C07C5/2775

High meso-surface area and high acid site density pentasil zeolite for use in xylene conversion

A process for the production of para-xylene is presented. The process includes the isomerization of C8 aromatics to para-xylene utilizing a new catalyst. The new catalyst and designated as UZM-54 is represented by the empirical composition in the as synthesized and anhydrous basis expressed by the empirical formula of:
M.sub.m.sup.n+R.sub.1 r1.sup.p.sub.1.sup.+R.sub.2 r2.sup.p.sub.2.sup.+Al.sub.1-xE.sub.xSi.sub.yO.sub.z
where M is an alkali, alkaline earth, or rare earth metal such as sodium and/or potassium, R.sub.1 and R.sub.2 are organoammonium cation and E is a framework element such as gallium, iron, boron, or indium. UZM-54 are characterized by unique x-ray diffraction patterns, high meso surface area, low Si/Al ratios.

CATALYST COMPRISING AN IZM-2 ZEOLITE WITH AN OPTIMIZED Si/Al MOLAR RATIO, FOR THE ISOMERIZATION OF C8 AROMATIC CUTS
20180029957 · 2018-02-01 · ·

A catalyst is described comprising at least one IZM-2 zeolite containing silicon atoms and aluminium atoms, at least one matrix and at least one metal from group VIII of the periodic classification of the elements, the zeolite having a ratio between the number of moles of silicon and the number of moles of aluminium in the range 60 to 150. Said catalyst is used in a process for the isomerization of an aromatic feed comprising at least one compound containing eight carbon atoms per molecule.

Methods for producing crystalline microporous solids with a new CIT-7 topology and compositions derived from the same

This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having CIT-7 topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation structuring agents.

Methods for producing crystalline microporous solids with the HEU topology and compositions derived from the same

This disclosure relates to new crystalline microporous solids (including silicate- and aluminosilicate-based solids), the compositions comprising 8 and 10 membered inorganic rings, particularly those having HEU topologies having a range of Si:Al ratios, methods of preparing these and known crystalline microporous solids using certain quaternized imidazolium cation structuring agents.

Process for the manufacture of diesel range hydrocarbons

The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400 C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1.

Method of preparing an activated EU-2 zeolite

Disclosed herein is a method of making activated EU-2 zeolite, including: pores having a diameter of 30 to 40 while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 , wherein the volume of the pores having a diameter of 30 to 40 is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 is 0.07 to 0.4 cc/g.

METHOD OF PREPARING AN ACTIVATED EU-2 ZEOLITE

Disclosed herein is a method of making activated EU-2 zeolite, including: pores having a diameter of 30 to 40 while maintaining the crystal structure of the EU-2 zeolite; and pores having a diameter of 40 to 200 , wherein the volume of the pores having a diameter of 30 to 40 is 0.01 to 0.06 cc/g, and the volume of the pores having a diameter of 40 to 200 is 0.07 to 0.4 cc/g.

ZEOLITES FOR HYDROCARBON CONVERSION

A process is provided for the conversion of a hydrocarbon feedstock using catalyst system comprising one or more zeolites. The zeolites have been identified to be capable of selectively catalyzing the hydroisomerization reactions of linear or slightly branched long-chain hydrocarbons. Also provided is a method for the systematic discovery of zeolite framework types that are suitable for such conversion processes, according to a set of criteria: large affinity towards linear alkanes, high adsorption selectivity of linear over branched alkanes, and low adsorption selectivity of linear alkanes of different molecular weights.

PROCESS FOR THE PRODUCTION OF HIGH-PURITY PARAXYLENE FROM A XYLENES CUT, USING TWO SIMULATED MOVING BED SEPARATION UNITS OPERATING IN SERIES AND TWO ISOMERIZATION UNITS.

The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units.

PROCESS FOR THE PRODUCTION OF HIGH-PURITY PARAXYLENE FROM A XYLENES CUT, USING TWO SIMULATED MOVING BED SEPARATION UNITS OPERATING IN SERIES AND TWO ISOMERIZATION UNITS.

The present invention describes a process for the production of high-purity paraxylene from a xylenes cut capable of containing ethylbenzene and C9 compounds, said process using two simulated moving bed separation units operating in series and two isomerization units.