The invention relates to a multi-component composition for the manufacture of polyurethane/urea cementitious hybrid system, comprising at least one isocyanate component selected from the group consisting of monoisocyanate, polyisocyanate and NCO terminated prepolymer, at least one polyol, water, catalyst, at least one acidic additive, and hydraulic binder, wherein the acidic additive is at least one selected from the group consisting of Lewis acids, acid precursors and acidic buffers and is in an amount of 0.01 to 3 wt %, based on the total weight of the composition, to the preparation thereof, and to the use of the composition for the preparation of a flooring, waterproofing, screed, grouting, primer, wall paint, roofing or coating in construction applications.

Shaped flexible PU foam articles, preferably mattresses and/or cushions, may use a flexible polyurethane foam obtained by reaction of at least one polyol component and at least one isocyanate component in the presence of at least one blowing agent and one or more catalysts that catalyze the isocyanate-polyol and/or isocyanate-water reactions and/or isocyanate trimerization and further additives, wherein the additives include one or more organic esters.

Disclosed is a reaction mixture for the manufacturing of a polyurethane foam, which mixture can be obtained by reacting a polyfunctional isocyanate with an isocyanate-reactive compound, in the presence of a scavenger and at least one catalyst; and curing such reaction mixture enables providing a foam with reduced aldehyde emissions particularly useful in means of transport, such as interior part of cars.

This disclosure provides for new low density, open cell polyurethane (PUR) foams, which can be prepared using a combination of precursors and conditions, for example, an off-ratio A-side:B-side volume ratio (v:v) which includes a higher volume of A-side than the volume of B-side, an aromatic polyisocyanate component having an isocyanate functionality of from about 2.5 to about 3.0, and an Isocyanate Index of from about 20 percent to about 40 percent. Using the processes and precursors disclosed herein, polyurethane foams having a density of from about 0.25 lb/ft.sup.3 to about 0.45 lb/ft.sup.3 can be obtained.

A stable polyol pre-mix composition comprises a blowing agent, a polyol, a surfactant, and a catalyst composition comprising an oxygen-containing amine catalyst and a metallic salt. The oxygen-containing amine catalyst may be, for example, one or more of an alkanol amine, an ether amine, or a morpholine group-containing compound such as, for example, 2-(2-dimethylaminoethoxy)ethanol or N,N,N′-trimethylaminoethyl-ethanolamine. The metallic salt may be, for example, alkali earth carboxylates, alkali carboxylates, and carboxylates of metals selected form the group consisting of zinc (Zn), cobalt (Co), tin (Sn), cerium (Ce), lanthanum (La), aluminum (Al), vanadium (V), manganese (Mn), copper (Cu), nickel (Ni), iron (Fe), titanium (Ti), zirconium (Zr), chromium (Cr), scandium (Sc), calcium (Ca), magnesium (Mg), strontium (Sr), and barium (Ba)

Tertiary amine catalysts having isocyanate reactive groups capable of forming thermally stable covalent bonds able to withstand temperatures from 120° C. and higher and up to 250° C. are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60); b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25° C. to 90° C.); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.

Described herein is a process for producing a polyurethane foam including mixing (a) polyisocyanate, (b) polymeric compounds having isocyanate-reactive groups, (c) silicone-free stabilizer, (d) optionally chain extending and/or crosslinking agents, (e) catalysts, (f) blowing agents, and (g) optionally auxiliaries and additives to afford a reaction mixture and reacting the reaction mixture to afford the polyurethane foam. Also described herein are a polyol component including the silicone-free stabilizer (c), a polyurethane foam obtained by the process, and a method of using the polyurethane foam in enclosed spaces or in the interior of vehicles.

An isocyanate polymerization catalyst, a preparation method thereof and a method for preparing polyisocyanates comprising isocyanurate groups by using the same. The catalyst is a carboxylic acid salt containing a di-quaternary ammonium ion. The structure of the catalyst contains hydroxyl-containing aromatic heterocyclic residues. The catalyst is highly active. Only a small quantity of the catalyst is required for the polymerization of isocyanates. The prepared polyisocyanates have color values lower than 25 Hazen, monomer contents of less than 0.5% by weight, high contents of isocyanurates and low viscosities.

The present invention relates to a rigid polyurethane foam and use thereof in automotive interiors. The polyurethane foam is prepared from a reaction system comprising the reaction components of polyisocyanate, polyether polyol, catalyst and water, in which the catalyst is N,N-dimethyl-N′,N′-di(2-hydroxypropyl)-1,3-propanediamine. The rigid polyurethane foam according to the present invention has a desired low odor, while ensuring good physical properties, such as good mechanical strength and tensile strength.

Flexible polyurethane foams are made by reacting a polyether mixture and water with a polyisocyanate. The foams have excellent suite of properties for use in seating applications, as they are supporting, comfortable and resilient foam. A further advantage is these properties can be obtained at isocyanate indices of close to or even greater than 100.