Methods of coating a substrate are disclosed. The methods comprise applying shear force to a coating composition either before or during application of the coating composition to the substrate. The coating composition comprises a water-borne or solvent-borne film-forming resin and a catalyst associated with a carrier, wherein at least some of the catalyst can be released from the carrier upon application of the shear force. Also provided are coated articles prepared by the methods.

The present invention provides multilayer coated substrates, prepared using primer and/or sealer compositions comprising waterborne curable film-forming compositions, in turn comprising: a) an aqueous dispersion of a pigment and i) polymeric urethane-shell particles having a care-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell comprises a polyurethane or polyurethane-urea polymer; or ii) polymeric acrylic-shell particles having a core-shell morphology and having hydroxyl functional groups, wherein the core is prepared from a monomer mixture comprising hydrophobic, ethylenically unsaturated monomers and the shell is prepared from a monomer mixture comprising hydrophilic, ethylenically unsaturated monomers; b) a polyisocyanate crosslinking agent; and optionally c) a hydroxyl functional, water dispersible acrylic polymer.

A method of producing a polyurethane or polyisocyanurate foam is provided which involves the use of a specific combination of hydrofluoroolefin blowing agents and cell nucleators. The resulting foams have excellent long term thermal insulating performance and have reduced thickness in comparison to conventional thermal insulating boards. The rigid polyurethane and polyisocyanurate boards may be used to insulate refrigeration bodies, such as those employed in vehicles comprising refrigeration units, and cold storage containers.

A process for producing an object from a precursor comprises the steps of: I) depositing a free-radically crosslinked resin atop a carrier to obtain a ply of a construction material joined to the carrier which corresponds to a first selected cross section of the precursor; II) depositing a free-radically crosslinked resin atop a previously applied ply of the construction material to obtain a further ply of the construction material which corresponds to a further selected cross section of the precursor and which is joined to the previously applied ply; III) repeating step II) until the precursor is formed; IV) treating the precursor obtained after step III) under conditions sufficient to at least partially trimerize to isocyanurate groups NCO groups present in the free-radically crosslinked resin of the obtained precursor to obtain the object.

The invention relates to a non-aqueous coating composition comprising a. a polyisocyanate, b. a polyol having an average functionality of more than 3 hydroxyl groups per molecule, c. a metal based curing catalyst for the addition reaction of isocyanate groups and hydroxyl groups, and d. a mercapto carboxylic acid,
wherein the coating composition does not contain a carboxylic acid wherein the carbonyl group of the carboxylic acid is in conjugation with a π-electron system.

A composition comprising an isocyanate component A) comprising at least one cycloaliphatic or araliphatic diisocyanate, a polyol component B) comprising at least one polyol having an OH number of 80 to 1000 mg KOH/g, an additive component C) comprising at least one internal demoulding agent, and a catalyst component D) comprising at least one inorganic metal complex as thermally latent catalyst, characterized in that the thermally latent catalyst has a quotient of reaction rates between catalysed reaction and uncatalysed reaction at 30° C. of =5.0 and at 60° C. of =1.1. The present invention further provides a process for producing an elastomer and for the use of the composition for production of transparent shaped bodies.

A composition comprising an isocyanate component A) comprising at least one cycloaliphatic or araliphatic diisocyanate, a polyol component B) comprising at least one polyol having an OH number of 80 to 1000 mg KOH/g, an additive component C) comprising at least one internal demoulding agent, and a catalyst component D) comprising at least one inorganic metal complex as thermally latent catalyst, characterized in that the thermally latent catalyst has a quotient of reaction rates between catalysed reaction and uncatalysed reaction at 30° C. of =5.0 and at 60° C. of =1.1. The present invention further provides a process for producing an elastomer and for the use of the composition for production of transparent shaped bodies.

An aqueous polyurethane resin having a cationic group in a side chain thereof is obtainable by reacting a polyester polyol, a polyisocyanate, and a diol containing a quaternary N-atom or amino group, the quaternary N-atom or amino group being not present in the carbon chain between the two hydroxyl groups of the diol. The polyester polyol is obtained by reacting an aromatic polycarboxylic acid and a polyol. The polyurethane resin is suitable as a resin in treatment liquids for inkjet printing.

A method of forming a three-dimensional object, wherein said three-dimensional object is an insert for use between a helmet and a human body, is described. The method may use a polymerizable liquid, or resin, useful for the production by additive manufacturing of a three-dimensional object, comprising a mixture of (i) a light polymerizable liquid first component, and (ii) a second solidifiable component that is different from said first component.

A flexible gastight material for a landfill site includes a component A and a component B, the component A including: at least one of polypropylene glycol with a molecular weight of 600-4000, polytetrahydrofuran diol with a molecular weight of 1000-3000, polycaprolactone diol with a molecular weight of 1000-3000, and polycarbonate diol with a molecular weight of 1000-3000; and at least one of 2,4′-diphenylmethane diisocyanate, 4,4′-diphenylmethane diisocyanate, toluene diisocyanate, isophorone diisocyanate, and hexamethylene diisocyanate. The flexible gastight material for the landfill site provided in the present application has a micro-closed-cell foam structure. The closed-cell elastic structure of the flexible gastight material may block the volatilization of toxic and harmful odors, and may cut off the diffusion path of the odors by combining with gas treatment systems at the landfill site. The flexible gastight material has excellent water blocking and gas sealing performance.