A storage stable one component aqueous basecoat composition containing a melamine formaldehyde crosslinker and a resin having groups reactive to the melamine formaldehyde crosslinker under acid catalysis is provided. The basecoat composition is curable at a temperature of 110° C. or less when cured wet on wet with a solvent borne clear coat composition containing a polyisocyanate crosslinker. Also provided is a wet on wet two layer coating containing the one component aqueous basecoat and the solvent borne clear coat, a wet on wet three layer coating containing an aqueous primer, the one component aqueous basecoat and the solvent borne clear coat and a cured topcoat coating obtained by curing the wet on wet two layer coating.

This invention provides a method for forming a multilayer coating film, comprising applying a base paint (X) having a solids content ratio of 30 to 62 mass % to a substrate to form a base coating film having a cured film thickness of 6 to 45 μm; applying an effect pigment dispersion (Y) having a solids content ratio of 0.1 to 10 mass % to the base coating film to form an effect coating film having a cured film thickness of 0.1 to 5.0 μm; applying a two-component clear paint (Z) containing a hydroxy-containing resin and a polyisocyanate compound to the effect coating film to form a clear coating film; and heating the base coating film, the effect coating film, and the clear coating film to simultaneously cure these coating films; wherein the base paint (X) contains a polyurethane resin (A), an alcohol (B) containing 6 to 12 carbon atoms, and an organic solvent (C) having an HLB of 7 to 9, and the effect pigment dispersion (Y) contains water, a flake-effect pigment (P), a resin emulsion (Q), and cellulose nanofibers (R).

This invention provides a method for forming a multilayer coating film, comprising applying a base paint (X) having a solids content ratio of 30 to 62 mass % to a substrate to form a base coating film having a cured film thickness of 6 to 45 μm; applying an effect pigment dispersion (Y) having a solids content ratio of 0.1 to 10 mass % to the base coating film to form an effect coating film having a cured film thickness of 0.1 to 5.0 μm; applying a two-component clear paint (Z) containing a hydroxy-containing resin and a polyisocyanate compound to the effect coating film to form a clear coating film; and heating the base coating film, the effect coating film, and the clear coating film to simultaneously cure these coating films; wherein the base paint (X) contains a polyurethane resin (A), an alcohol (B) containing 6 to 12 carbon atoms, and an organic solvent (C) having an HLB of 7 to 9, and the effect pigment dispersion (Y) contains water, a flake-effect pigment (P), a resin emulsion (Q), and cellulose nanofibers (R).

Caprolactam-derived solvents for use as processing solvents and/or coalescing agents for polyurethane dispersions (PUDs). The caprolactam-derived solvents are suitable for processing solvents and coalescing agents in PUDs created through traditional PUD manufacturing processes or as coalescing agents in PUDs created through solvent-free PUD manufacturing processes. Blends of more than one caprolactam-derived solvent may be used as the processing solvent and/or coalescing agent.

Disclosed are (2,2-dimethyl-1,3-dioxolan-4-yl)methyl 2-bromo-2,2-difluoroacetate, a waterborne polyurethane, and preparation methods thereof. The (2,2-dimethyl-1,3-dioxolan-4-yl)methyl 2-bromo-2,2-difluoroacetate could be used as a modified monomer for preparing a waterborne polyurethane, and substituents at a C2 position of the (2,2-dimethyl-1,3-dioxolan-4-yl)methyl 2-bromo-2,2-difluoroacetate are two fluorine atoms and one bromine atom. When it is used for preparing the waterborne polyurethane, fluorine and bromine groups are introduced into the structure of the waterborne polyurethane, and the resultant waterborne polyurethane exhibits good moisture resistance and flame retardance.

A waterborne one-component coating composition capable of self-crosslinking and exhibiting a gloss and hardness improvement when cured that is similar to a solventborne two-component composition. The composition includes a urethane phase including a polyurethane polymer with at least polyester diol monomer units, polycarbonate diol monomer units, and ketone-functionalized diol monomer units. The composition may include an optional acrylic phase including an acrylic polymer having monomer units selected from one of alkyl (meth)acrylate monomer units, vinyl acetate monomer units, styrene monomer units, ketone-functional vinyl monomer units, or combinations thereof. The composition includes a hydrazine-functionalized crosslinking agent configured to crosslink one of the ketone-functionalized diol monomer units, the ketone-functional vinyl monomer units, or both. The composition further includes one or more tertiary amine reaction moderators or neutralizing agents.

Provided are a waterborne polyurethane emulsion for ultra-thin polyurethane condoms having a low modulus and a high strength, and a method for preparing the emulsion, wherein the waterborne polyurethane emulsion comprises 15 to 18 parts by mass of a macromolecular diol, 4 to 6 parts by mass of a diisocyanate, 0.6 to 0.9 parts by mass of a hydrophilic chain extender, 0.4 to 0.8 parts by mass of a small-molecule chain extender, and the like. The prepared waterborne polyurethane emulsion is characterized by a low modulus, a high strength, and high resilience.

The present invention relates to a novel polyurethane-based UV-curable composition, comprising a low-crystallinity polyurethane polymer, a multifunctional thiol compound, a multifunctional epoxy resin compound, a photobase generator, and an optional photosensitizer. Adhesive films, adhesive tapes, and bonded members with excellent initial bonding performance, die cutting performance, overlap strength and drop-resistance performance may be obtained by using the polyurethane-based UV-curable composition provided by the present invention.

Radiation curable aqueous compositions (I) with reduced photo-yellowing are provided. Said composition comprises water, at least one ethylenically unsaturated compound and at least one carboxylic acid hydrazide-containing compound (H) in an amount sufficient to reduce photo-yellowing. Materials of the invention have the advantage that they help to reduce photo-yellowing. They may have a beneficial effect on long term yellowing caused by weathering too. Compositions (I) of the invention allow a better quality control of products and materials just after cure. Materials of the invention can be used to make coatings, inks, paints, varnishes and adhesives and they are further suitable for the making of composites, gel coats, 3D-curing and the making of 3D-objects in general.

The use of an aqueous polyurethane dispersion adhesive is described for producing composite foils which are biodisintegratable at home compost conditions where at least two substrates are adhesive-bonded to one another with use of the polyurethane dispersion adhesive, where at least one of the substrates is a polymer foil which is biodisintegratable at home compost conditions. At least 60% by weight of the polyurethane is composed of diisocyanates, polyesterdiols, and at least one bifunctional carboxylic acid selected from dihydroxy carboxylic acids and diamino carboxylic acids, wherein the polyurethane has no melting point above 20° C. or wherein the polyurethane has a melting point above 20° C. with an enthalpy of fusion lower than 10 J/g, and wherein a film of the polyurethane adhesive is biodegradable at home compost conditions.