An apparatus and method for producing a lower olefin-containing gas including propylene from CH.sub.4 and CO.sub.2 via CO and H.sub.2 with high activity and high selectivity. The apparatus is provided with: a synthetic gas production unit to which a gas containing CH.sub.4 and CO.sub.2 is supplied from a first supply unit, and which generates a synthetic gas containing CO and H.sub.2 while heating a first catalytic structure; a gas production unit to which the synthetic gas is supplied and which generates a lower olefin-containing gas including propylene while heating a second catalytic structure; and a detection unit which detects propylene discharged from the gas production unit, in which the first catalytic structure includes first supports having a porous structure and a first metal fine particle in the first supports, the first supports have a first channels, the first metal fine particle is present in the first channels, the second catalyst structure includes second supports having a porous structure and a second metal fine particle in the second supports, the second supports have a second channels, and a portion of the second channels have an average inner diameter of 0.95 nm or less.

An apparatus and method for producing a lower olefin-containing gas including propylene from CH.sub.4 and CO.sub.2 via CO and H.sub.2 with high activity and high selectivity. The apparatus is provided with: a synthetic gas production unit to which a gas containing CH.sub.4 and CO.sub.2 is supplied from a first supply unit, and which generates a synthetic gas containing CO and H.sub.2 while heating a first catalytic structure; a gas production unit to which the synthetic gas is supplied and which generates a lower olefin-containing gas including propylene while heating a second catalytic structure; and a detection unit which detects propylene discharged from the gas production unit, in which the first catalytic structure includes first supports having a porous structure and a first metal fine particle in the first supports, the first supports have a first channels, the first metal fine particle is present in the first channels, the second catalyst structure includes second supports having a porous structure and a second metal fine particle in the second supports, the second supports have a second channels, and a portion of the second channels have an average inner diameter of 0.95 nm or less.

The present disclosure relates to a reactor and a method of operation for an exothermal process being catalyzed by a catalytically active material receiving a reactant gas and providing a product gas, in which said exothermal process has a heat development having a potential for thermally degrading said catalytically active material, and which exothermal process operates at a temperature at which the reactants and at least 80% or all of the products are present as gases, said method comprising the steps of a) directing the reactant gas to a first zone of a material catalytically active in the exothermal process producing an first product gas, and b) directing the first product gas to a second zone of a material catalytically active in the exothermal process producing a product gas, with the option of fully or partially by-passing either said first zone or said second zone, while directing a non-condensing gas stream having a temperature at least 50° C. lower than the product gas to said by-passed zone, wherein the choice of by-passing said zone is made based on the time of operation or a process parameter reflecting the catalytic activity of the zone of catalytically active material which is not by-passed with the associated benefit of reducing the extent of thermal deactivation of the catalytically active material, and thus increasing the overall lifetime of the catalytically active material.

The present invention relates to a method for producing the activated catalyst for Fischer-Tropsch synthesis comprising: a first step of reducing a catalyst for Fischer-Tropsch synthesis; a second step of preparing liquid hydrocarbon in which a part or all of molecular oxygen is eliminated; and a third step of introducing the reduced catalyst prepared in the first step into the liquid hydrocarbon prepared in the second step while blocking its contact with air. Since the reduced catalyst used for Fischer-Tropsch synthesis is introduced into liquid hydrocarbon from which molecular oxygen is removed or coated by liquid hydrocarbon, the catalyst for Fischer-Tropsch synthesis activated based on the present invention maintains a high activity even if exposed to the air for a long time, thereby easily facilitating the long-term storage and long-distance transfer of the reduced catalyst.

Integrated systems are provided for the production of higher hydrocarbon compositions, for example liquid hydrocarbon compositions, from methane using an oxidative coupling of methane system to convert methane to ethylene, followed by conversion of ethylene to selectable higher hydrocarbon products. Integrated systems and processes are provided that process methane through to these higher hydrocarbon products.

In a broad form the present disclosure relates to a stabilized catalyst support comprising in oxide form; aluminum, zirconium, and one or more lanthanoid elements taken from the lanthanoid group of the periodic system characterized in that at least a part of the aluminum is present as transition alumina such as χ, κ, γ, δ, η, ρ and θ-alumina, characterized in the concentration of zirconium being at least 1.5 wt %, 5 wt % or 10 wt %, the concentration of lanthanoid being at least 0.5 wt %, 1.0 wt %, 2 wt % or 4 wt % and the combined concentration of zirconium and lanthanoid being at least 4 wt %, 7 wt % or 10 wt %, with the associated benefit of a support comprising transition alumina being a high surface area due to the small crystallites typical for transition alumina, and the benefit of the combined presence of oxides of zirconium and lanthanoid in the stated amounts being that at these levels these oxides stabilize the structure of the transition alumina.

The invention relates to a catalyst containing an active cobalt phase, deposited on a support comprising alumina, silica or silica-alumina, said support also containing a mixed oxide phase containing cobalt and/or nickel, said catalyst having been prepared by introducing at least one hydrocarbon organic compound of formula C.sub.xH.sub.y. The invention also relates to the use thereof in the field of Fischer-Tropsch synthesis processes.

The present disclosure relates to a power production system that is adapted to achieve high efficiency power production with carbon capture when using a solid or liquid hydrocarbon or carbonaceous fuel. More particularly, the solid or liquid fuel first is partially oxidized in a partial oxidation reactor that is configured to provide an output stream that is enriched in methane content. The resulting partially oxidized stream can be cooled, filtered, additionally cooled, and then directed to a combustor of a power production system as the combustion fuel. The partially oxidized stream is combined with a compressed recycle CO.sub.2 stream and oxygen. The combustion stream is expanded across a turbine to produce power and passed through a recuperator heat exchanger. The recycle CO.sub.2 stream is compressed and passed through the recuperator heat exchanger and optionally the POX heat exchanger in a manner useful to provide increased efficiency to the combined systems.

The invention relates to a method for converting a gas into methane (CH.sub.4) which includes: a step of activating a catalytic material including praseodymium oxide (Pr.sub.6O.sub.11) associated with nickel oxide (NiO) and alumina (Al.sub.2O.sub.3), the respective proportions of which are, relative to the total mass of these three compounds: Pr.sub.6O.sub.11: 1 wt % to 20 wt %, NiO: 1 wt % to 20 wt %, and Al.sub.2O.sub.3: 60 to 98 wt %; and a step of passing a gas including at least one carbon monoxide (CO) over the activated catalytic material.

The invention relates to a method for converting a gas into methane (CH.sub.4) which includes: a step of activating a catalytic material including praseodymium oxide (Pr.sub.6O.sub.11) associated with nickel oxide (NiO) and alumina (Al.sub.2O.sub.3), the respective proportions of which are, relative to the total mass of these three compounds: Pr.sub.6O.sub.11: 1 wt % to 20 wt %, NiO: 1 wt % to 20 wt %, and Al.sub.2O.sub.3: 60 to 98 wt %; and a step of passing a gas including at least one carbon monoxide (CO) over the activated catalytic material.