Hydrophobic polyurethane polymers which may be useful in making synthetic leathers comprising at least two immediately consecutive repeating units according to Formula I:
(—OC(O)N—).sub.nA-NC(O)O-L(M)-  (I)
wherein n is 1 or 2, A represents the residue of an organic di- or tri-isocyanate compound, L represents a hydrocarbon group that optionally contains one or more catenary or non-catenary hetero-atoms, and M represents an oligomer comprising 2-12 (meth)acrylate units. The polyurethane polymers may additionally comprise end group(s) according to the formula -L′M wherein L′ represents a hydrocarbon group that may contain one or more catenary or non-catenary hetero-atoms. In some embodiments, M is according to Formula III: ##STR00001##
wherein Q is hydrogen or methyl, p is an integer between 2 and 12 inclusive, and Z is a hydrocarbon group which may optionally be substituted.

Hydrophobic polyurethane polymers which may be useful in making synthetic leathers comprising at least two immediately consecutive repeating units according to Formula I:
(—OC(O)N—).sub.nA-NC(O)O-L(M)-  (I)
wherein n is 1 or 2, A represents the residue of an organic di- or tri-isocyanate compound, L represents a hydrocarbon group that optionally contains one or more catenary or non-catenary hetero-atoms, and M represents an oligomer comprising 2-12 (meth)acrylate units. The polyurethane polymers may additionally comprise end group(s) according to the formula -L′M wherein L′ represents a hydrocarbon group that may contain one or more catenary or non-catenary hetero-atoms. In some embodiments, M is according to Formula III: ##STR00001##
wherein Q is hydrogen or methyl, p is an integer between 2 and 12 inclusive, and Z is a hydrocarbon group which may optionally be substituted.

The present disclosure relates to novel fluoromonomer and fluorooligomer compounds, a photopolymerizable composition including these compounds, methods for producing these compounds, and a hydrophobic film using the photopolymerizable composition.

A polishing pad includes a polyurethane, wherein the polyurethane includes a fluorinated repeating unit represented by Formula 1, wherein the number of defects on a substrate after polishing with the polishing pad and a fumed silica slurry is 40 or less;

##STR00001## wherein R.sub.11 and R.sub.12 are each independently selected from the group consisting of hydrogen, C.sub.1-C.sub.10 alkyl groups, and fluorine, with the proviso that at least one of R.sub.11 and R.sub.12 is fluorine, L is a C.sub.1-C.sub.5 alkylene group or O, R.sub.13 and R.sub.14 are each independently selected from the group consisting of hydrogen, C.sub.1-C.sub.10 alkyl groups, and fluorine, with the proviso that at least one of R.sub.13 and R.sub.14 is fluorine, and n and m are each independently an integer from 0 to 20, with the proviso that n and m are not simultaneously 0.

A polishing pad includes a polyurethane, wherein the polyurethane includes a fluorinated repeating unit represented by Formula 1, wherein the number of defects on a substrate after polishing with the polishing pad and a fumed silica slurry is 40 or less;

##STR00001## wherein R.sub.11 and R.sub.12 are each independently selected from the group consisting of hydrogen, C.sub.1-C.sub.10 alkyl groups, and fluorine, with the proviso that at least one of R.sub.11 and R.sub.12 is fluorine, L is a C.sub.1-C.sub.5 alkylene group or O, R.sub.13 and R.sub.14 are each independently selected from the group consisting of hydrogen, C.sub.1-C.sub.10 alkyl groups, and fluorine, with the proviso that at least one of R.sub.13 and R.sub.14 is fluorine, and n and m are each independently an integer from 0 to 20, with the proviso that n and m are not simultaneously 0.

Tumor resection is commonly practiced to prevent the progression of cancer. However, there are post-surgery concerns including the formation of a void that can allow cancer cells to escape at the surgery site, which increases the risk of metastasis. To counter this challenge, an embodiment includes a polyurethane-based shape memory foam as a tissue void-filling device that can also release anti-cancer drugs. Such foams may activate at body temperature and become malleable. Such properties may enable the foam to be shaped to precisely seal the tissue void and then serve as a drug-eluting device. Based on the drug composition with poly vinyl alcohol (PVA), the drug release profile from the foam may be altered depending on the application.

Disclosed are compositions that may be useful for forming synthetic membranes, methods of forming membranes therefrom, and membranes. In an embodiment, a membrane comprises a free hydrophilic polymer and a polyurethane, the polyurethane comprising a backbone comprising the reaction product of a diisocyanate, a polymeric aliphatic diol, and, optionally, a chain extender, wherein the backbone comprises a C.sub.2-C.sub.16 fluoroalkyl or C.sub.2-C.sub.16 fluoroalkyl ether, or the polyurethane comprises an endgroup comprising a C.sub.2-C.sub.16 fluoroalkyl or C.sub.2-C.sub.16 fluoroalkyl ether.

Disclosed are compositions that may be useful for forming synthetic membranes, methods of forming membranes therefrom, and membranes. In an embodiment, a membrane comprises a free hydrophilic polymer comprising a polyoxazoline, and a polyurethane, the polyurethane comprising a backbone comprising the reaction product of a diisocyanate, a polymeric aliphatic 5 diol, and optionally a chain extender.

A method forming a surface modifying composition with reduced need for organic solvent and evaporation thereof for removal of insoluble reaction byproducts from the composition. The purified composition can be used in the formation of articles having improved biocompatibility, such as medical articles (e.g., spun hollow fiber).

A method forming a surface modifying composition with reduced need for organic solvent and evaporation thereof for removal of insoluble reaction byproducts from the composition. The purified composition can be used in the formation of articles having improved biocompatibility, such as medical articles (e.g., spun hollow fiber).