The invention relates to a composition and to a process for preparing moisture-crosslinking polymers under catalysis by at least one metal-siloxane-silanol(ate) compound, and to the use of the composition in the CASE sector (coatings, adhesives, sealants and elastomers), especially in the field of adhesives and sealants.

A process for making a molded flexible foam. The processes includes: (a) depositing a foam-forming reaction mixture onto a surface of a mold cavity, and (b) allowing the foam-forming reaction mixture to react in the mold cavity. The foam-forming reaction mixture includes: (1) a polyisocyanate present in an amount of less than 45% by weight, based on the total weight of the reaction mixture; (2) an isocyanate-reactive composition; (3) a blowing agent; and (4) a catalyst. The isocyanate-reactive composition includes: (i) at least 50% by weight, based on the total weight of polyol in the isocyanate-reactive composition, of a polyether polyol having a functionality of greater than 2, an oxyethylene content of 0 to 50% by weight, based on the total weight of the polyether polyol, more than 50 mol % of primary OH groups and an OH number of 8 to 112 mg KOH/g; and (ii) a component comprising: (A) an amine-initiated polyether polyol (II), wherein amine-initiated polyether polyol (II) has an OH number of at least 500 mg KOH/g and a functionality of 2.5 to 4, and wherein amine-initiated polyether polyol (II) is present in an amount of greater than 0 and no more than 10% by weight, based on the total weight of polyol in the isocyanate-reactive composition; (B) a CO.sub.2-producing carbamic acid which is present in an amount of greater than 0 and no more than 10% by weight, based on the total weight of polyol in the isocyanate-reactive composition; or (C) both (A) and (B).

Processes for making a molded flexible foam. The processes include: (a) depositing a foam-forming reaction mixture onto a surface of a mold cavity, and (b) allowing the foam-forming reaction mixture to react in the mold cavity. The foam-forming reaction mixture comprises: (1) a polyisocyanate present in an amount of less than 45% by weight, based on the total weight of the foam-forming reaction mixture; (2) an isocyanate-reactive composition comprising at least 50% by weight, based on the total weight of polyol in the isocyanate-reactive composition, of a polyether polyol having a functionality of greater than 2, an oxyethylene content of 0 to 50% by weight, based on the total weight of the polyether polyol, more than 50 mol % of primary OH groups, and an OH number of 8 to 112 mg KOH/g; (3) a blowing agent comprising water present in an amount of at least 0.5% by weight, based on the total weight of the foam-forming reaction mixture; and (4) a tin-free metallic catalyst composition comprising a bismuth-based catalyst and a zinc-based catalyst.

The invention relates to a method for producing soft polyurethane foam obtained by reacting a composition containing a component A1 containing at least one filled polyol, a component A2 containing compounds reactive with isocyanates and having a hydroxyl value of ≥20 to <100 mg KOH/g, the component A2 not containing any filled polyol, a component A3 containing water and/or at least one physical blowing agent, a component A4 containing auxiliary agents and additives, and a component B containing di- and/or polyisocyanates, characterized in that the reaction occurs in the presence of 0.5 to 3 parts by weight of an organic urea derivative as component C, which is obtained by reacting urea with a difunctional amine having a number-average molecular weight of 200 to 1000 g/mol. The invention also relates to a soft polyurethane foam obtainable by the method.

The present invention relates to a process for preparing a mixed silane-terminated polymer by reacting a polyol component A) with a diisocyanate component B) comprising 1-isocyanato-3,3,5-trimethyl-5-isocyanatomethylcyclohexane (isophorone diisocyanate), at least one isocyanatosilane C) and an aminosilane E), in which the urethanization reaction is carried out in the presence of at least one catalyst D) which is free of organically bonded tin. The invention further relates to the use of the polymers thus obtained.

A process for preparing polyether-siloxane block copolymers by hydrosilylation of alpha,omega-modified hydrosiloxanes with alpha,omega-modified di(meth)allyl polyethers in the presence of a hydrosilylation catalyst, wherein the reaction is performed in a solvent mixture comprising aromatic solvents, polyethers and alkoxylated alcohol, is described.

A waterborne poly(alkynyl carbamate) prepolymer is provided which comprises a reaction product of a polyisocyanate comprising a first portion and a second portion of isocyanate groups; an isocyanate-reactive component comprising 0.1 mol % to 6 mol % of a C.sub.10-C.sub.50 glycol ether; and 99.9 mol % to 94 mol % of an alkynol, wherein the mol % is based on the moles of isocyanate in the polyisocyanate, wherein the first portion of isocyanate groups reacts with the C.sub.10-C.sub.50 glycol ether, wherein the second portion of isocyanate groups reacts with the alkynol, and wherein reaction occurs optionally in the presence of a catalyst. The reaction of long chain glycol ethers with the polyisocyanate at a level of from 0.1 mol % to 6 mol % imparts water dispersibility to the prepolymer, and when the prepolymer is dispersed in water, the performance of waterborne alternative polyurethane compositions made therefrom, such as coatings, adhesives, sealants, films, elastomers, castings, foams, and composites, are not compromised. The invention allows for the use of water as a carrier, thus eliminating the need for organic solvents.

The invention relates to an adhesive dual-component composition based on polyurethane, comprising an —NCO component and an —OH component such that: the —NCO component is a composition comprising A) at least one polyurethane prepolymer comprising at least two NCO terminal groups obtained by polyaddition reaction of at least one aliphatic polyisocyanate selected from aliphatic diisocyanate monomers and mixtures of at least one aliphatic diisocyanate monomer with at least one triisocyanate based on XDI, and at least one polyester diol, and B) at least one triisocyanate based on XDI; and the —OH component is a composition comprising at least one polyester polyol. The invention relates to a method for producing a multilayer structure implementing an adhesive composition according to the invention, as well as to the use of such a structure in the field of flexible packaging.

The present invention is directed to a powder coating composition including a hydroxy-functional polymer, a carbodiimide crosslinker, and an organometallic catalyst. The present invention is also directed to a substrate at least partially coated with the powder coating composition. The present invention is also directed to a method of applying a coating composition to a substrate including: applying the powder coating composition to a substrate and heating the powder coating composition to form a coating over the substrate.

Described herein is a process for producing a pipe insulated with polyurethane foam, where (a) isocyanates are mixed with (b) polyols, (c) blowing agent including at least one aliphatic, halogenated hydrocarbon compound (c1), made up of from 2 to 5 carbon atoms, at least one hydrogen atom and at least one fluorine and/or chlorine atom, where the compound (c1) includes at least one carbon-carbon double bond, (d) catalyst including N,N-dialkylbenzylamine, optionally (e) chain extenders and/or crosslinkers and optionally (f) auxiliaries and additives to give a reaction mixture, the reaction mixture is applied to a pipe for media and is allowed to cure to give the polyurethane foam. Also described herein is an insulated pipe obtained by such a process and a method of using such an insulated pipe as insulated composite wall pipe for district heating or district cooling networks laid in the ground.