A spray foam formulation used to form a spray foam insulation layer in a wall structure is described. The formulation may include the reaction product of a polyisocyanate compound and a polyol compound; a fire retardant chosen from at least one of a non-halogenated fire retardant; and a reactive halogen-containing fire retardant, and a carbohydrate. The spray foam insulation layer has an insulative R value of 3.0 to 7.2 per inch, and a density of between about 0.3 to about 4.5 pcf. Further, spray foam insulation made from the spray foam formulation may have fire retardant characteristics that are equivalent to or better than a similar spray insulation foam insulation using non-reactive halogenated fire retardants such as tris(1-chloro-2-propyl)phosphate (TCPP).

Compositions suitable for production of polyurethane foams, comprising at least one OH-functional compound (OHC) obtainable by the partial or complete hydrogenation of ketone-aldehyde resins, wherein the OH-functional compound contains at least one structural element of the formula (1a) and optionally of the formulae (1b) and/or (1c), ##STR00001##
with R=aromatic with 6-14 carbon atoms, (cyclo)aliphatic with 1-12 carbon atoms, R.sup.1=H, CH.sub.2OH, R.sup.2=H, or a radical of the formula (CH.sub.2CH(R)O).sub.yH where R is hydrogen, methyl, ethyl or phenyl and y=1 to 50, k=2 to 15, preferably 3 to 12, more preferably 4 to 11, m=0 to 13, preferably 0 to 9, l=0 to 2,
where the sum of k+l+m is from 5 to 15, preferably from 5 to 12, and k>m, are described.

A rigid polyurethane foam comprises the reaction product of an isocyanate and a thixotropic composition. The thixotropic composition comprises: a first polyether polyoi which is aromatic amine initiated and has ethylene and propylene oxide end capping; a second polyether polyoi having a viscosity at 25 C. of from about 500 to about 15,000 cps; a third polyether polyoi having a viscosity at 25 C. of from about 18,000 to about 60,000 cps and a functionality of from about 5 to about 7; and a hydrofluoroolefin. The thixotropic composition has a viscosity at 25 C. of from about 350 to about 5,000 cps. A method of forming a composite article comprising a substrate and the rigid polyurethane foam includes the steps of providing the thixotropic composition, providing an isocyanate, combining the thixotropic composition and the isocyanate to form a reaction mixture, and applying the reaction mixture to the substrate to form the composite article.

A reaction system, such as for forming a rigid polyurethane foam, includes a flame retardant polyol that is a brominated reaction product of a cardanol component, a bromine component, and an additive component. The cardanol component includes at least 80 wt % of cardanol, based on the total weight of the cardanol component, and the bromine component including at least 80 wt % of bromine, based on the total weight of the bromine component.

Disclosed are methods of forming foam comprising: (a) providing a foamable composition comprising an isocyanate, a polyol and a physical blowing agent comprising at least about 50% by weight of hydrohaloolefin, including trans1233zd, and wherein the polyol comprises a polyol or mixture of polyols such that the hydrohaloolefin, including trans1233zd, has a solubility in said polyol of less than about 30%; and (b) forming a foam from said foamable composition.

Compositions suitable for production of polyurethane foams, comprising at least one OH-functional compound (OHC) obtainable by the partial or complete hydrogenation of ketone-aldehyde resins, wherein the OH-functional compound contains at least one structural element of the formula (1a) and optionally of the formulae (1b) and/or (1c),

##STR00001##

with R=aromatic with 6-14 carbon atoms, (cyclo)aliphatic with 1-12 carbon atoms, R.sup.1=H, CH.sub.2OH, R.sup.2=H, or a radical of the formula (CH.sub.2CH(R)O).sub.yH
where R is hydrogen, methyl, ethyl or phenyl and y=1 to 50, k=2 to 15, preferably 3 to 12, more preferably 4 to 11, m=0 to 13, preferably 0 to 9, l=0 to 2,
where the sum of k+1+m is from 5 to 15, preferably from 5 to 12, and k>m, are described.

The embodiments described herein generally relate to methods and chemical compositions of triazine-arylhydroxy-aldehyde condensates. In one embodiment, a triazine-arylhydroxy-aldehyde condensate is reacted with at alkoxylation agent to form alkoxylated triazine-arylhydroxy-aldehyde condensates.

A process comprising, consisting of, or consisting essentially of: forming a reaction mixture containing at least one polyisocyanate and an isocyanate-reactive compound comprising at least one alkoxylated triazine-arylhydroxy-aldehyde condensate composition wherein the alkoxylated triazine-arylhydroxy-aldehyde condensate composition is a reaction product of a triazine-arylhydroxy-aldehyde condensate and at least one alkylene carbonate, is disclosed.

Polyurethane composites comprising non-silane treated glass fibers and methods of manufacturing are described herein. The polyurethane composites can include (a) a polyurethane formed by the reaction of (i) one or more isocyanates selected from the group consisting of diisocyanates, polyisocyanates, and mixtures thereof, and (ii) one or more polyols; (b) a filler; and (c) non-silane treated glass fibers. In some instances, none of the glass fibers in the polyurethane composites are silane treated. The polyurethane composites comprising the non-silane treated glass fibers can have a flexural strength that is greater than the flexural strength of an identical composition wherein the non-silane treated glass fibers are replaced with silane-treated glass fibers. Articles comprising the polyurethane composites are also disclosed herein.

An intumescent coating system contains: a polyol component; an isocyanate component; a latent crosslinker having two or more NACH.sub.2OR groups, where A is selected from a group consisting of H and CH.sub.2OR, and in each case R is independently selected from a group consisting of hydrocarbons having from one to four carbons, the latent crosslinker being present at a concentration of 30 weight-percent or more based on polyol weight; a boron component one weight-percent or more and 10 weight-percent or less based on total weight of the formulation; and expandable graphite at a concentration of 10 weight-percent or more and 50 weight-percent or less based on the total intumescent system weight; where the polyol and isocyanate are selected so that the reaction product at room temperature of the intumescent coating system components produces a coating having a tensile elongation of 40-percent or more as determined according to ISO 37.