The present invention relates to a photocurable acrylic resin which is a polymer of a monomer mixture including a crosslinkable monomer represented by [Formula 1]; a (meth)acrylic monomer including a photoinitiating functional group; and an alkyl (meth)acrylate-based monomer, and has a weight average molecular weight of 100,000 to 500,000, and a branch-type polymer structure, and an adhesive composition and an adhesive film including the same.

The present invention relates to a photocurable acrylic resin which is a polymer of a monomer mixture including a crosslinkable monomer represented by [Formula 1]; a (meth)acrylic monomer including a photoinitiating functional group; and an alkyl (meth)acrylate-based monomer, and has a weight average molecular weight of 100,000 to 500,000, and a branch-type polymer structure, and an adhesive composition and an adhesive film including the same.

Coating compositions or paint having a pigment blended with a polymer system including one or more latex polymers, wherein the polymer system contains an alkali-soluble resin having an acid value and molecular weight and provided in a preferably desired amount to demonstrate optimal performance characteristics of washability, stain resistance or scrubability without negatively impacting block resistance, especially when neutralized with a low-volatility base.

Coating compositions or paint having a pigment blended with a polymer system including one or more latex polymers, wherein the polymer system contains an alkali-soluble resin having an acid value and molecular weight and provided in a preferably desired amount to demonstrate optimal performance characteristics of washability, stain resistance or scrubability without negatively impacting block resistance, especially when neutralized with a low-volatility base.

An aqueous polymer dispersion is based on copolymers of alkyl (meth)acrylates having long side chains and unsaturated carboxylic acids. The aqueous polymer dispersion also contains at least one cosolvent and an emulsifier system containing at least one emulsifier from the group of sulfosuccinates.

First embodiment of a (meth)acrylic copolymer in the present invention includes following: a (meth)acrylic copolymer having at least one kind of constitutional unit selected from the group consisting of a constitutional unit (A1) having at least one kind of structure (I) selected from the group consisting of structures represented by the following formula (1), formula (2), or formula (3) and a constitutional unit (A2) having a triorganosilyloxycarbonyl group and a constitutional unit (B) derived from a macromonomer (b): ##STR00001## (where, X represents —O—, —S—, or —NR.sup.14—, R.sup.14 represents a hydrogen atom or an alkyl group, R.sup.1 and R.sup.2 each represent a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, R.sup.3 and R.sup.5 each represent an alkyl group having from 1 to 20 carbon atoms, a cycloalkyl group, or an aryl group, and R.sup.4 and R.sup.6 each represent an alkylene group having from 1 to 10 carbon atoms).

First embodiment of a (meth)acrylic copolymer in the present invention includes following: a (meth)acrylic copolymer having at least one kind of constitutional unit selected from the group consisting of a constitutional unit (A1) having at least one kind of structure (I) selected from the group consisting of structures represented by the following formula (1), formula (2), or formula (3) and a constitutional unit (A2) having a triorganosilyloxycarbonyl group and a constitutional unit (B) derived from a macromonomer (b): ##STR00001## (where, X represents —O—, —S—, or —NR.sup.14—, R.sup.14 represents a hydrogen atom or an alkyl group, R.sup.1 and R.sup.2 each represent a hydrogen atom or an alkyl group having from 1 to 10 carbon atoms, R.sup.3 and R.sup.5 each represent an alkyl group having from 1 to 20 carbon atoms, a cycloalkyl group, or an aryl group, and R.sup.4 and R.sup.6 each represent an alkylene group having from 1 to 10 carbon atoms).

The present invention discloses novel calibrants containing between 1 and 5 iodine atoms and methods of making them using linear polymers, hyperbranched polymers, and biological polymers (including but not limited to proteins and peptides.) Methods of using the calibrants are also disclosed, such as mass spectrometry. The novel calibrants disclosed herein have a more cost- and time-efficient synthesis than other calibrants.

The present invention discloses novel calibrants containing between 1 and 5 iodine atoms and methods of making them using linear polymers, hyperbranched polymers, and biological polymers (including but not limited to proteins and peptides.) Methods of using the calibrants are also disclosed, such as mass spectrometry. The novel calibrants disclosed herein have a more cost- and time-efficient synthesis than other calibrants.

A POSS modified polyacrylate fluorine-free waterproofing agent includes following components: 1-10 wt % of a functionalized POSS monomer, 2-20 wt % of methyl methacrylate, 3-26 wt % of butyl acrylate, 1-10 wt % of a long-chain acrylate monomer, 0.5-3.5 wt % of an initiator, 0.5-4 wt % of a reactive cationic emulsifier, and 50-80 wt % of deionized water. A method of preparing a POSS modified polyacrylate fluorine-free waterproofing agent is also disclosed.