wt %, one or more cellulosic powder air-entraining additives in a range of 0.005 wt % to 2.0 wt %, one or more binders in a range of 1 wt % to 40 wt %, and one or more superplasticizers in a range of 0.05 wt % to 0.5 wt %. The refractory aggregates include at least one of alumina and silica. The foaming additives include at least one of alkylbenzene sulfonates, alkene sulfonates, and hydroxylalkane sulfates. The superplasticizers include at least one of sodium polyacrylates, naphthalene sulfonates, polyethylene glycols, polycarboxylates, polyacrylates, and polycarboxylate ethers.

A ceramic matrix composite (CMC) is formed using a three-dimensional (3-D) woven preform by removing the set of sacrificial fibers from the 3-D woven preform and allowing a metal or metal alloy infiltrate the 3-D woven preform. The 3-D woven preform is formed by a method that includes providing a woven layer comprising a first set of ceramic fibers oriented in a first (x) direction woven with a second set of ceramic fibers oriented in a second (y) direction; stacking a plurality of woven layers on top of each other, said woven layers providing a two-dimensional (2-D) preform; weaving a set of sacrificial fibers in a third (z) direction with the 2-D preform, said weaving providing the 3-D woven preform; and shaping the 3-D woven preform into a predetermined shape.

Disclosed is a modified preceramic polymer having a polymer backbone consisting of silicon or a combination of silicon and carbon; and a pendant modifier bonded to the backbone wherein the modifier includes silicon, boron, aluminum, a transition metal, a refractory metal, or a combination thereof. The modified preceramic polymer can be used to form a ceramic matrix composite.

A composition which comprises a soluble or partially soluble phosphate, a refractory material and less than 1% of an oxide or hydroxide of magnesium or calcium. The composition may be mixed with water to form an investment casting slurry into which a wax pattern may be dipped. Slurry coated onto the pattern may be set by applying a stucco composition which comprises an oxide or hydroxide of magnesium or calcium. Coats of set slurry may be built up on the pattern to form an investment casting shell.