A moisture-curable reactive hot-melt adhesive composition comprises: a urethane prepolymer having an isocyanate group, the urethane prepolymer being a reaction product of a polyol component comprising a polyester polyol, a polyether polyol and a polybutadiene polyol with an isocyanate component; and an antioxidant.

A curable composition including: a component (a): a polycarbonate polyol having a hydroxyl value of 40 to 75 mgKOH/g; a component (b): a polycarbonate polyol having a hydroxyl value of 100 to 280 mgKOH/g; and a component (c): a polyisocyanate having an average number of functional groups per molecule, of 2 to 6.

The invention features a reactive hot melt adhesive composition comprising the reaction product of from 5% by weight to 40% by weight of a first polyester polyol comprising the reaction product of a dicarboxylic acid monomer, a tetra alkyl cyclobutane diol and optionally one or more additional monomers, from 10% by weight to 80% by weight of a sustainable polyol, and a diisocyanate.

A polyurethane composition suitable for coating a surface of a substrate. The polyurethane composition can include an aliphatic polyester urethane matrix and a fluorinated ionic antistatic additive. The aliphatic polyester urethane matrix can comprise an aliphatic diisocyanate, a polyester polyol having a polyester diol and a polyester triol, and sulfonated polyester urethane polyol.

A method for preparing polyisocyanurate and polyurethane foams by the use of a liquid siloxane nucleating additive, and a foam-forming composition for preparing foams with improved thermal insulation performance, comprising an isocyanate component, an isocyanate-reactive component, a blowing agent, and a liquid siloxane nucleating additive.

Described herein is a multilayered article and methods of making and using such articles. The multilayered article comprises: .Math. (a) a microsphere layer comprising a plurality of microspheres (11) disposed in a monolayer; .Math. (b) a bead bonding layer (12) comprising a first major surface and a second opposing major surface wherein the plurality of microspheres is at least partially embedded in the first major surface of the bead bonding layer, and wherein the bead bonding layer comprises a thermoset polyurethane, and wherein the thermoset polyurethane is derived from one or more liquid polyols; and .Math. (c) an elastomeric layer (14) disposed on the second opposing major surface of the bead bonding layer.

A thermoplastic polyurethane resin suitable for a laminating process and a method for producing the same are provided. The thermoplastic polyurethane resin is formed of an isocyanate component, a polyol component, a chain extender component, and a chain terminator component that is a monohydric alcohol via a polymerization reaction. The polyol component includes a first polyol having a number average molecular weight between 600 and 2,000 g/mol and a second polyol having a number average molecular weight between 1,500 and 3,000 g/mol. The chain extender component includes a first chain extender and a second chain extender. The first chain extender is a dihydric alcohol having a carbon chain length of C2-6, and a molecular structure thereof is linear and symmetrical. The second chain extender is a dihydric alcohol having a carbon chain length of C3-10, and a molecular structure thereof has a side chain and/or an ether group.

The present invention relates to a thermoplastic silicone-polyurethane elastomer and a method for preparing the same. The elastomer is prepared from raw materials comprising: 25-80 parts of a macromolecular polyol, 0-60 parts of a silicone oil or a liquid silicone rubber, 10-50 parts of a diisocyanate, 3-20 parts of a small molecular diol as a chain extender, and 0.1-3 parts of an auxiliary agent. The macromolecular polyol is selected from a silicon-free polyol having a molecular weight of between 1,000 and 4,000 g/mol and a polyol modified by silicone through copolymerization or grafting. The small molecular diol is a small molecular diol comprising 10 or less carbon atoms. The thermoplastic silicone-polyurethane elastomer of the present invention has the following excellent performance parameters: a hardness of Shore A40-D80; a tensile strength ≥5 MPa; smooth hand feeling; resistance to dirt such as dust; resistance to liquid permeation; no irritation to skin; good encapsulation effect on PC, ABS, TPU and the like; and a 180° peel strength >25 N/25 mm.

An isocyanate-reactive composition comprising (i) at least one isocyanate-reactive compound; and (ii) at least one T-shaped siloxane material at a predetermined amount; and a foam-forming composition for producing a polyurethane or polyisocyanurate foam comprising at least one isocyanate component and at least one isocyanate-reactive component; wherein the at least one isocyanate-reactive component is the above isocyanate-reactive composition.

A sheet like article produced from a polyurethane resin has a carbonate group and an oxycarbonyl group as ester groups and has uniform, elegant surface quality, a flexible, highly crease recoverable texture, and high resistance to light and hydrolysis, and also provided is a production method therefore. The sheet like article is produced by adding, as a binder, a polyurethane resin that meets requirements (I) and (II) to a fibrous base material formed mainly of ultrafine fibers: (I) a polyurethane resin such that the polyurethane resin contains, in its interior, an oxycarbonyl group and a carbonate group as ester groups; (II) a polyurethane resin such that the sum of the content of the urethane group and the content of the urea group in the polyurethane resin is 7.0 to 11.0 mass %.