C07F9/657154

Flame retarding agent, flame-retardant aqueous resin composition and flame-retardant urethane resin composition containing said flame-retarding agent, and use therefor

The present invention relates to a flame-retarding agent comprising a phosphoramidate compound represented by Formula (I): ##STR00001##
wherein R.sub.1 and R.sub.2 are each independently C.sub.1-3 alkyl, R.sub.11 and R.sub.12 are each independently C.sub.1-3 alkylene, R.sub.13 is C.sub.1-6 alkylene, B.sub.1 is hydrogen or C.sub.1-6 alkyl, and A is hydrogen or an organic group represented by Formula (Ia): ##STR00002##
wherein R.sub.3 and R.sub.4 are each independently C.sub.1-3 alkyl, R.sub.14 and R.sub.15 are each independently C.sub.1-3 alkylene, and B.sub.2 is hydrogen or C.sub.1-6 alkyl,
wherein when B.sub.1 is C.sub.1-6 alkyl, and A is hydrogen, B.sub.1 and R.sub.13-A, taken together with nitrogen to which they are attached, may form a non-aromatic nitrogen-containing heterocycle, and
wherein when B.sub.1 is C.sub.1-6 alkyl, A is an organic group represented by Formula (Ia), and B.sub.2 is C.sub.1-6 alkyl, B.sub.1 and B.sub.2, taken together with nitrogen to which they are attached and with R.sub.13, may form a non-aromatic nitrogen-containing heterocycle.

PROCESS FOR OLIGOMERIZATION

The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.

Catalytic Enantioselective Synthesis of 2-Aryl Chromenes and Related Phosphoramidite Ligands and Catalyst Compounds
20180099943 · 2018-04-12 ·

Methods to access 2-aryl chromene compounds via an asymmetric catalytic process.

Process for the asymmetric oxidation of organic compounds with peroxides in the presence of a chiral acid catalyst

The present invention relates to a process for the asymmetric oxidation of nucleophilic organic compounds, particularly metal-free, with peroxide compounds in the presence of a chiral Brnsted acid catalyst. In one detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral imidodiphosphate catalyst. In another detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral phosphoric acid catalyst.

CHROMIUM COMPLEX AND CATALYST THEREFROM

The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.

Bidentate diphosphoramidites with a piperazine group as ligands for hydroformylation

The invention relates to Rh, Ru, Co and Ir complexes comprising bidentate diphosphoramidites as ligands and to the use thereof as catalysts for the hydroformylation of olefins. The invention also relates to a process for preparing an aldehyde from an olefin using the complexes or ligands mentioned.

Bidentate diphosphoramidites with a homopiperazine group as ligands for hydroformylation

The invention relates to Rh, Ru, Co and Ir complexes comprising bidentate diphosphoramidites as ligands and to the use thereof as catalysts for the hydroformylation of olefins. The invention also relates to a process for preparing an aldehyde from an olefin using the complexes or ligands mentioned.

Catalytic enantioselective synthesis of 2-aryl chromenes and related phosphoramidite ligands and catalyst compounds
09840487 · 2017-12-12 · ·

Methods to access 2-aryl chromene compounds via an asymmetric catalytic process.

Catalytic Enantioselective Synthesis of 2-Aryl Chromenes and Related Phosphoramidite Ligands and Catalyst Compounds
20170217919 · 2017-08-03 ·

Methods to access 2-aryl chromene compounds via an asymmetric catalytic process.

BIDENTATE DIPHOSPHORAMIDITES WITH A PIPERAZINE GROUP AS LIGANDS FOR HYDROFORMYLATION

The invention relates to Rh, Ru, Co and Ir complexes comprising bidentate diphosphoramidites as ligands and to the use thereof as catalysts for the hydroformylation of olefins. The invention also relates to a process for preparing an aldehyde from an olefin using the complexes or ligands mentioned.