Patent classifications
C08G18/3203
Ultralow Monomer Polyurethanes
The present invention relates to ultralow monomer PU prepolymers containing free NCO groups obtainable from polyols, diisocyanates and NCO-reactive compounds, obtainable by reacting at least one polyol with at least one polyisocyanate, wherein the at least one polyisocyanate is used in molar excess relative to the hydroxyl groups of the at least one polyol to obtain a polyurethane prepolymer containing free isocyanate groups; and adding at least one compound having at least one H-acidic functional group to the polyurethane prepolymer containing free isocyanate groups in an amount such that the molar ratio of the free isocyanate groups to H-acidic functional groups (NCO:XH ratio) is 2 to 15, preferably 2.5 to 10, more preferably 3 to 8. Also encompassed are methods for its production, laminating adhesives containing said prepolymer, methods of bonding substrates and the use of the described adhesives for laminating two or more films.
ALKOXYSILANE- AND ALLOPHANATE-FUNCTIONALIZED COATING MATERIALS
An alkoxysilane-functionalized and allophanate-functionalized coating material including a) a binder component of 10-99 wt % of at least one reaction product of I. and II. wherein I includes A) at least one alkoxysilane-containing monourethane A) of the formula 1 R.sub.n(OR.sub.1).sub.3-nSi—R.sup.2—NH—(C═O)—OR.sup.3 wherein R, R.sup.1, R.sup.2 and R.sup.3 represent hydrocarbon radicals having 1-8 carbon atoms, and n represents 0-2, and B) at least one diisocyanate B), and II includes the subsequent reaction of C) with at least one diol and/or polyol C), in a ratio of NCO groups of reaction product I to OH groups of the diol and/or polyol II. C) of 1.0:1.5 to 1.0:0.6; b) 1-90 wt % of at least one further binder component distinct from a) a hydroxyl-containing or amino-containing binder component, c) 0-50 wt % of at least one polyisocyanate having an NCO functionality of at least 2, d) 0-5 wt % of at least one catalyst, wherein components a)-d) add up to 100 wt %.
Digestion of keratin
The present invention relates to the chemical digestion of keratin, such as avian feathers and wool. The digestion product is made by heating the feathers or wool with a solvent selected from glycols, alkanolamines, polyamines, and combinations thereof. The resulting digested keratin product is a keratin-derived polyol useful for making polymeric materials such as polyurethanes. The digestion products provide a sustainable alternative to petrochemical based intermediates.
ADHESIVE COMPOSITION AND LAMINATE
Provided is an adhesive which, in a metal foil-containing laminated composite film used in a high temperature sterilization treatment, is resistant to the effects of moisture in the air during curing, has good workability when used as a solvent-free adhesive, and exhibits excellent adhesive strength and acid resistance. Provided is a method for producing an adhesive composition, the method including: a step of obtaining an alcohol-added isocyanate (E) by reacting a trifunctional or higher isocyanate compound (C2) and a monofunctional alcohol (D) at an equivalence ratio of isocyanate groups in the trifunctional or higher isocyanate compound (C2):monofunctional alcohol (D)=100 mol %:25 to 65 mol %, and a step of mixing a polyisocyanate (A) containing a trifunctional or higher isocyanate compound (C1) and the alcohol-added isocyanate (E), and an alcohol (B) having an acid value of 0.5 to 30 mgKOH/g, so that the equivalence ratio between isocyanate groups in the polyisocyanate (A) and hydroxyl groups in the alcohol (B) (isocyanate groups/hydroxyl groups) is within a range from 0.7 to 2.5.
AQUEOUS PEPTIDE-STABILIZED POLYURETHANE DISPERSIONS
The present invention relates to aqueous peptide-stabilized polyurethane dispersions that can be used in various applications including adhesives and cosmetics, as they are surfactant and solvent free and have low VOC emissions. As hybrid materials, they provide for a versatile system that can be finely tuned and combine the advantageous properties of polyurethane and peptide materials. Also encompassed are processes for their production including dispersing an NCO-terminated polyurethane prepolymer into a continuous aqueous phase comprising one or more peptides, thereby forming peptide-stabilized polyurethane particles, compositions containing them and their use in cosmetics and adhesives.
ANTI-MICROBIAL ADDITIVE AND PROPERTIES TO FOAM TO PREVENT MOLD
A method for forming polyurethane foams for vehicle seat components in a molding apparatus is provided. The method includes a step of directing one or more polyol compositions into a mold. Each of the one or more polyol compositions includes a polyol, water, and a catalyst. The method also includes a step of directing an isocyanate composition into the mold, the isocyanate composition including one or more isocyanates. The one or more polyol compositions and the one or more isocyanates are combined into a reaction composition that forms a foamed vehicle seat component. Characteristically, the mold has a shape that defines a foamed vehicle seat component. Characteristically, either the one or more polyol compositions and/or the isocyanate composition includes a liquid antimicrobial agent that is a liquid at temperatures above 10° C.
BIO-BASED POLYOLS, ESTERS, AND SURFACTANTS
The present disclosure relates to methods for making polyols, esters, and surfactants. Generally, a carboxyl-containing molecule is reacted with an epoxide-containing molecule to obtain a hydroxylated ester. If multiple epoxide groups are present in the epoxide-containing molecule, the resulting molecule can also be considered a polyol. The hydroxyl groups can be further ethoxylated to obtain a surfactant/stabilizer.
SELF-REPAIRING POLYURETHANE RESIN MATERIAL, SELF-REPAIRING POLYURETHANE RESIN, SELF-REPAIRING COATING MATERIAL, SELF-REPAIRING ELASTOMER MATERIAL, METHOD FOR PRODUCING SELF-REPAIRING POLYURETHANE RESIN MATERIAL, AND METHOD FOR PRODUCING SELF-REPAIRING POLYURETHANE RESIN
In a self-repairing polyurethane resin material produced by reaction of pentamethylenediisocyanate with an active hydrogen group-containing compound, the active hydrogen group-containing compound contains a polyol compound having a number average molecular weight of 100 to 2000 and an average functionality of 2 to 3.
Polyurethanes, articles and coatings prepared therefrom and methods of making the same
The present invention provides polyurethanes including a reaction product of components including: (a) an isocyanate functional urethane prepolymer comprising a reaction product of components including: (i) about 1 equivalent of at least one polyisocyanate; and (ii) about 0.1 to about 0.5 equivalents of at least one diol having 2 to 18 carbon atoms; and (b) about 0.05 to about 0.9 equivalents of at least one branched polyol having 4 to 18 carbon atoms and at least 3 hydroxyl groups; and (c) up to about 0.9 equivalents of at least one polyol different from branched polyol (b) and having 2 to 18 carbon atoms, wherein the reaction product components are essentially free of polyester polyol and polyether polyol; compositions, coatings and articles made therefrom and methods of making the same.
Anti-staining resin, anti-staining fabric and fabricating method thereof
An anti-staining fabric includes a base cloth and an anti-staining resin. The anti-staining resin is disposed on the base cloth, in which a method of fabricating the anti-staining resin includes the following steps. A first thermal process is performed to mix a polyol, a cross-linking agent, and a choline to form a first mixture, in which a reaction temperature of the first thermal process is between 90° C. and 120° C. A second thermal process is performed to mix the first mixture and a chain extender to form the anti-staining resin, in which the chain extender includes a first reagent and a second reagent, and a reaction temperature of the second thermal process is between 120° C. and 150° C.