Patent classifications
C07C2/24
p-XYLENE PRODUCTION METHOD
A method for producing p-xylene, comprising: a dimerization step of bringing a first raw material comprising isobutene into contact with a dimerization catalyst comprising at least one selected from the group consisting of Group 9 metal elements and Group 10 metal elements to generate C8 components comprising 2,5-dimethylhexene; and a cyclization step of bringing a second raw material comprising the C8 components into contact with a dehydrogenation catalyst to generate p-xylene by the cyclodehydrogenation reaction of the C8 components.
Phosphate-promoted nickel catalyst for high temperature oligomerization
An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500° C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170° C. to 360° C.
Phosphate-promoted nickel catalyst for high temperature oligomerization
An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500° C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170° C. to 360° C.
Phosphate-promoted nickel catalyst for high temperature oligomerization
An oligomerization catalyst, oligomer products, methods for making and using same. The catalyst can include a supported nickel phosphate compound. The catalyst is stable at oligomerization temperatures of 500° C. or higher and particularly useful for making oligomer products containing C4 to C26 olefins having a boiling point in the range of 170° C. to 360° C.
NICKEL-BASED MICROPOROUS AND MESOPOROUS CATALYSTS FOR SELECTIVE OLEFIN OLIGOMERIZATION
A novel catalyst composition and its use in the oligomerization reaction converting a portion of a C.sub.2 to C.sub.5+ alkene feed stream to C.sub.4 to C.sub.6+ olefin derivatives. The catalyst comprises a Group VIII noble metal selected from the group consisting of nickel, iron, cobalt, and combinations thereof, on a support. The support can be silica, silicon dioxide, titanium dioxide, metal modified silica, silica-pillared clays, silica-pillared micas, metal oxide modified silica-pillared mica, silica-pillared tetrasilicic mica, silica-pillared taeniolite, zeolite, molecular sieve, and combinations thereof. The catalyst composition is an active and selective catalyst for the catalytic oligomerization of alkenes to olefins and olefin derivatives.
NICKEL-BASED MICROPOROUS AND MESOPOROUS CATALYSTS FOR SELECTIVE OLEFIN OLIGOMERIZATION
A novel catalyst composition and its use in the oligomerization reaction converting a portion of a C.sub.2 to C.sub.5+ alkene feed stream to C.sub.4 to C.sub.6+ olefin derivatives. The catalyst comprises a Group VIII noble metal selected from the group consisting of nickel, iron, cobalt, and combinations thereof, on a support. The support can be silica, silicon dioxide, titanium dioxide, metal modified silica, silica-pillared clays, silica-pillared micas, metal oxide modified silica-pillared mica, silica-pillared tetrasilicic mica, silica-pillared taeniolite, zeolite, molecular sieve, and combinations thereof. The catalyst composition is an active and selective catalyst for the catalytic oligomerization of alkenes to olefins and olefin derivatives.
METHOD FOR PRODUCING POROUS MOLDED BODY, METHOD FOR PRODUCING CATALYST FOR alpha-OLEFIN DIMERIZATION, METHOD FOR PRODUCING alpha-OLEFIN DIMER, POROUS MOLDED BODY, AND CATALYST FOR alpha-OLEFIN DIMERIZATION
Provided is a method of producing a porous molded body, the method including: the step of obtaining a molded body by molding a raw material that contains from 1 part by mass to 100 parts by mass of a bicarbonate compound (A) represented by AHCO.sub.3 (wherein, A represents Na or K) and from 0 parts by mass to 99 parts by mass of a compound (B) represented by B.sub.nX (wherein, B represents Na or K; X represents CO.sub.3, SO.sub.4, SiO.sub.3, F, Cl, or Br; and n represents an integer of 1 or 2 as determined by the valence of X) (provided that a total amount of (A) and (B) is 100 parts by mass); and the step of obtaining a porous molded body by performing a heat treatment of the molded body in a temperature range of from 100 C. to 500 C. and an atmosphere that contains water vapor in an amount of from 1.0 g/m.sup.3 to 750,000 g/m.sup.3 and thereby thermally decomposing not less than 90% by mass of the bicarbonate compound (A).
METHOD FOR PRODUCING POROUS MOLDED BODY, METHOD FOR PRODUCING CATALYST FOR alpha-OLEFIN DIMERIZATION, METHOD FOR PRODUCING alpha-OLEFIN DIMER, POROUS MOLDED BODY, AND CATALYST FOR alpha-OLEFIN DIMERIZATION
Provided is a method of producing a porous molded body, the method including: the step of obtaining a molded body by molding a raw material that contains from 1 part by mass to 100 parts by mass of a bicarbonate compound (A) represented by AHCO.sub.3 (wherein, A represents Na or K) and from 0 parts by mass to 99 parts by mass of a compound (B) represented by B.sub.nX (wherein, B represents Na or K; X represents CO.sub.3, SO.sub.4, SiO.sub.3, F, Cl, or Br; and n represents an integer of 1 or 2 as determined by the valence of X) (provided that a total amount of (A) and (B) is 100 parts by mass); and the step of obtaining a porous molded body by performing a heat treatment of the molded body in a temperature range of from 100 C. to 500 C. and an atmosphere that contains water vapor in an amount of from 1.0 g/m.sup.3 to 750,000 g/m.sup.3 and thereby thermally decomposing not less than 90% by mass of the bicarbonate compound (A).
Oligomerization of ethylene
Provided is a method for oligomerization of ethylene, and more particularly, a method for producing 1-hexene and 1-octene at a high selectivity under an ethylene atmosphere by inducing a remarkably improved catalytic activity while effectively reducing a production amount of polyethylene by introducing the oligomerization catalyst and a cocatalyst mixture containing at least two aluminums together and adjusting the kind of oligomerization catalyst and injection conditions thereof.
Oligomerization of ethylene
Provided is a method for oligomerization of ethylene, and more particularly, a method for producing 1-hexene and 1-octene at a high selectivity under an ethylene atmosphere by inducing a remarkably improved catalytic activity while effectively reducing a production amount of polyethylene by introducing the oligomerization catalyst and a cocatalyst mixture containing at least two aluminums together and adjusting the kind of oligomerization catalyst and injection conditions thereof.