Disclosed herein are ethylene-based polymers generally characterized by a density from 0.89 to 0.93 g/cm.sup.3, a ratio of Mw/Mn from 3 to 6.5, a Mz from 200,000 to 650,000 g/mol, a CY-a parameter at 190 C. from 0.2 to 0.4, and a reverse short chain branching distribution. The ATREF profile of these polymers can have a high temperature peak from 92 to 102 C., and a low temperature peak from 18 to 36 C. less than that of the high temperature peak. These polymers can have comparable physical properties to that of a metallocene-catalyzed LLDPE, but with improved processability, shear thinning, and melt strength, and can be used in blown film and other end-use applications.

Methods for simultaneously determining the concentrations of transition metal compounds in solutions containing two or more transition metal compounds are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems.

Methods for simultaneously determining the concentrations of transition metal compounds in solutions containing two or more transition metal compounds are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems.

An object of the present invention is to provide a novel method of producing a nonpolar olefin polymer (e.g., a copolymer of a nonpolar olefin and a polar olefin). The present invention provides a method of producing a polar olefin polymer or copolymer, the method including the polymerization step of polymerizing a polar olefin monomer using, as a catalyst, a polymerization catalyst composition containing: 1) a metallocene complex represented by Formula (I), which contains a central metal M that is scandium (Sc) or yttrium (Y), a ligand Cp* containing a cyclopentadienyl derivative and being bound to the central metal, monoanionic ligands Q.sup.1 and Q.sup.2, and W neutral Lewis bases L wherein W is an integer of 0 to 3; and 2) an ionic compound composed of a non-coordinating anion and a cation.

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An object of the present invention is to provide a novel method of producing a nonpolar olefin polymer (e.g., a copolymer of a nonpolar olefin and a polar olefin). The present invention provides a method of producing a polar olefin polymer or copolymer, the method including the polymerization step of polymerizing a polar olefin monomer using, as a catalyst, a polymerization catalyst composition containing: 1) a metallocene complex represented by Formula (I), which contains a central metal M that is scandium (Sc) or yttrium (Y), a ligand Cp* containing a cyclopentadienyl derivative and being bound to the central metal, monoanionic ligands Q.sup.1 and Q.sup.2, and W neutral Lewis bases L wherein W is an integer of 0 to 3; and 2) an ionic compound composed of a non-coordinating anion and a cation.

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Methods to produce heterogeneous polyethylene granules, the method including: contacting first olefin monomers and second olefin monomers with a catalyst system in a single reaction zone to produce heterogeneous polyethylene granules and recovering the heterogeneous polyethylene granules; wherein the catalyst system includes a product of a combination including: one or more catalysts having a Group 3 through Group 12 metal atom or lanthanide metal atom; at least one activator; and optionally, one or more support material compositions; and wherein the heterogeneous polyethylene granules include a product of a combination of: a first portion comprising a first polyethylene including the first olefin monomers and the second olefin monomers; a second portion including a second polyethylene including the first monomers and the second monomers; and wherein the first polyethylene has a higher second monomer weight percent than the second polyethylene, are provided.

Methods to produce heterogeneous polyethylene granules, the method including: contacting first olefin monomers and second olefin monomers with a catalyst system in a single reaction zone to produce heterogeneous polyethylene granules and recovering the heterogeneous polyethylene granules; wherein the catalyst system includes a product of a combination including: one or more catalysts having a Group 3 through Group 12 metal atom or lanthanide metal atom; at least one activator; and optionally, one or more support material compositions; and wherein the heterogeneous polyethylene granules include a product of a combination of: a first portion comprising a first polyethylene including the first olefin monomers and the second olefin monomers; a second portion including a second polyethylene including the first monomers and the second monomers; and wherein the first polyethylene has a higher second monomer weight percent than the second polyethylene, are provided.

Methods for simultaneously determining the concentrations of transition metal compounds in solutions containing two or more transition metal compounds are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems.

Methods for simultaneously determining the concentrations of transition metal compounds in solutions containing two or more transition metal compounds are described. Polymerization reactor systems providing real-time monitoring and control of the concentrations of the transition metal components of a multicomponent catalyst system are disclosed, as well as methods for operating such polymerization reactor systems.

The invention relates to a process for transitioning from a first continuous polymerization reaction in a reactor, for example a gas-phase reactor conducted in the presence of a first catalyst to a second continuous polymerization reaction in the reactor conducted in the presence of a second catalyst, wherein the first and second catalysts are incompatible, the process comprising: (a) discontinuing the introduction of the first catalyst from a catalyst feeding system into a reactor and emptying the catalyst feeding system of the first catalyst; (b) introducing a first catalyst killer to the reactor to substantially deactivate the first catalyst in the reactor; (c) introducing a second catalyst killer to the catalyst feeding system to substantially deactivate the first catalyst in the catalyst feeding system; (d) introducing a second catalyst to the catalyst feeding system and (e) introducing the second catalyst to the reactor from the catalyst feeding system, wherein the second catalyst killer is the same as or different from the first catalyst killer.