C07C5/2775

METHOD FOR ISOMERISING DEHYDRATION OF A NON-LINEAR PRIMARY MONOALCOHOL ON A QUADRILOBED IRON ZEOLITE CATALYST

A method for isomeris ng dehydration in the presence of a specific catalyst, to produce at least one alkene, carried out on a feedstock containing a non-linear primary monoalcohol, where the catalyst includes a zeolite having a series of 8MR channels and a binder having certain pore volume, which catalyst is multilobe-shaped and has characteristics including certain average mesopore volume Vm, and mesopores having a certain diameter, an average certain macropore volume VM, the macropores having a certain diameter, and certain average micropore volume V, the micropores having a certain diameter, and the catalyst has a certain exposed geometric area.

Process for recovering para-xylene

Para-xylene is separated from a mixture of xylenes and ethylbenzene by a separation process. An ortho-selective adsorbent is used to reduce the ortho-xylene concentration of the xylenes, prior to contact of the xylenes and ethylbenzene with a para-selective adsorbent. The stream rich in ortho-xylene may be isomerized in the liquid phase to increase the amount of para-xylene therein. The para-xylene-depleted stream may be treated in the vapor phase to remove the ethylbenzene and then subjected to isomerization in the liquid phase to produce a stream having a higher than equilibrium amount of para-xylene.

Process for preparing a catalyst based on IZM-2 from a solution comprising specific precursors and use for the isomerization of paraffinic feedstocks
10906030 · 2021-02-02 · ·

The present invention relates to a process for preparing a difunctional catalyst using a zeolite IZM-2, a hydrogenating function and a matrix. The preparation process according to the invention simultaneously allows preferential localization of said hydrogenating function on the surface and/or in the microporosity of zeolite IZM-2 and homogeneous distribution of the hydrogenating function in the catalyst and preferably on zeolite IZM-2 by means of using an impregnation solution comprising specific noble metal precursors combined with the presence of ammonium salts, with a quite precise ratio of ammonium salt to noble metal.

Catalyst composition comprising modified crystalline aluminosilicate for dehydration

Process for preparing a catalyst composition containing a modified crystalline aluminosilicate and a binder, wherein the catalyst composition comprises from 5 to 95% by weight of crystalline aluminosilicate as based on the total weight of the catalyst composition, the process being remarkable in that it comprises a step of steaming said crystalline aluminosilicate: at a temperature ranging from 100 C. to 380 C.; under a gas phase atmosphere containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H.sub.2O ranging from 2 to 200 bars; and said steaming being performed during at least 30 min and up to 144 h;
and in that the process also comprises a step of shaping, or of extruding, the crystalline aluminosilicate with a binder, wherein the binder is selected to comprise at least 85 wt % of silica as based on the total weight of the binder, and less than 1000 ppm by weight as based on the total weight of the binder of aluminium, gallium, boron, iron and/or chromium.

Catalyst composition comprising modified crystalline aluminosilicate for dehydration

Process for preparing a catalyst composition containing a modified crystalline aluminosilicate and a binder, wherein the catalyst composition comprises from 5 to 95% by weight of crystalline aluminosilicate as based on the total weight of the catalyst composition, the process being remarkable in that it comprises a step of steaming said crystalline aluminosilicate: at a temperature ranging from 100 C. to 380 C.; under a gas phase atmosphere containing from 5 wt % to 100 wt % of steam; at a pressure ranging from 2 to 200 bars; at a partial pressure of H.sub.2O ranging from 2 to 200 bars; and said steaming being performed during at least 30 min and up to 144 h;
and in that the process also comprises a step of shaping, or of extruding, the crystalline aluminosilicate with a binder, wherein the binder is selected to comprise at least 85 wt % of silica as based on the total weight of the binder, and less than 1000 ppm by weight as based on the total weight of the binder of aluminium, gallium, boron, iron and/or chromium.

Catalyst for Ethylbenzene Conversion in a Xylene Isomerization Process
20210001312 · 2021-01-07 ·

The present invention relates to a method for converting a feed mixture comprising an aromatic C8 mixture of xylenes and ethylbenzene in which the para-xylene content of the xylene portion of the feed is less than equilibrium to produce a product mixture of reduced ethylbenzene content and a greater amount of para-xylene, which method comprises contacting the feed mixture at conversion conditions with a first catalyst having activity for the conversion of ethylbenzene, and with a second catalyst having activity for the isomerization of a xylene.

PROCESS FOR THE MANUFACTURE OF DIESEL RANGE HYDROCARBONS

The invention relates to a process for the manufacture of diesel range hydrocarbons wherein a feed is hydrotreated in a hydrotreating step and isomerised in an isomerisation step, and a feed comprising fresh feed containing more than 5 wt % of free fatty acids and at least one diluting agent is hydrotreated at a reaction temperature of 200-400 C., in a hydrotreating reactor in the presence of catalyst, and the ratio of the diluting agent/fresh feed is 5-30:1.

Isomerization and catalytic activation of pentane-enriched hydrocarbon mixtures

Processes for producing liquid transportation fuels by converting a hydrocarbon feed stream comprising both isopentane and n-pentane. The hydrocarbon feed stream is separated into a first fraction that predominantly comprises isopentane and a second fraction that predominantly comprises n-pentane and some C6 paraffins. The first fraction is catalytically activated to an activation effluent comprising olefins and aromatics, while the second fraction is isomerized to convert at least a portion of the n-pentane to isopentane, then combined with the hydrocarbon feed stream to allow the newly-produced isopentane to be separated into the first fraction. The process yields products that are suitable for use as a blend component of liquid transportation fuels.

Liquid phase isomerization process integration

Processes and apparatuses for producing a C.sub.8 aromatic isomer product are provided. The process comprises introducing a reformate stream comprising aromatic hydrocarbons to a reformate splitter column to provide a plurality of streams. One or more streams comprising at least one stream from the plurality of streams is passed to a reformate upgrading unit to obtain an upgraded reformate stream. The upgraded reformate stream is passed to an aromatics stripper column to provide an aromatics stripper sidedraw stream comprising C.sub.8 aromatic hydrocarbons. The aromatics stripper sidedraw stream is passed to a xylene separation unit to provide the C.sub.8 aromatic isomer product and a raffinate product stream. At least a portion of the raffinate product stream is processed in a liquid phase isomerization unit to obtain an isomerized stream.

Liquid phase isomerization process integration

Processes and apparatuses for producing a C.sub.8 aromatic isomer product are provided. The process comprises introducing a reformate stream comprising aromatic hydrocarbons to a reformate splitter column to provide a plurality of streams. One or more streams comprising at least one stream from the plurality of streams is passed to a reformate upgrading unit to obtain an upgraded reformate stream. The upgraded reformate stream is passed to an aromatics stripper column to provide an aromatics stripper sidedraw stream comprising C.sub.8 aromatic hydrocarbons. The aromatics stripper sidedraw stream is passed to a xylene separation unit to provide the C.sub.8 aromatic isomer product and a raffinate product stream. At least a portion of the raffinate product stream is processed in a liquid phase isomerization unit to obtain an isomerized stream.