The present disclosure relates to a new catalytic process for the production of methanol from carbon dioxide, comprising: (1) the conversion of carbon dioxide and hydrogen to formic acid or formate salts; (2) converting the formic acid or formate salts to diformate esters of diols; (3) hydrogenating the diformate esters to methanol and diols. The diols produced from the hydrogenation reaction can be recovered and re-used to prepare the diformate esters.

The invention provides a compound of chemical formula (1), a precursor compound for producing the compound, a surfactant composition and a detergent composition including the compound,

##STR00001##

wherein R.sup.1 and R.sup.2 are each an aliphatic hydrocarbon group, X is a single bond or a hydrocarbon group having 1 or more and 5 or less carbon atoms, a total number of carbon atoms of R.sup.1, R.sup.2, and X is 2 or more and 39 or less, A.sup.1 is O(-A.sup.11O).sub.l-H, A.sup.2 is OCH.sub.2CH(O(-A.sup.21O).sub.m-H)(CH.sub.2O(-A.sup.22O).sub.n-H) or OCH(CH.sub.2O(-A.sup.23O).sub.s-H)(CH.sub.2O(-A.sup.24O).sub.t-H), A.sup.11, A.sup.21, A.sup.22, A.sup.23, and A.sup.24 are each independently an alkanediyl group having 2 or more and 8 or less carbon atoms, l, m, n, s, and t are an average value and are each independently 0 or more, and a total of l, m, and n, and a total of l, s, and t are each independently more than 0 and 200 or less.

The present disclosure relates to a new catalytic process for the production of methanol from carbon dioxide, comprising: (1) the conversion of carbon dioxide and hydrogen to formic acid or formate salts; (2) converting the formic acid or formate salts to diformate esters of diols; (3) hydrogenating the diformate esters to methanol and diols. The diols produced from the hydrogenation reaction can be recovered and re-used to prepare the diformate esters.

The present disclosure relates to a new catalytic process for the production of methanol from carbon dioxide, comprising: (1) the conversion of carbon dioxide and hydrogen to formic acid or formate salts; (2) converting the formic acid or formate salts to diformate esters of diols; (3) hydrogenating the diformate esters to methanol and diols. The diols produced from the hydrogenation reaction can be recovered and re-used to prepare the diformate esters.

A foam control agent and method of controlling foam for bioethanol processing by use of a foam control agent, wherein the agent comprises at least a (poly)glycerol ether.

A foam control agent and method of controlling foam for bioethanol processing by use of a foam control agent, wherein the agent comprises at least a (poly)glycerol ether.

A wetting agent according to Formula (I): ##STR00001## wherein R.sup.1 is selected from a branched alkyl group or linear alkyl group or a cycloaliphatic group or an aromatic group, each having 6 to 15 carbon atoms; R.sup.2 is selected from hydrogen, methyl, or ethyl; R.sup.3 is selected from hydrogen, methyl, or ethyl; R.sup.4 is selected from hydrogen, methyl, or ethyl; R.sup.5 is selected from methyl or ethyl; x ranges from 0 to 5; y ranges from 0 to 10; z ranges from 1 to 10; with the proviso that when x ranges from 1 to 5, R.sup.2 is different from R.sup.3; and with the proviso that when x=0, R.sup.3 is different from R.sup.4. The wetting agent also imparts anti-foam properties to aqueous solutions while reducing surface tension.

A wetting agent according to Formula (I): ##STR00001## wherein R.sup.1 is selected from a branched alkyl group or linear alkyl group or a cycloaliphatic group or an aromatic group, each having 6 to 15 carbon atoms; R.sup.2 is selected from hydrogen, methyl, or ethyl; R.sup.3 is selected from hydrogen, methyl, or ethyl; R.sup.4 is selected from hydrogen, methyl, or ethyl; R.sup.5 is selected from methyl or ethyl; x ranges from 0 to 5; y ranges from 0 to 10; z ranges from 1 to 10; with the proviso that when x ranges from 1 to 5, R.sup.2 is different from R.sup.3; and with the proviso that when x=0, R.sup.3 is different from R.sup.4. The wetting agent also imparts anti-foam properties to aqueous solutions while reducing surface tension.

The disclosure discloses a dendritic polyethylene glycol derivative and a preparation method and an application thereof. The dendritic polyethylene glycol derivative has a structure of formula (I), has multiple end functional groups, has a stronger water solubility in comparison with linear-chain polyethylene glycol, and can solve a problem of insufficient water solubility due to the increase of load when modifying an insoluble drug by the polyethylene glycol. The preparation method of the dendritic polyethylene glycol derivative provided by the disclosure has mild reaction conditions, is green and environmentally friendly, is low in cost, and is easy to implement industrialization. ##STR00001##

The disclosure discloses a dendritic polyethylene glycol derivative and a preparation method and an application thereof. The dendritic polyethylene glycol derivative has a structure of formula (I), has multiple end functional groups, has a stronger water solubility in comparison with linear-chain polyethylene glycol, and can solve a problem of insufficient water solubility due to the increase of load when modifying an insoluble drug by the polyethylene glycol. The preparation method of the dendritic polyethylene glycol derivative provided by the disclosure has mild reaction conditions, is green and environmentally friendly, is low in cost, and is easy to implement industrialization. ##STR00001##