This invention relates to moisture curable polyurethane adhesive compositions and more particularly to moisture curable polyurethane adhesive compositions having improved initial tack and moisture permeability when cured. In one embodiment the disclosed moisture curable polyurethane adhesive compositions are suited for use as hot melt adhesives for use in manufacturing textile, clothing and/or footwear articles.

This invention relates to moisture curable polyurethane adhesive compositions and more particularly to moisture curable polyurethane adhesive compositions having improved initial tack and moisture permeability when cured. In one embodiment the disclosed moisture curable polyurethane adhesive compositions are suited for use as hot melt adhesives for use in manufacturing textile, clothing and/or footwear articles.

Adhesive sealant composition comprising at least one moisture-crosslinkable prepolymer and, as plasticizing agent, an ester compound of formula (I): ##STR00001##
in which: R.sup.1, R.sup.2 and R.sup.3 represent an oxycarbonylalkyl radical of 4 to 20 carbon atoms; R.sup.4 represents a hydrogen atom, a methyl or ethyl radical or else a radical: —CH.sub.2—R.sup.5 in which R.sup.5 represents an oxycarbonylalkyl radical of 4 to 20 carbon atoms.

Adhesive sealant composition comprising at least one moisture-crosslinkable prepolymer and, as plasticizing agent, an ester compound of formula (I): ##STR00001##
in which: R.sup.1, R.sup.2 and R.sup.3 represent an oxycarbonylalkyl radical of 4 to 20 carbon atoms; R.sup.4 represents a hydrogen atom, a methyl or ethyl radical or else a radical: —CH.sub.2—R.sup.5 in which R.sup.5 represents an oxycarbonylalkyl radical of 4 to 20 carbon atoms.

A moisture-curable reactive hot-melt adhesive composition comprises: a urethane prepolymer having an isocyanate group, the urethane prepolymer being a reaction product of a polyol component comprising a polyester polyol, a polyether polyol and a polybutadiene polyol with an isocyanate component; and an antioxidant.

A moisture-curable reactive hot-melt adhesive composition comprises: a urethane prepolymer having an isocyanate group, the urethane prepolymer being a reaction product of a polyol component comprising a polyester polyol, a polyether polyol and a polybutadiene polyol with an isocyanate component; and an antioxidant.

A cold-stable NCO-containing prepolymer obtainable from the reaction of an isocyanate-reactive component comprising polyether carbonate polyols having an isocyanate component comprising methylene diphenyl diisocyanate (MDI) with high contents of 4,4′-MDI, a method for the preparation thereof, and the use thereof in one- or two-component systems for foams, elastomers, adhesives and sealants provided.

The present disclosure relates to a process of manufacturing a moisture-curable adhesive composition, wherein the process comprises the steps of: a) providing a multi-screw extruder comprising a reaction chamber; b) providing reactants and reagents comprising: i. at least one isocyanate; ii. at least one amine; and iii. optionally, at least one plasticizer; c) incorporating the reactants and reagents into the reaction chamber of the multi-screw extruder, thereby forming a reaction product comprising a urea derivative; and d) incorporating at least one moisture-curable prepolymer into the reaction product resulting from step c), thereby forming a moisture-curable adhesive composition. In another aspect, the present disclosure is directed to a moisture-curable adhesive composition obtainable by the process as described above.

The present disclosure relates to a process of manufacturing a moisture-curable adhesive composition, wherein the process comprises the steps of: a) providing a multi-screw extruder comprising a reaction chamber; b) providing reactants and reagents comprising: i. at least one isocyanate; ii. at least one amine; and iii. optionally, at least one plasticizer; c) incorporating the reactants and reagents into the reaction chamber of the multi-screw extruder, thereby forming a reaction product comprising a urea derivative; and d) incorporating at least one moisture-curable prepolymer into the reaction product resulting from step c), thereby forming a moisture-curable adhesive composition. In another aspect, the present disclosure is directed to a moisture-curable adhesive composition obtainable by the process as described above.

Specific hydroxysilanes of formula (I), a method for the production thereof, the use thereof as a constituent of moisture-curing compositions, and silane-functional compounds produced therefrom, in particular silane-functional polymers and isocyanatosilanes. The hydrosilanes can be produced in a simple process with a high degree of purity and are storage-stable after production. Production from the reaction of lactides with aminosilanes is particularly advantageous. Hydroxysilane of formula (I), where n is 1 or 2.