A low-VOC, two-component polyurethane adhesive is provided. The polyurethane adhesive has an A-side that includes an isocyanate and a non-reactive plasticizer, and a B-side that includes an aliphatic polyester polyol, a non-polyester polyol, and a urethane catalyst. The A-side and the B-side are reacted at a volume ratio of 1:1 and formulated at an NCO/OH index within the range of 0.90 to 1.10. The polyurethane adhesive is solvent-free and is particularly suitable for adhering a polymeric membrane to a substrate.

Provided is a resin composition for producing a coating composition excellent in appearance, abrasion resistance, and hardness of a coating film. The resin composition of the present invention includes a compound A having a branched structure which has a terminal hydroxyl group, a polyisocyanate B, and an inorganic particle C, in which the inorganic particle C has a functional group enabling reacting with a hydroxyl group or an isocyanate group on a surface thereof.

Provided is a polyurethane resin-forming composition for a membrane-sealing material, the polyurethane resin-forming composition contributing to formation of (1) a urethane resin that is excellent in moldability, has a suppressed elution amount of a low-molecular-weight reaction product, and has excellent appearance or (2) a urethane resin that has a low viscosity, is excellent in cast moldability, and has a reduced water elution amount of a low-molecular-weight reaction product and a reduced solvent elution amount of a molded product.

The polyurethane resin-forming composition for a membrane-sealing material comprises: a polyisocyanate prepolymer (A) or an allophanate group-containing polyisocyanate prepolymer (A′) comprising a reaction product of a diphenylmethane diisocyanate (a1-1) and/or a modified product of a diphenylmethane diisocyanate (a1-2), and an active hydrogen-containing compound (a2); and a castor oil polymerized polyol (b1) comprising a castor oil polymerization product.

An amine functional compound is provided comprising: i. at least one segment consisting of at least one ether unit and at least one ester unit, wherein the ether units and ester units are connected by an ether link or an ester link, and wherein the sum of the number of ether units and ester units is at least three, and wherein the ether units and ester units are arranged in random order, and ii. at least one amine group ii. selected from a tertiary amine group, a salt of a tertiary amine group and a quaternary ammonium group, and wherein each segment i. is covalently linked to the at least one amine group ii. via a linkage comprising an urethane group and another group selected from an urethane group, an urea group, a biuret group and an allophanate group.

Methods are provided for producing bio-oil polyols, alkoxylating bio-oil polyols to provide polyols, and for employing the alkoxylated bio-oil polyols for making polymers or copolymers of polyesters or polyurethanes.

Polyol premixes and thermally insulating rigid polyurethane foams, such as those that can be used as a thermal insulation medium in the construction of refrigerated storage devices, are disclosed. A polymer polyol having a OH number of greater than 260 mg KOH/g is utilized. The resulting polyurethane foams can exhibit improved thermal insulation properties without sacrificing other important physical and processing properties.

A shape memory polymer hydrogel that is biodegradable, includes antimicrobial agents, and has a tunable drug delivery is used for wound healing internally and externally. The shape memory polymer is synthesized using a combination of hydrophilic precursors that are configured to have two to four functional end groups, with at least one component that has at least three functional groups. The synthesis route provides for a covalently crosslinked thermoset hydrogel. The chemistry can be tuned to provide desired transition temperatures for delivery (e.g. below 37° C.) and desired pore sizes for healing (e.g. 250-500 μm).

The invention relates to an adhesive composition that can be activated at a low temperature (from 110° C., preferably from 100° C.) and is available in the form of a film, and to the method for the production thereof. The invention also relates to a composition comprising at least one specific polyester polyol and at least one specific polyisocyanate dispersible in said polyester polyol in the presence of at least one specific organic solvent, and to the use of said composition for producing an adhesive composition that can be activated at a low temperature and is available in the form of a film.

A composite resin comprising silver nanoparticles and a polymer where the silver nanoparticles are formed by reduction of silver ions by the functional groups of the polymer without the addition or application of an external reducing agent. The composite resin has a low silver leach rate. The composite resin may be used as a surface coating, particularly an antimicrobial or antifouling surface coating.

A composite resin comprising silver nanoparticles and a polymer where the silver nanoparticles are formed by reduction of silver ions by the functional groups of the polymer without the addition or application of an external reducing agent. The composite e resin has a low silver leach rate. The composite resin may be used as a surface coating, particularly an antimicrobial or antifouling surface coating.