Methods for regenerating a sulfur-contaminated catalyst are disclosed. Such methods may employ a step of washing the sulfur-contaminated catalyst with an aqueous solution containing an alkali metal, followed by contacting the washed catalyst with a halogen solution containing chlorine and fluorine.

Spent aromatization catalysts containing a transition metal and a catalyst support are selectively poisoned in the disclosed reforming methods, resulting in improvements in overall aromatics yield and selectivity.

The disclosure is for a process for producing propylene and hexene (along with ethylene, pentenes, product butenes, heptenes and octenes) by metathesis from butenes (iso-, 1- and cis and trans 2-) and pentenes and then aromatizing the hexenes (along with higher olefins, such as heptenes and octenes) to benzene (along with toluene, xylenes, ethylbenzene and styrene). Since the desired products of the metathesis reaction are propylene and hexene, the feed to the metathesis reaction has a molar ratio for 1-butene:2-butene which favors production of propylene and 3-hexene with the concentration of hexenes and higher olefins in the metathesis product being up to 30 mole %. An isomerization reactor may be used to obtain the desired molar ratio of 1-butene:2-butene for the feed composition into the metathesis reactor. After the metathesis reaction, of hexene and higher olefins are separated for aromatization to benzene and other aromatics.

Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, such as, for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprises the steps of contacting said feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline aluminosilicate having a constraint index in the range of 3 to 12, a Group 10 metal, and, optionally, a Group 11 metal, in combination with a Group 1 alkali metal and/or a Group 2 alkaline earth metal.

Methods for regenerating a sulfur-contaminated catalyst are disclosed. Such methods may employ a step of washing the sulfur-contaminated catalyst with an aqueous solution containing an alkali metal, followed by contacting the washed catalyst with a halogen solution containing chlorine and fluorine.

Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, including cyclopentadiene, and catalyst compositions for use in such process. The process comprises contacting the feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprises a microporous crystalline metallosilicate, a Group 10 metal or compound thereof, and a Group 11 metal or compound thereof.

A method for producing light aromatic hydrocarbons from C.sub.9.sup.+ aromatic hydrocarbons includes a step of contacting a C.sub.9.sup.+ aromatic hydrocarbon with a dealkylation catalyst comprising a KL zeolite, and platinum and a modifying metal supported thereon in the presence of hydrogen, to obtain a light aromatic hydrocarbon. The modifying metal is selected from the group consisting of Group IIA metals and rare earth metals. By using a Pt/KL catalyst comprising a specific modifying metal in the dealkylation reaction of C.sub.9.sup.+ aromatic hydrocarbons for producing light aromatic hydrocarbons, the method shows the advantages of high conversion rate of feedstock, high yield of light aromatic hydrocarbons, good reaction selectivity.

Methods for producing supported catalysts containing a transition metal and a bound zeolite base are disclosed. These methods employ a step of impregnating the bound zeolite base with the transition metal, fluorine, and high loadings of chlorine. The resultant high chlorine content supported catalysts have improved catalyst activity in aromatization reactions.

This invention relates to a process for converting acyclic C.sub.5 hydrocarbons to cyclopentadiene in a reactor system, wherein the process comprises: providing to the reaction system a feedstock comprising acyclic C.sub.5 hydrocarbons; providing to the reaction system a particulate material comprising a catalyst material; contacting the feedstock and the particulate material in at least one reaction zone under reaction conditions to convert at least a portion of the acyclic C.sub.5 hydrocarbons to a first effluent comprising cyclopentadiene; wherein the feedstock flows counter-current to a direction of a flow of the particulate material.

Disclosed is a process for the conversion of acyclic C.sub.5 feedstock to a product comprising cyclic C.sub.5 compounds, such as for example, cyclopentadiene, and catalyst compositions for use in such process. The process comprising the steps of contacting said feedstock and, optionally, hydrogen under acyclic C.sub.5 conversion conditions in the presence of a catalyst composition to form said product. The catalyst composition comprising a microporous crystalline ferrosilicate, a Group 10 metal, and, optionally, a Group 11 metal, in combination with an optional Group 1 alkali metal and/or an optional Group 2 alkaline earth metal.