Patent classifications
C07C45/35
Catalyst for preparing acrolein and acrylic acid, and preparation method thereof
The present invention relates to a catalyst for preparing acrolein and acrylic acid, and a preparation method thereof. The catalyst according to the present invention can be uniformly packed in a reactor and the collapse of the catalyst can be minimized because it has excellent mechanical properties, and it can be stably used for a long period of time.
Catalyst for preparing acrolein and acrylic acid, and preparation method thereof
The present invention relates to a catalyst for preparing acrolein and acrylic acid, and a preparation method thereof. The catalyst according to the present invention can be uniformly packed in a reactor and the collapse of the catalyst can be minimized because it has excellent mechanical properties, and it can be stably used for a long period of time.
Catalyst for preparing acrolein and acrylic acid, and preparation method thereof
The present invention relates to a catalyst for preparing acrolein and acrylic acid, and a preparation method thereof. The catalyst according to the present invention can be uniformly packed in a reactor and the collapse of the catalyst can be minimized because it has excellent mechanical properties, and it can be stably used for a long period of time.
Restarting method
A method for producing at least one oxidation product selected from the group consisting of acrolein and acrylic acid is provided. This method can alleviate concerns about deterioration of a gas-phase oxidation catalyst and reaction runaway in a restart period after a shutdown, and can allow the reaction to proceed in a stable state. Using a fixed-bed reactor filled with a gas-phase oxidation catalyst, at least one source gas selected from the group consisting of propylene and acrolein is subjected to a gas-phase contact oxidation reaction while a heating medium is caused to contact with or circulate through the fixed-bed reactor and thereby to heat the fixed-bed reactor. The temperature of the heating medium when the load is maximum in the restart period after the shutdown is controlled to be lower than the temperature of the heating medium when the load is maximum in an initial start-up period.
Restarting method
A method for producing at least one oxidation product selected from the group consisting of acrolein and acrylic acid is provided. This method can alleviate concerns about deterioration of a gas-phase oxidation catalyst and reaction runaway in a restart period after a shutdown, and can allow the reaction to proceed in a stable state. Using a fixed-bed reactor filled with a gas-phase oxidation catalyst, at least one source gas selected from the group consisting of propylene and acrolein is subjected to a gas-phase contact oxidation reaction while a heating medium is caused to contact with or circulate through the fixed-bed reactor and thereby to heat the fixed-bed reactor. The temperature of the heating medium when the load is maximum in the restart period after the shutdown is controlled to be lower than the temperature of the heating medium when the load is maximum in an initial start-up period.
Restarting method
A method for producing at least one oxidation product selected from the group consisting of acrolein and acrylic acid is provided. This method can alleviate concerns about deterioration of a gas-phase oxidation catalyst and reaction runaway in a restart period after a shutdown, and can allow the reaction to proceed in a stable state. Using a fixed-bed reactor filled with a gas-phase oxidation catalyst, at least one source gas selected from the group consisting of propylene and acrolein is subjected to a gas-phase contact oxidation reaction while a heating medium is caused to contact with or circulate through the fixed-bed reactor and thereby to heat the fixed-bed reactor. The temperature of the heating medium when the load is maximum in the restart period after the shutdown is controlled to be lower than the temperature of the heating medium when the load is maximum in an initial start-up period.
PROCESS AND CATALYSTS FOR THE OXIDATION AND/OR AMMOXIDATION OF OLEFIN
Embodiments of the present disclosure describe a catalyst and/or a precatalyst, in particular a single site catalyst and/or a single site precatalyst, for the oxidation and/or ammoxidation of olefins to produce aldehydes and/or nitriles, methods of preparing a corresponding catalyst and/or precatalyst, in particular single site catalyst and/or single site precatalyst, and methods of using said catalyst and/or precatalyst, in particular said single site catalyst and/or single site precatalyst, to produce aldehydes and/or nitriles.
PROCESS AND CATALYSTS FOR THE OXIDATION AND/OR AMMOXIDATION OF OLEFIN
Embodiments of the present disclosure describe a catalyst and/or a precatalyst, in particular a single site catalyst and/or a single site precatalyst, for the oxidation and/or ammoxidation of olefins to produce aldehydes and/or nitriles, methods of preparing a corresponding catalyst and/or precatalyst, in particular single site catalyst and/or single site precatalyst, and methods of using said catalyst and/or precatalyst, in particular said single site catalyst and/or single site precatalyst, to produce aldehydes and/or nitriles.
PROCESS AND CATALYSTS FOR THE OXIDATION AND/OR AMMOXIDATION OF OLEFIN
Embodiments of the present disclosure describe a catalyst and/or a precatalyst, in particular a single site catalyst and/or a single site precatalyst, for the oxidation and/or ammoxidation of olefins to produce aldehydes and/or nitriles, methods of preparing a corresponding catalyst and/or precatalyst, in particular single site catalyst and/or single site precatalyst, and methods of using said catalyst and/or precatalyst, in particular said single site catalyst and/or single site precatalyst, to produce aldehydes and/or nitriles.
Multimetal oxide compositions comprising Mo, Bi, Fe and Cu
Multimetal oxide composition comprising Mo, Bi, Fe, Cu and one or more than one of the elements Co and Ni and use thereof.