This invention provides resin formulations which may be used for 3D printing and pyrolyzing to produce a ceramic matrix composite. The resin formulations contain a solid-phase filler, to provide high thermal stability and mechanical strength (e.g., fracture toughness) in the final ceramic material. The invention provides direct, free-form 3D printing of a preceramic polymer loaded with a solid-phase filler, followed by converting the preceramic polymer to a 3D-printed ceramic matrix composite with potentially complex 3D shapes or in the form of large parts. Other variations provide active solid-phase functional additives as solid-phase fillers, to perform or enhance at least one chemical, physical, mechanical, or electrical function within the ceramic structure as it is being formed as well as in the final structure. Solid-phase functional additives actively improve the final ceramic structure through one or more changes actively induced by the additives during pyrolysis or other thermal treatment.

The present invention provides a method for producing a zirconia particle-containing powder that enables easy production of a zirconia sintered body having both high translucency and high strength. The present invention relates to a method for producing a zirconia particle-containing powder, comprising a drying step of spray drying a slurry containing zirconia particles, wherein the zirconia particles have an average primary particle diameter of 30 nm or less, and the slurry comprises a dispersion medium containing a liquid having a surface tension at 25° C. of 50 mN/m or less. Preferably, the zirconia particles comprise 2.0 to 9.0 mol % yttria. Preferably, wherein the content of the liquid in the dispersion medium is 50 mass % or more.

A ceramic electronic device includes a multilayer structure in which a plurality of dielectric layers and a plurality of internal electrode layers are alternately stacked. Each of the plurality of dielectric layers includes ceramic grains of a main component thereof expressed by (Ba.sub.1−x−yCa.sub.xSr.sub.y)(Ti.sub.1−zZr.sub.z)O.sub.3 (0<x≤0.2, 0≤y≤0.1, 0≤z≤0.1). D3<D1<D2 is satisfied when an average grain diameter of the ceramic grains of the main component of the plurality of dielectric layers in a section in which each two internal electrode layers is D1, an average grain diameter of the ceramic grains of the main component of first dielectric layers which are located at different height positions from the internal electrode layers is D2, an average grain diameter of the ceramic grains of the main component of second dielectric layers which are located at same height positions of the internal electrode layers is D3.

A surface-enhanced Raman scattering (SERS) substrate and its method of formation is disclosed. The surface-enhanced Raman scattering (SERS) substrate comprises a solid support, a first noble metal nanoparticles is disposed on the solid support, a porous oxide layer comprising transition metal oxide nanoparticles is disposed on the first noble metal nanoparticles and a second noble metal nanoparticles is disposed on the porous oxide layer. The porous oxide layer prevents contact between the first noble metal nanoparticles and the second noble metal nanoparticles and has a mean pore size of 2 to 30 nm.

A solid electrolyte ceramic material that includes sintered solid electrolyte particles containing, at least, lithium (Li), lanthanum (La), bismuth (Bi), and oxygen (O), wherein the Bi is at a higher concentration in a vicinity of a grain boundary of the sintered solid electrolyte particles than in a grain interior of the sintered solid electrolyte particles.

A nanoparticle cluster reduction method yields a new composition of matter including a large percentage (e.g., 75% or higher percentage) of primary nanoparticles in the new composition of matter. The particle reduction method reduces the size of nanoparticle clusters in material of the new composition of matter, allows particle reduction of specific nanoparticle cluster sizes, and allows particle reduction to primary nanoparticles. This new composition of matter can include a high permittivity and high resistivity dielectric compound. This new composition of matter, according to certain examples, has high permittivity, high resistivity, and low leakage current. In certain examples, the new composition of matter constitutes a dielectric energy storage device that is a battery with very high energy density, high operating voltage per cell, and an extended battery life cycle. An example method can include a controlled gas evolution reaction to reduce the size of nanoparticle clusters.

An exemplary embodiment of the present disclosure provides a method for manufacturing a transparent ceramic material. The method comprises providing a compact comprising a metal oxide and, during sintering, exposing the compact to a vapor comprising one of or both fluorine ions and lithium ions to form a transparent ceramic material comprising at least 90% of a theoretical transparency.

A method for making ceramic composites via sintering a mixture of alumina and oil fly ash. The alumina is in the form of nanoparticles and/or microparticles. The oil fly ash may be treated with an acid prior to the sintering. The composite may comprise graphite carbon derived from oil fly ash dispersed in an alumina matrix. The density, mechanical performance (e.g. Vickers hardness, fracture toughness), and thermal properties (e.g. thermal expansion, thermal conductivity) of the ceramic composites prepared by the method are also specified.

The present disclosure provides a high-temperature nano-composite coating and a preparation method thereof, and a small bag flexible packaging coating. The high-temperature nano-composite coating provided by the present disclosure controls the fiber length. Moreover, high-temperature reinforcing filler and high-temperature expansion filler are introduced, to make the coating have ultra-high strength at high temperature without cracks caused by shrinkage at high-temperature. In addition, nanopowder, high-temperature skeleton filler and other additives are introduced to make the coating be uniform and stable and reach a slurry state similar to toothpaste. There is no precipitation and stratification during the placement process. Small packaging can be realized to facilitate construction and operation. Besides, the coating has a good bonding to furnace lining, and will not fall off from the furnace lining, thereby prolonging the service life of the furnace lining.

The present disclosure relates to a negative temperature coefficient product comprising an electrically conductive percolation network of printable NTC material as particles in a cross-linked dielectric polymer matrix and to a method of manufacturing thereof. The particles comprising a spinel phase, preferably a C-spinel phase, having a general formula M.sub.3O.sub.4 comprising at least a first metal M.sup.I that is manganese and second metal M.sup.II that is nickel. In addition the particles include a nickel oxide phase. The printable NTC material can be dispersed in a printable NTC ink comprising a dispersant, from which the NTC product, e.g. a thermistor, can be formed, e.g., after drying of the dispersant. During processing the ink is kept at a temperature below 300° C. Optionally, the spinel phase comprises a further metal M.sup.III. The weight fraction of nickel oxide with respect to the overall mass of the printable NTC material is preferably in a range between one and twenty weight percent.