Provided is an aqueous coating composition that can exhibit high coating film performance even when cured at a relatively low temperature. The present invention pertains to an aqueous coating composition comprising (A) a hydroxyl group-containing resin and (B) a blocked polyisocyanate compound. The weight average molecular weight of the blocked polyisocyanate compound (B) is in a range of 20,000-200,000.

Provided is an aqueous coating composition that can exhibit high coating film performance even when cured at a relatively low temperature. The present invention pertains to an aqueous coating composition comprising (A) a hydroxyl group-containing resin and (B) a blocked polyisocyanate compound. The weight average molecular weight of the blocked polyisocyanate compound (B) is in a range of 20,000-200,000.

Provided herein according to embodiments is a prepolymer compound of formula I: ##STR00001##
and a prepolymer compound of formula II: ##STR00002##
A polymerizable liquid composition comprising the prepolymer compound, methods of use in forming a three-dimensional object, and objects produced are also provided.

Provided herein according to embodiments is a prepolymer compound of formula I: ##STR00001##
and a prepolymer compound of formula II: ##STR00002##
A polymerizable liquid composition comprising the prepolymer compound, methods of use in forming a three-dimensional object, and objects produced are also provided.

New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling Chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.

New shape memory polymer compositions, methods for synthesizing new shape memory polymers, and apparatus comprising an actuator and a shape memory polymer wherein the shape memory polymer comprises at least a portion of the actuator. A shape memory polymer comprising a polymer composition which physically forms a network structure wherein the polymer composition has shape-memory behavior and can be formed into a permanent primary shape, re-formed into a stable secondary shape, and controllably actuated to recover the permanent primary shape. Polymers have optimal aliphatic network structures due to minimization of dangling chains by using monomers that are symmetrical and that have matching amine and hydroxl groups providing polymers and polymer foams with clarity, tight (narrow temperature range) single transitions, and high shape recovery and recovery force that are especially useful for implanting in the human body.

A method of pouring a body, including mixing an isocyanate, a polyol, and a catalyst to yield an admixture, dispersing a particulate phase in the admixture to yield a homogeneous composition, pouring the homogeneous composition into a preform, capping the preform to prevent expansion of the homogeneous composition thereoutof, and curing the homogeneous composition to yield a polymeric composite body. The matrix portion is formed from a polymerizable formulation comprising at least one isocyanate precursor, at least one polyol, and a catalyst contained in a mold having a pressure rating of at least 0.4 Mpa. The at least one isocyanate precursor is selected from the group consisting of polymethylene polyphenylisocyanate, diphenylmethane diisocyanate, triphenylmethane triisocyanate, toluene diisocyanate and methyl diisocyanate (MDI), and combinations thereof. The catalyst is selected from the group consisting of a dialkyltin derivative, tributyl bismuth, and combinations thereof and is a tertiary amine.

An elastomeric composite polyurethane skin having an average flexural modulus, measured in accordance with ASTM D790-03, smaller than 35 MPa is disclosed. The elastomeric composite polyurethane skin includes a first aliphatic polyurethane layer made from a first polyurethane reaction mixture having at least one isocyanate compound with at least two NCO-groups which are not directly attached to an aromatic group, at least one isocyanate-reactive component (B1), and at least one catalyst component (C1) substantially free of lead, and a second aromatic polyurethane layer made from a second polyurethane reaction mixture having at least one aromatic isocyanate compound (A2), and at least one isocyanate-reactive component (B2).

An embodiment includes a polymer composition comprising a thermoplastic polymer that: (a) is bonded to iodine, (b) includes a vinyl group, and (c) includes urethane linkages. Other embodiments are described herein.

Disclosed is an organic amine salt foaming agent, that is, a composite polyurethane foaming agent, comprising: 1) hexafluorobutene; and 2) an alkanolamine salt mixture (MAA), the alkanolamine salt mixture (MAA) contains an organic amine salt compound having the following general formula (I): A.sup.n−[B.sup.m+].sub.p (I); wherein A.sup.n− is one or two or three selected from the following anions: (b) carbonate: CO.sub.3.sup.2−; (c) formate: HCOO.sup.−; (d) bicarbonate: HO—COO.sup.−. A polyurethane foaming method using carbon dioxide and an organic amine in combination is also disclosed, in which carbon dioxide is added to a polyurethane composition for foaming. A method for preparing an alkanolamine carbonate salt with low water content from ammonium carbonate and an epoxide is additionally disclosed, in which a liquid alkanolamine salt mixture is used as a dispersion medium or as a solvent for reaction raw material.