An impact resistant textile-supported garment, or component thereof, comprises a fabric layer, and (i) at least five non-interconnected impact resistant polyurethane segments upon an outer surface of the fabric layer, wherein at least two of the non-interconnected impact resistant polyurethane segments has a depth of at least 3 mm, preferably at least 4 mm, and wherein at least five of the plurality of non-interconnected segments have dimensions smaller than 1.75 cm × 1 cm × 1 cm; or (ii) at least one non-interconnected impact resistant polyurethane segment, wherein the at least one segment has a depth of at least 3 mm at its deepest part, and wherein the at least one segment is a hollow segment comprising one or more regions defined by an outer polyurethane perimeter, surrounding a region of fabric that is not covered by polyurethane.

A method for preparing polyisocyanurate and polyurethane foams by the use of a liquid siloxane nucleating additive, and a foam-forming composition for preparing foams with improved thermal insulation performance, comprising an isocyanate component, an isocyanate-reactive component, a blowing agent, and a liquid siloxane nucleating additive.

An isocyanate-reactive composition comprising (i) at least one isocyanate-reactive compound; and (ii) at least one T-shaped siloxane material at a predetermined amount; and a foam-forming composition for producing a polyurethane or polyisocyanurate foam comprising at least one isocyanate component and at least one isocyanate-reactive component; wherein the at least one isocyanate-reactive component is the above isocyanate-reactive composition.

A polyurethane insulation foam composition is disclosed herein. The polyurethane insulation foam comprises: (i) an isocyanate compound; (ii) an isocyanate reactive compound; (iii) water; (iv) a tertiary amine compound; (v) a hydrophilic carboxylic acid compound; (vi) a halogenated olefin compound; and (vii) optionally, other additives.

A reactive composition for making a PIR comprising foam at an isocyanate index of at least 120, said composition comprising at least an isocyanate composition comprising one or more isocyanate compounds, an isocyanate-reactive composition comprising one or more isocyanate-reactive compounds, at least one PIR promoting catalyst, at least one physical blowing agent with a lambda gas ≤12 mW/m.Math.K at 10° C., at least one CO.sub.2 scavenging compound selected from at least one epoxy compound, and optionally a catalyst promoting epoxy reaction with CO.sub.2 characterized in that the amount of isocyanate-reactive compounds in the reactive composition is at least 10 wt % calculated on the total weight of the reactive composition, or at least more than the amount of epoxy compounds and the molar amount of epoxy compounds in the reactive composition is at least 7.8 times higher than the molar amount of CO.sub.2 formed by the water present in the reactive composition after reaction with isocyanates.

The invention pertains generally to a process and a composition-of-matter for a shelf-stable open cell polyurethane HFO-blown two-component polyurethane foam composition having improved flame-retardant properties through the use of at least one organo-tin containing catalyst and at least one potassium containing catalyst; and at least one dimorpholino-based ether catalyst, a ratio of the at least one potassium-containing catalyst to the tin-containing catalyst being at least approximately 1.5:1.0, the at least one surfactant comprising a polydimethylsiloxane (PDMS) backbone and polyethylene oxide-co-propylene oxide (PEO-PPO) random copolymer grafts; and the added water comprises at least 8 weight percent of said B-side reactants, the polyurethane foam having a Class B rating with a flame spread between 25 and 75 inclusive and a smoke developed of under 450 using ASTM E 84 testing protocol.

A reaction system for forming a viscoelastic polyurethane foam includes an isocyanate component that has at least one isocyanate and an isocyanate-reactive component that is a mixture formed by adding at least a polyol component, an additive component, and a preformed aqueous polymer dispersion. The mixture includes, based on the total weight of the mixture, from 50.0 wt % to 99.8 wt % of a polyol component including at least one polyether polyol, from 0.1 wt % to 50.0 wt % of an additive component including at least one catalyst, and from 0.1 wt % to 6.0 wt % of a preformed aqueous polymer dispersion. The preformed aqueous polymer dispersion has a solids content from 10 wt % to 80 wt %, based on the total weight of the preformed aqueous polymer dispersion, and is one of an aqueous acid polymer dispersion or an aqueous acid modified polyolefin polymer dispersion in which the polyolefin is derived from at least one C.sub.2 to C.sub.20 alpha-olefin.

Disclosed is a thermoset, thermal insulating foams having desirable and unexpectedly low thermal conductivity, and to compositions, method and systems which use and/or are used to make such foams comprising: (a) providing thermosetting foam forming component and a blowing agent for forming predominantly closed cells in the foam, wherein the blowing agent comprises: (i) cis-1,1,1,4,4,4-hexafluoro-2-butene (HFO-1336mzzm(Z)) and cyclopentane, with the HFO-1336mzzm(Z) and cyclopentane in the blowing agent together comprising at least about 50% by weight of the total of all components in the blowing agent and (ii) the weight ratio of HFO-1336mzzm(Z) to cyclopentane in the blowing agent is from about 45:55 to less than 68:32 and (b) forming foam from said provided foamable composition.

The present invention relates to a selective process for producing polyurethane prepolymers, to the polyurethane prepolymers obtainable from this process, and also to a process for producing moisture-crosslinking silylated polymers, more particularly silane-functional hybrid polymers, and also to the use thereof in CASE sectors (coatings, adhesives, sealants and elastomers).

A one-pack moisture-curing composition of the present technology contains a preliminary composition, an adhesiveness-imparting agent containing a compound (A) and/or a compound (B), a first catalyst containing a compound (C) and/or dibutyltin bis(pentadione), and a second catalyst containing a dimorpholinodiethylether.