C08G18/3203

Production and use of new thermoplastic polyurethane elastomers based on polyether carbonate polyols

The invention relates to a method for producing a thermoplastic polyurethane elastomer based on polyether carbonate polyols. The method comprises a first step, in which at least A) an organic diisocyanate and B) a polyol having a number-average molecular weight Mn>=500 and <=5000 g/mol are reacted to form an isocyanate-terminated prepolymer. In a second step, the prepolymer is reacted with C) one or more chain extenders having a molecular weight>=60 and <=490 g/mol and optionally D) a monofunctional chain stopper or E) an organic diisocyanate, wherein optionally at least F) one catalyst is used in the first and/or second step.; The molar ratio of the sum of the isocyanate groups from A) and, if applicable, E) to the sum of the groups reactive to isocyanate in B), C), and, if applicable, D) is >=0.9:1 and <=12:1, and component B) contains at least one polyether carbonate polyol, which can be obtained by adding carbon dioxide and alkylene oxides to H-functional starter substances. The invention further relates to a thermoplastic polyurethane elastomer produced in accordance with the method according to the invention, the use of said thermoplastic polyurethane elastomer to produce extruded or injection molded items, and the items produced by extrusion or injection molding.

Production and use of new thermoplastic polyurethane elastomers based on polyether carbonate polyols

The invention relates to a method for producing a thermoplastic polyurethane elastomer based on polyether carbonate polyols. The method comprises a first step, in which at least A) an organic diisocyanate and B) a polyol having a number-average molecular weight Mn>=500 and <=5000 g/mol are reacted to form an isocyanate-terminated prepolymer. In a second step, the prepolymer is reacted with C) one or more chain extenders having a molecular weight>=60 and <=490 g/mol and optionally D) a monofunctional chain stopper or E) an organic diisocyanate, wherein optionally at least F) one catalyst is used in the first and/or second step.; The molar ratio of the sum of the isocyanate groups from A) and, if applicable, E) to the sum of the groups reactive to isocyanate in B), C), and, if applicable, D) is >=0.9:1 and <=12:1, and component B) contains at least one polyether carbonate polyol, which can be obtained by adding carbon dioxide and alkylene oxides to H-functional starter substances. The invention further relates to a thermoplastic polyurethane elastomer produced in accordance with the method according to the invention, the use of said thermoplastic polyurethane elastomer to produce extruded or injection molded items, and the items produced by extrusion or injection molding.

Polyurethanes

The present invention relates to a polyurethane which is the reaction product of a polyisocyanate and polyester, wherein said polyester is formed from a dimer fatty acid, a C.sub.2 to C.sub.4 diol, and a C.sub.8 to C.sub.16 dicarboxylic acid or C.sub.6 to C.sub.12 lactide. The inventions also relates to a polyester for use in forming the polyurethane of the first aspect, said polyester formed from a dimer fatty acid, a C.sub.2 to C.sub.4 diol, and a C.sub.8 to C.sub.16 dicarboxylic acid or C.sub.6 to C.sub.12 lactide.

Polyurethanes

The present invention relates to a polyurethane which is the reaction product of a polyisocyanate and polyester, wherein said polyester is formed from a dimer fatty acid, a C.sub.2 to C.sub.4 diol, and a C.sub.8 to C.sub.16 dicarboxylic acid or C.sub.6 to C.sub.12 lactide. The inventions also relates to a polyester for use in forming the polyurethane of the first aspect, said polyester formed from a dimer fatty acid, a C.sub.2 to C.sub.4 diol, and a C.sub.8 to C.sub.16 dicarboxylic acid or C.sub.6 to C.sub.12 lactide.

Aircraft windows
11248083 · 2022-02-15 · ·

The present invention provides an aircraft window including a polyurethane including a reaction product of components including (a) about 1 equivalent of at least one polyisocyanate; and (b) about 1 equivalent of 1,4-cyclohexane dimethanol based upon the about 1 equivalent of the at least one polyisocyanate, and other aircraft window compositions.

HYBRID NOVOLAC POLYUREA/POLYURETHANE
20170260319 · 2017-09-14 ·

A hybrid polyurethane/polyurea polymer suitable for forming a coating on a structure which is in contact with water includes the reaction product of a polyol component consisting of one or more polyols, a polyamine, and a curing agent, such as a polyisocyanate. The polyol component includes a Novolac-type polyether polyol.

Urethane acrylic hybrid polymer dispersion with robust dry/wet adhesion and basecoats prepared therefrom

This invention relates to urethane acrylic hybrid polymer dispersion with robust dry/wet adhesion and the basecoats prepared therefrom for automotive applications. In this system, the polyurethane dispersion (PUD) prepolymer is based on a combination of polyols and aliphatic diisocyanates. The acrylic portion is based on (meth)acrylated monomers. A combination of this hybrid polymer dispersion and other resins having defined glass transition temperature (T.sub.g) values, organic and/or inorganic rheology modifiers, and different additives including pigment, dispersant, and defoamer are used to prepare waterborne basecoats having modified appearance and performance. The final coatings show excellent dry/wet adhesion to the primer for automotive applications.

Reactive amine catalysts for polyurethane applications

Tertiary amine catalysts having isocyanate reactive groups that are capable of forming thermally stable covalent bonds able to withstand temperatures up to 120° C. are disclosed. These catalyst can be used to produce polyurethane foam having the following desirable characteristics: a) very low chemical emissions over a wide range of environmental conditions and isocyanate indexes (e.g., indexes as low as 65 but higher than 60) while meeting all physical property requirements; b) sufficient hydrolytic stability to maintain the catalyst covalently bound to foam without leaching of tertiary amine catalyst when foam is exposed to water or aqueous solutions even at temperatures higher than ambient (temperature range 25° C. to 90° C.); and c) stable contact interface between the polyurethane polymer and other polymers (for example polycarbonate) with minimal migration of tertiary amine catalyst from polyurethane polymer to other polymers yielding no noticeable polymer deterioration at the point of contact even under conditions of heat and humidity.

POLYURETHANE FOAM SPONGE AND WOUND DRESSING HAVING THE SAME
20210395438 · 2021-12-23 ·

Disclosed herein is a polyurethane foam sponge produced by the steps of a) providing an hydrophobic polyol which has six hydroxyl groups, b) providing a hydrophilic diisocyanate obtained by reacting a diisocyanate with a hydrophilic polyether diol, c) reacting the hydrophobic polyol with the hydrophilic diisocyanate to obtain a prepolymer which includes 3 to 6 isocyanate groups, and d) mixing the prepolymer with a hydrophilic polyether polyol, a blowing agent, an end-capping agent, a reinforcing agent, and a catalyst to obtain the polyurethane foam sponge. A wound dressing including the polyurethane foam sponge is also disclosed.

Thermoplastic compositions, methods, apparatus, and uses

Thermoplastic polyurethane (TPU) compositions, methods for producing TPU compositions, methods of using TPU compositions, and apparatuses produced therefrom are disclosed. Disclosed TPU compositions include a thermoplastic polyurethane polymer, a heat stabilizer, a flow agent, and a filler material. The filler may be a glass fiber. Disclosed TPU compositions have improved thermal stability and improved flow properties suitable for injection molding of articles of manufacture having a large plurality of fine openings or pores. Articles produced from the composition have superior thermal stability, abrasion resistance, and chemical resistance. Example articles include screening members for vibratory screening machines.