Disclosed are silane modified copolymers that are moisture curable; curable adhesive compositions comprising the silane modified copolymers; and methods of making the silane modified copolymers.

A polymer containing silane groups, a method for synthesizing same, and curable compositions including the polymer. The polymer containing silane groups has a very long shelf life and cures quickly with moisture. The polymer is suitable as an elastic adhesive or sealant or coating that can be applied at room temperature and has good heat resistance, or as a hot melt adhesive.

Methods for producing a polymer with end groups of formula (I), which is free of isocyanate groups, ##STR00001##
wherein at least one hydrosilane of formula (II) is reacted with at least one polyurethane polymer containing isocyanate groups, ##STR00002##
where R.sup.1 stands for an alkyl group having 1 to 12 C atoms, R.sup.2 stands for a hydrogen atom or for an alkyl group having 1 to 12 C atoms, which optionally comprises ether oxygen or amine nitrogen, R.sup.3 stands for a linear or a branched alkylene or cycloalkylene residue having 1 to 20 C atoms, optionally with aromatic parts, and optionally with one or more heteroatoms, R.sup.4 stands for an alkyl group having 1 to 6 C atoms, R.sup.5 stands for an alkyl group having 1 to 10 C atoms, which optionally comprises one or more ether oxygens, n stands for 2 or 3 or 4, and x stands for 0 or 1.

The present invention relates to a compound of formula (I):

##STR00001##

and also to the process for preparing same, and to the uses thereof. The present invention also relates to the polyurethanes obtained from the compounds of formula (I), and also to the uses of said polyurethanes.

The present invention relates to a process for producing flame-retarded polyurethane foams, in particular flexible polyurethane foams, using halogen-free flame retardants, wherein the resulting flame-retarded polyurethane foams exhibit low emission values coupled with good mechanical properties. The present invention further relates to halogen-free flame retardants.

The invention relates in a first aspect to a process for producing a polyurethane foam, comprising the reaction of (a) an isocyanate composition comprising at least one polyisocyanate based on diphenylmethane diisocyanate; (b) a polyol mixture, wherein the polyol mixture comprises (b1) 50% to 85% by weight of at least one polyether polyol having a hydroxyl value in the range from 10 to 60 mg KOH/g, an OH functionality of more than 2, and an ethylene oxide proportion in the range from 50% to 100% by weight based on the alkylene oxide content of the at least one polyether polyol, and (b2) 15% to 50% by weight of at least one polyether polyol having a hydroxyl value in the range from 10 to 100 mg KOH/g, an OH functionality of more than 2, an ethylene oxide proportion in the range from 2% to 30% by weight based on the alkylene oxide content of the at least one polyether polyol, and a proportion of primary OH groups of 40 to 100% based on the total number of OH groups in the at least one polyether polyol, in each case based on the total amount by weight of constituents (b1) and (b2), which adds up to 100% by weight, and (b3) 0 to 20 further parts by weight of an optionally derivatized filler, based on 100 parts by weight of components (b1) and (b2), optionally present as a constituent of a graft polyol based on one or more of components (b1) and (b2); (c) a blowing agent composition comprising water; wherein the reaction employs the blowing agent composition (c) in a weight-based ratio of the weight of blowing agent composition (c) to the total weight of all isocyanate-reactive compounds used in the reaction in the range from 1:14 to 1:6; wherein a polyurethane foam having a foam density, determined according to DIN EN ISO 845 (October 2009), of not more than 25 kg/m.sup.3 and a compression hardness, determined at 40% compression in the first compression in accordance with DIN EN ISO 3386-1 (October 2015), in the range from 10 to 80 kPa is obtained.

In a second aspect, the invention relates to a polyurethane foam obtained or obtainable by the process of the first aspect.

A third aspect of the invention relates to the use of a polyurethane foam according to the second aspect as a sound absorption material.

According to a fourth aspect, the invention relates to a sound absorption material comprising a polyurethane foam according to the second aspect, preferably consisting of a polyurethane foam according to the second aspect.

A fifth aspect of the invention relates to the use of a polyol mixture (b) comprising (b1), (b2), and (b3) as defined in the first aspect, for producing a polyurethane foam.

A polyol composition for forming flexible polyurethane foam including a polyol component having a number average molecular weight of 2,500 or more, a catalyst, a foam stabilizer, a foaming agent, and a crosslinking agent, wherein water is contained as the foaming agent, wherein a sugar alcohol is contained as the crosslinking agent, wherein the content of the sugar alcohol with respect to 100 parts by mass of the polyol component is 0.1 to 5.0 parts by mass, and wherein no divalent tin catalyst is contained.

This invention relates to improved flexible foams prepared from polymer polyols and to a process for preparing these improved flexible foams.

In a process for producing polyoxymethylene-polyalkylene oxide block copolymers comprising the step of polymerizing an alkylene oxide in the presence of an OH-terminated polyoxymethylene polymer and a catalyst, the polyoxymethylene polymer has a number-average molecular weight Mn determined after derivatization with propylene oxide and gel permeation chromatography against polystyrene standards with tetrahydrofuran as the eluent of ≥1100 g/mol to ≤2300 g/mol and the ratio of alkylene oxide to polyoxymethylene polymer is ≥0.05 mol/g. The invention further relates to copolymers obtainable by the process, to a process for producing polyurethane polymers using these copolymers and to polyurethanes obtainable therefrom.

This invention relates to a process for preparing a flexible polyurethane foam in which the isocyanate-reactive component comprises a specific isocyanate-reactive component. The invention also relates to flexible polyurethane foam wherein the isocyanate-reactive comprises the specific isocyanate-reactive component.