High resiliency polyurethane foam is made from a polyether polyol having an equivalent weight of at least 1000. At least a portion of the polyether polyol is one or more random copolymer(s) formed by polymerizing a mixture of 70 to 95% by weight propylene oxide and 5 to 30% by weight ethylene oxide onto an initiator compound. The random copolymer(s) has a nominal hydroxyl functionality of at least 5, a hydroxyl equivalent weight of at least 1500 g/equivalent and no more than 0.01 milliequivalents per gram of terminal unsaturation. The randomly polymerized propylene oxide and ethylene oxide constitute at least 80% of the total weight of the random copolymer. At least 70% of the hydroxyl groups of the random copolymer are secondary hydroxyls.

This invention relates to a novel polyol composition and a process for preparing these polyol compositions. These novel polyol compositions comprise (a) an in-situ formed polyol blend which comprises (i) one or more polyether monols and (ii) one or more polyether polyols; and (b) a polyether polyol. This invention also relates to a process for preparing an open celled, flexible polyurethane foam in which the isocyanate-reactive component comprises this novel polyol composition, and to a viscoelastic polyurethane foam wherein the isocyanate-reactive comprise the novel polyol composition.

A moisture-curing polyurethane composition having a content of monomeric diisocyanates of at most 0.1 wt %, containing: at least one isocyanate-group-containing polyurethane polymer having a content of monomeric diisocyanates of at most 0.5 wt %, obtained from reaction of at least one monomeric diisocyanate with at least one polyether polyol at a NCO/OH ratio of at least 3/1 and subsequent removal of a large part of monomeric diisocyanates by way of a suitable separating method; and at least one polyether having blocked hydroxyl groups and free of isocyanate groups, as a plasticizer. Moisture-curing polyurethane composition is highly storage-stable when moisture is excluded, can be safely handled without special safety precautions, can be sold without hazard label, can be well processed, has long open time and has fast curing to form elastic material of high strength and extensibility, high cold flexibility, good adhesion properties and high stability with respect to heat and moisture.

This invention relates to a process for preparing viscoelastic polyurethane foam in which the isocyanate-reactive component comprises a specific polyol blend, and to viscoelastic polyurethane foam wherein the isocyanate-reactive comprises the specific polyol blend. The polyol blend may be an in situ formed polyol blend.

Disclosed is a moisture curable silane modified terpolymer comprising a polyether segment, a segment of polytetrahydrofuran or polycarbonate, a polysiloxane segment and terminal amino silane groups joined to the terpolymer via urethane linkages and wherein the polyether segment comprises at least 70% by weight based on the total weight of the silane modified terpolymer. Also disclosed is a method of forming moisture curable silane modified terpolymer.

This invention relates to novel preformed stabilizers in which a portion of the polymer control agent is recovered and comprises from 10 to 1500 ppm of an inhibitor. This invention also relates to a process for preparing these preformed stabilizers, and to polymer polyols comprising these novel preformed stabilizers macromers and to a process for preparing polymer polyols comprising these novel preformed stabilizers. The present invention also relates to polyurethane foams comprising these polymer polyols, and to processes for preparing these polyurethane foams.

Curable compositions that include an oligomer with one or more internal urethane linkages and OH groups capped by an Acrylate-End-Capping (AEC) compound. The curable compositions may be made by reacting a polyol with a diisocyanate compound to form a pre-oligomer compound having one or more internal urethane linkages and terminal OH groups. The curable coating compositions may be cured to form a coating for an optical fiber, for example, a primary coating for an optical fiber.

Provided herein is a process for producing viscoelastic polyurethane foams having a density of from 100 g/dm.sup.3 to 300 g/dm.sup.3, in which (a) polyisocyanate is mixed with (b) polymeric compounds having groups that are reactive toward isocyanates, (d) a catalyst, and (e) a blowing agent including water at an isocyanate index of from 50 to 95 to give a reaction mixture. The reaction mixture is placed in a mold and reacted to give the flexible polyurethane foam, wherein the polyisocyanate (a) is obtainable by mixing 4,4-MDI and oligomers of propylene oxide having from 2 to 8 propylene oxide units. The polymeric compounds (b) include at least one polyalkylene oxide having a hydroxyl number of from 20 to 50 mg KOH/g derived from a trifunctional starter molecule and a proportion of ethylene oxide, based on the content of alkylene oxide, of from 0 to 10% by weight.

Described herein are coated optical fibers including an optical fiber portion, wherein the optical fiber portion includes a glass core and cladding section that is configured to possesses certain mode-field diameters and effective areas, and a coating portion including a primary and secondary coating, wherein the primary coating is the cured product of a composition that possesses specified liquid glass transition temperatures, such as below 82 C., and/or a viscosity ratios, such as between 25 C. and 85 C., of less than 13.9. Also described are radiation curable coating compositions possessing reduced thermal sensitivity, methods of coating such radiation curable coating compositions to form coated optical fibers, and optical fiber cables comprising the coated optical fibers and/or radiation curable coating compositions elsewhere described.

An aldiminosilane of the formula (I), to the use thereof as adhesion promoters and/or crosslinking agents, and to curable compositions including same. The aldiminosilane of the formula (I) is odorless, pH-neutral, liquid at room temperature, and has a low sensitivity to heat. The hydrolysis of the aldiminosilane proceeds relatively slowly, and the aldiminosilane is highly effective as an adhesion promoter. Furthermore, the aldiminosilane exhibits excellent compatibility with curable compositions based on isocyanates, epoxides, or silanes, whereby such compositions do not exhibit a propensity for migration effects such as bleeding or substrate soiling after being cured. In particular, isocyanate group-containing compositions containing the aldiminosilane of the formula (I) are highly storage-stable regardless of the storage temperature and the isocyanate used.